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971.
972.
973.
We derive a thermodynamically consistent general continuum-mechanical model describing mutually coupled martensitic and ferro/paramagnetic phase transformations in electrically-conductive magnetostrictive materials such as NiMnGa. We use small-strain and eddy-current approximations, yet large velocities and electric current injected through the boundary are allowed. Fully nonlinear coupling of magneto-mechanical and thermal effects is considered. The existence of energy-preserving weak solutions is proved by showing convergence of time-discrete approximations constructed by a carefully designed semi-implicit regularized scheme. 相似文献
974.
Phthalimide derivatives as nitrogen nucleophiles with α,β‐unsaturated aldehydes for asymmetric aza‐Michael additions have been reported. The reactions proceed smoothly to afford corresponding Michael adducts in good yields (up to 98%) and enantioselectivities (up to 95% ee). 相似文献
975.
976.
Linyong Wang Meng Ye Lei Wang Wenzeng Duan Chun Song Yudao Ma 《Tetrahedron: Asymmetry》2017,28(1):54-61
Fluorine-substituted [2.2]paracyclophane-based carbene precursors have been successfully synthesized and applied to copper-catalyzed asymmetric β-boration of α,β-unsaturated ketones. Fluorination of the planar chiral carbenes has a beneficial impact on the catalytic performance of the relevant complexes. A variety of chiral β-boryl ketones were obtained in excellent yields (up to 99%) and with high enantioselectivities (up to 99% ee). 相似文献
977.
Jan Pecháček Jiří Václavík Jan Přech Petr Šot Jakub Januščák Beáta Vilhanová Jiří Vavřík Marek Kuzma Petr Kačer 《Tetrahedron: Asymmetry》2013,24(4):233-239
We present, to the best of our knowledge, the first parametric study of the asymmetric transfer hydrogenation of imines catalyzed by a Noyori-type catalytic complex based on ruthenium. A model imine for this study was 1-methyl-3,4-dihydroisoquinoline, and a well-known complex RuCl(η6-p-cymene)((1S,2S)-N-p-toluenesulfonyl-1,2-diphenylethylenediamine) was chosen as the model catalyst. The reactions were performed in the presence of a formic acid–triethylamine mixture as the source of hydrogen.The parameters examined include general parameters, for example, concentration, temperature, and substrate-to-catalyst molar ratio, as well as parameters specific to this particular reaction, such as the amount of the hydrogenation mixture used, the ratio of its components, or the inhibitive effect of carbon dioxide. During this study, several unexpected parameters worth further investigation have emerged. 相似文献
978.
A potential calcium-phosphate fl ower-like nanocoating were coated onto the titanium surface in an easy approach. It has high surface area, low cytotoxicity as well as promising cell affi nity, which makes it a potential alternative modifi cation method for titanium surface. 相似文献
979.
Yuzhao Ma 《Optical Review》2013,20(1):31-35
In the present work two types of low-coherence interferometry are used to estimate the ellipticity of the core of an optical fiber in the cross section. Using the time-domain low-coherence interferometry the group-index difference between the degenerate high-order modes is measured. Because of the usage of a short fiber sample the group-index difference between the degenerate fundamental modes is too small to measure. Secondly, a frequency-domain low-coherence interferometry is presented in details. Since it is an all-fiber setup, longer fiber is allowed to be used. The high-order modes are filtered. The group-index difference between the degenerate fundamental modes is obtained. For each of the methods the experimental results are used to estimate the ellipticity of the fiber core in numerical simulations. 相似文献
980.
Jiafu Wang Shaobo Qu Zhuo Xu Hua Ma Xinhua Wang Daqing Huang Yongfeng Li 《Photonics and Nanostructures》2012,10(4):540-546
We demonstrated the possibility of designing super-thin electromagnetic cloaks based on spoof surface plasmon (SSP). Using a metamaterial layer, incident waves can be coupled into SSP efficiently at the air/metamaterial interface. Due to the strong surface confinement of SSP, EM waves are squeezed into and propagate in deep sub-wavelength scales. Implementation of an 8.2 GHz cloak less than 1/50 the cloaking diameter was presented using split ring resonator (SRR). Excellent cloaking effect was verified by simulations. Rather than isolating objects from the background, such cloaks can drastically enhance the field intensity around the cloaked object. This is of particular importance in applications such as weak wave detection and near-field sensing. 相似文献