高功率连续侧面泵浦1 341.4 nm Nd:YAP激光器

报道了一台线性偏振输出、波长为1 341.4 nm、采用激光二极管（LD）连续侧面泵浦的Nd:YAP激光器。通过分析Nd:YAP晶体的能级结构和跃迁特点,显示了Nd:YAP晶体作为1.3 μm波段激光器的工作物质的优点。实验对比了不同透过率的输出耦合镜片的输出功率。最终以透过率为6.5% 的输出耦合镜片,在555 W的LD泵浦功率下获得了121 W的平行于晶体c轴线性偏振（c偏振）的1 341.4 nm激光输出,光-光转化效率21.8%,斜率效率为41%;并且在c偏振激光失稳后成功获得了平行于a轴的线性偏振（a偏振）的1 339.2 nm激光。     

重离子冷却储存环CSRm双电子复合实验研究类锂36,40Ar15+离子同位素移动

配备电子冷却装置的重离子储存环为开展高电荷态离子的双电子复合（dielectronic recombination,DR）精密谱学研究提供了绝佳的实验平台。本工作在兰州重离子加速器冷却储存环主环（HIRFL-CSRm）上开展了类锂36,40Ar15+离子的双电子复合实验,实验观测了电子-离子质心系能量范围为0~35 eV的双电子复合速率系数谱。通过外推法获得了36,40Ar15+离子2s_1/2→2p_1/2和2s_1/2→2p_3/2的跃迁能量。同时利用GRASP2K程序理论计算了36,40Ar15+离子2s_1/2→2p_1/2和2s_1/2→2p_3/2跃迁的质量移动因子和场移动因子,进而得到双电子复合谱的同位素移动值。36,40Ar15+离子2s_1/2→2p_1/2和2s_1/2→2p_3/2同位素移动分别为0.861 meV和0.868 meV。它们均小于目前CSRm上双电子复合实验的实验分辨为~10 meV,进而解释了实验测量的DR谱上未能观察到同位素移动的原因。然而,高电荷态离子的同位素移动场效应与原子序数Z5成正比,因此,在重离子加速器冷却储存环实验环（HIRFL-CSRe）以及未来大型加速器--强流重离子加速器装置（HIAF）上有望通过DR精密谱学方法研究高电荷态重离子甚至放射性离子的同位素移动,进而获得相关原子核的核电荷半径等信息。The cooler storage ring is equipped with an electron-cooler. It is an excellent experimental platform for dielectronic recombination (DR) experiment of highly-charged ions. In this paper, the dielectronic recombination experiments of lithium-like Ar15+ ions with mass number 36 and 40 are conducted at the HIRFL-CSRm(main ring of the Cooling Storage Ring of Heavy Ion Research Facility in Lanzhou). The experimental electron-ion collision energy scale is from 0 eV to 35 eV. Extrapolation method is exploited to obtain the excitation energies of transitions 2s_1/2→2p_1/2 and 2s_1/2→2p_3/2 of the 36,40Ar15+ ions from experimental data. Meanwhile, GRASP2K program is utilized to calculate the mass shift factors and field shift factors of 36,40Ar15+ ions for 2s_1/2→2p_1/2 and 2s_1/2→2p_3/2 transitions to obtain isotope shifts in DR spectra. In theoretical calculation, isotope shifts of 36,40Ar15+ ions corresponding to 2s_1/2→2p_1/2 and 2s_1/2→2p_3/2 are 0.861 meV and 0.868 meV, respectively. They are both less than the experimental precision (~10 meV) of these dielectronic recombination experiments at the CSRm, which explains that isotope shifts cannot be distinguished from the experimental dielectronic recombination spectra. However, the field shift of highly-charged ions is proportional to Z5. In the future, the dielectronic recombination experiments of highly-charged heavy ions even radioactive ions will be conducted at the HIRFL-CSRe (experimental ring of the Cooling Storage Ring of Heavy Ion Research Facility in Lanzhou) and the future large accelerator facility--HIAF(High intensity Heavy-ion Accelerator Facility) to measure isotope shifts to obtain the nuclear charge radius information.     

Regulation of Zn/Sn ratio in kesterite absorbers to boost 10% efficiency of Cu_2ZnSn(S,Se)_4 solar cells

The Zn/Sn ratio in Cu_2ZnSn(S,Se)_4(CZTSSe)films has been regulated to control the composition-related phase,defect,and photoelectric properties for high performance kesterite solar cells.It is found that the increase in the Zn/Sn ratio can slightly narrow the energy band gap to extend the light absorption range and improve the photocurrent.Optimal Zn/Sn ratio of 1.39 in CZTSSe film is obtained with the least secondary phase,the lowest defect density,and the longest charge recombination lifetime.Up to 10.1%photoelectric conversion efficiency has been achieved by this composition regulation.     

8 mm回旋行波管和返波管的三折螺旋波纹波导色散分析

 三折螺旋波纹波导使TE11模和TE21模相互耦合,其色散曲线能够在宽频带内与电子回旋共振,因此需要对色散方程进行研究。提出了适合工程实用的行波模式和返波模式的色散方程,并对方程中的耦合系数进行了简化,误差在1%左右。利用CST软件的VBA语言对螺旋波纹波导进行建模和计算,根据模拟得到的传输特性曲线的特点,提出一种模拟方法,将模拟与理论计算得到的色散曲线作对比,误差在5%左右。     

多组元化合物晶体生长过程中的双扩散对流现象

针对多组元化合物晶体的Bridgman生长过程,通过对液相区流场和浓度场的数值模拟,研究生长过程中容器内部双扩散对流与组分分布的情况.首先对比了三段场和梯度场炉壁温度设计情况下液相区的流体双扩散对流以及组分分布情况.在此基础上,针对梯度场炉壁温度条件,分析了不同参数的影响.结果表明:在溶质格拉晓夫数较大时,它的增大能够明显地削弱液相区的流体流动,从而使得界面附近的组分分布也产生变化;此外,拉晶速度的增大也能够使得液相区的双扩散对流受到抑制.     

Tribological properties of diamond-like carbon films deposited by pulsed laser arc deposition

A novel method, pulsed laser arc deposition combining the advantages of pulsed laser deposition and cathode vacuum arc techniques, was used to deposit the diamond-like carbon (DLC) nanofilms with different thicknesses. Spectroscopic ellipsometer, Auger electron spectroscopy, x-ray photoelectron spectroscopy, Raman spectroscopy, atomic force microscopy, scanning electron microscopy and multi-functional friction and wear tester were employed to investigate the physical and tribological properties of the deposited films. The results show that the deposited films are amorphous and the sp$^{2}$, sp$^{3}$ and C--O bonds at the top surface of the films are identified. The Raman peak intensity and surface roughness increase with increasing film thickness. Friction coefficients are about 0.1, 0.15, 0.18, when the film thicknesses are in the range of 17--21~nm, 30--57~nm, 67--123~nm, respectively. This is attributed to the united effects of substrate and surface roughness. The wear mechanism of DLC films is mainly abrasive wear when film thickness is in the range of 17--41~nm, while it transforms to abrasive and adhesive wear, when the film thickness lies between 72 and 123~nm.     

3′″-羰基-2″-β-L奎诺糖基淫羊藿次苷Ⅱ的NMR数据解析

对3′″-羰基-2″-β-L-奎诺糖基淫羊藿次苷Ⅱ(3′″-carbonyl-2″-β-L-quinovosy licarisideⅡ),进行了1H和13C MNR检测,参考2″-O-鼠李糖基淫羊藿次苷Ⅱ(2″-O-rhamnosy licarisid Ⅱ)、淫羊藿次苷Ⅱ(icarisid Ⅱ)和淫羊藿苷(icariin)的1H、13C NMR数据,通过DEPT和1H-1H COSY、HSQC、HMBC等2D NMR技术对该化合物所有的1H和13C NMR信号进行了全归属和详细解析.     

First-Principles Study of Electronic Structure of the Laves Phase ZrFe2

We perform the ab initio calculation for obtaining the density of states and magnetic properties of ZrFe2 Laves phase compound based on the method of augmented plane waves plus local orbital The results indicate that the ferromagnetic state is more stable than the paramagnetic one, but with a slightly larger volume. The 3d - 4d exchange interactions between Fe and Zr electrons lead to the antiparallel coupling for Fe 3d and Zr 4d states, which is responsible for the ferrimagnetic ordering of the compound. The resulting magnetic moment of about 1.98μB for Fe is spatially localized near the Fe site, while around Zr a small but extended negative spin states causes a moment of about -0.44 μB. Moreover, the resulting magnetic moments with the generalized gradient approximation are more consistent with experimental values than that of the local-spin density approximation.     

并联螺旋蒸发管内汽液两相流动不稳定性的实验研究

一、前言 近年来高温气冷堆的研究受到国内外的广泛重视,高温气冷堆系统中的关键设备之一是蒸汽发生器,这种蒸发器通常由并联螺旋管构成。众所周知,蒸汽发生器并联蒸发管在设计不当时容易发生动态流动不稳定性,即流量脉动。流量脉动会引起系统控制问题,甚至导致发生蒸发管烧毁事故,因而必须避免流量脉动的发生。到目前为止,有关蒸发管     

非腔长匹配相干叠加脉冲锁模激光器的理论研究

提出了一个新的非腔长匹配相干叠加脉冲锁模激光器的物理模型,建立了它的数学方程,并进行了模拟计算.计算结果给出了各个参数对相干叠加脉冲锁模激光器运转的影响,以及脉冲宽度压缩速度和各参数之间的关系,获得了实现非腔长匹配相干叠加脉冲锁模激光器运转的最佳条件.