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91.
Florence Guéguen Hélène Isnard Karsten Kossert Carole Bresson Céline Caussignac Guillaume Stadelmann Anthony Nonell Sébastien Mialle Frédéric Chartier 《Journal of Radioanalytical and Nuclear Chemistry》2014,302(1):289-295
A methodology to purify a 166mHo solution has been developed by a combination of activity and mass concentration measurements in order to further determine the 166mHo half-life. The isobaric interference at m/q ? 166 requires Ho purification from non-natural Er with a high purification degree due to the large amount of Ho as opposed to Er. The Ho/Er separation was achieved using high-performance liquid chromatography on a semi-preparative column followed by purification on gravitational chromatography. The efficiency of the separation was evaluated after precise determination of the Er isotopic composition. The purification methodology enabled to separate Ho from Er. 相似文献
92.
Sylvain Cousinet Ali Ghadban Imène Allaoua Frédéric Lortie Daniel Portinha Eric Drockenmuller Jean‐Pierre Pascault 《Journal of polymer science. Part A, Polymer chemistry》2014,52(23):3356-3364
Vinyl levulinate (VL) is used as a biobased reactive diluent in styrene (St)‐free unsaturated polyester resins (UPR). The reactivity ratios for the radical copolymerization of VL with diethyl fumarate (DEF) are determined by the Jaacks method (rVL = 0.01 and rDEF = 0.81 at 60 °C in DMSO‐d6). The properties of UPRs having a stoichiometric ratio between unsaturated groups from the UPR and either St or VL are compared. Defect‐free, slightly yellow, transparent, and rigid thermosets are obtained after a mild curing cycle. Due to unfavorable reactivity ratios about 5.5 wt % of unpolymerized VL remains inside the network and acts as plasticizer. Consequently, compared with St‐based ones, VL‐based UPRs exhibit lower α relaxation (Tα = 180 and 100 °C, respectively), lower elastic moduli at the rubbery plateau (G′ = 108 and 107 Pa) and lower mechanical properties as measured by three points bending tests. Strain at break (εf = 1.8 ± 0.2%) and Charpy impact strength (~2.7 ± 0.3 kJ m?2) are comparable independently of the RD chemical nature. © 2014 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2014 , 52, 3356–3364 相似文献
93.
Mariem Ghali Chaima Brahmi Mahmoud Benltifa Cyril Vaulot Aissam Airoudj Philippe Fioux Frédéric Dumur Corine Simonnet-Jégat Fabrice Morlet-Savary Salah Jellali Latifa Bousselmi Jacques Lalevée 《Journal of polymer science. Part A, Polymer chemistry》2021,59(2):153-169
Different inorganic/organic photocomposites based on polyoxometalate (POM) nanoparticles have been developed for photocatalytic applications. Currently, polyoxometalate nanoparticles have been successfully in-situ embedded into an acrylate polymer network by photopolymerization upon mild visible light irradiation at 405 nm. The proposed POM/polymer photocomposites have been characterized using complementary techniques for a better understanding of their photocatalytic activity. Interestingly, the obtained photocomposites exhibit high rigidity, excellent thermal stability, a non-negligible porosity and new functionalities such as light reactivity and redox properties. Moreover, developed composites showed efficient catalytic activity for the color removal of aqueous solutions of erythrosine and rose Bengal under Light Emitting Diodes LED@375 nm irradiation reaching 80 and 90% as a final color removal, respectively. 相似文献
94.
95.
We consider the Vlasov-HMF (Hamiltonian Mean-Field) model. We consider solutions starting in a small Sobolev neighborhood of a spatially homogeneous state satisfying a linearized stability criterion (Penrose criterion). We prove that these solutions exhibit a scattering behavior to a modified state, which implies a nonlinear Landau damping effect with polynomial rate of damping. 相似文献
96.
David Mercier Éric Lefèvre François Delmotte 《International Journal of Approximate Reasoning》2012,53(2):146-158
In this article, the contextual discounting of a belief function, a classical discounting generalization, is extended and its particular link with the canonical disjunctive decomposition is highlighted. A general family of correction mechanisms allowing one to weaken the information provided by a source is then introduced, as well as the dual of this family allowing one to strengthen a belief function. 相似文献
97.
Pierrick Nun Violaine Pérez Monique Calmès Jean Martinez Frédéric Lamaty 《Chemistry (Weinheim an der Bergstrasse, Germany)》2012,18(12):3773-3779
The asymmetric alkylation of Schiff bases under basic conditions in a ball mill was performed. The starting Schiff bases of glycine were prepared beforehand by milling protected glycine hydrochloride and benzophenone imine, in the absence of solvent. The Schiff base was then reacted with a halogenated derivative in a ball mill in the presence of KOH. By adding a chiral ammonium salt derived from cinchonidine, the reaction proceeded asymmetrically under phase‐transfer catalysis conditions, giving excellent yields and enantiomeric excesses up to 75 %. Because an equimolar amount of starting material was used, purification was greatly simplified. 相似文献
98.
J. Antoni SellarÈs Godfried Toussaint 《International Journal of Mathematical Education in Science & Technology》2013,44(2):219-237
Computational geometry is a new (about 30 years) and rapidly growing branch of knowledge in computer science that deals with the analysis and design of algorithms for solving geometric problems. These problems typically arise in computer graphics, image processing, computer vision, robotics, manufacturing, knot theory, polymer physics and molecular biology. Since its inception many of the algorithms proposed for solving geometric problems, published in the literature, have been found to be incorrect. These incorrect algorithms rather than being ‘purely mathematical’ often contain a strong kinesthetic component. This paper explores the relationship between computational geometric thinking and kinesthetic thinking, the effect of the latter on the correctness and efficiency of the resulting algorithms, and their implications for education. 相似文献
99.
We consider the flow of a viscous incompressible fluid in a pipe when the boundary is a deformable shell of Naghdi type. We
prove that the corresponding system of partial differential equations has a solution when the deformation of the shell is
smooth and small enough. We propose an algorithm that uncouples the unknowns and prove its convergence. 相似文献
100.
Adil Mouahid David Bessieres Frédéric Plantier Gilles Pijaudier-Cabot 《Journal of Thermal Analysis and Calorimetry》2012,109(2):1077-1087
In order to assess and improve the quality of high pressure and temperature adsorption isotherms and differential enthalpies of adsorption on microporous and mesoporous materials, a specific thermostated device comprising a differential heat flow calorimeter coupled with a home-built manometric system has been built. The differential heat flow calorimeter is a Tian Calvet Setaram C80 model which can be operated isothermally, the manometric system is a stainless steel homemade apparatus. The thermostated coupled apparatus allows measurements for pressure up to 2.5?MPa and temperature from 303 to 423?K. Reliability and reproducibility were established by measuring adsorption isotherms on a benchmark sorbent (Filtrasorb F400). A detailed experimental study of the adsorption of pure carbon dioxide and methane has been made on activated carbons (Filtrasorb F400 and EcoSorb); a new procedure for determining the differential enthalpies of adsorption based on the stepwise method is also proposed. The error in the determination of the amount adsorbed is about 3.6%, and the error in the determination of the differential enthalpies of adsorption is 4%. 相似文献