全文获取类型
收费全文 | 32750篇 |
免费 | 185篇 |
国内免费 | 272篇 |
专业分类
化学 | 12444篇 |
晶体学 | 352篇 |
力学 | 1443篇 |
综合类 | 12篇 |
数学 | 9590篇 |
物理学 | 9366篇 |
出版年
2021年 | 92篇 |
2018年 | 1228篇 |
2017年 | 1507篇 |
2016年 | 825篇 |
2015年 | 644篇 |
2014年 | 568篇 |
2013年 | 853篇 |
2012年 | 3241篇 |
2011年 | 2480篇 |
2010年 | 1878篇 |
2009年 | 1641篇 |
2008年 | 631篇 |
2007年 | 681篇 |
2006年 | 642篇 |
2005年 | 4481篇 |
2004年 | 3966篇 |
2003年 | 2350篇 |
2002年 | 540篇 |
2001年 | 335篇 |
2000年 | 154篇 |
1999年 | 239篇 |
1998年 | 172篇 |
1997年 | 125篇 |
1996年 | 112篇 |
1995年 | 99篇 |
1994年 | 99篇 |
1993年 | 87篇 |
1992年 | 222篇 |
1991年 | 206篇 |
1990年 | 197篇 |
1989年 | 165篇 |
1988年 | 146篇 |
1987年 | 127篇 |
1986年 | 80篇 |
1985年 | 97篇 |
1984年 | 92篇 |
1983年 | 88篇 |
1982年 | 84篇 |
1981年 | 78篇 |
1979年 | 93篇 |
1978年 | 80篇 |
1976年 | 135篇 |
1975年 | 96篇 |
1974年 | 86篇 |
1973年 | 89篇 |
1972年 | 79篇 |
1969年 | 81篇 |
1968年 | 79篇 |
1967年 | 71篇 |
1966年 | 87篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
41.
E. Beinrohr M. Németh P. Tsch?pel G. T?lg 《Fresenius' Journal of Analytical Chemistry》1992,344(3):93-99
Summary Flow-through electrochemical cells with porous working electrodes made of crushed reticulated vitreous carbon and plated with mercury were used for absolute analysis of trace amounts of lead by anodic stripping coulometry with collection (ASCWC) in a flow system. The role of mercury coating, flow rate and pH were investigated. The coulombic content of the collection peak corresponded to the theoretical values calculated by Faraday's law in a concentration range from about 10–9 to 10–6 mol/l. The relative error and the relative standard deviation was +0.15% and 0.8%, respectively for 2×10–6 mol/l analyte concentration. The absolute detection limit (3 s) was 0.1 ng of Pb, the linear response range 7×104.
One leave from: Department of Analytical Chemistry, Slovak Technical University, CS-812 37 Bratislava, Czechoslovakia 相似文献
42.
Celik Tarimci Anda? Karamustafa Kutalmi? Güven Mehmet Kabak Akgül Ye?ilada 《Analytical sciences》2003,19(9):1347-1348
The crystal structure of 1-[3-(3,4-dimethoxyphenyl)-2-propenoyl]pyrrolidine (C15H19NO3) (I) has been determined by X-ray analysis. It crystallizes orthorhombic space group Pbca with a = 24.295(3), b = 15.086(3), c = 7.552(3)A, V = 2768(1)A3, Z = 8, Dcalc = 1.254 g/cm3, mu = (Mo K(alpha)) = 0.87 cm(-1). The title compound has analgesic activity of cycloaliphatic amine part. The molecule is deviated from planar configuration. 相似文献
43.
Lubomír Kubáček 《Mathematica Slovaca》2007,57(6):571-588
The multivariate model, where not only parameters of the mean value of the observation matrix, but also some other parameters
occur in constraints, is considered in the paper. Some basic inference is presented under the condition that the covariance
matrix is either unknown, or partially unknown, or known.
Supported by the grant of the Council of Czech Republic MSM 6 198 959 214. 相似文献
44.
We introduce and investigate the properties of Hochschild cohomology of algebras in an abelian monoidal category M. We show that the second Hochschild cohomology group of an algebra in M classifies extensions of A up to an equivalence. We characterize algebras of Hochschild dimension 0 (separable algebras), and of Hochschild dimension ≤1 (formally smooth algebras). Several particular cases and applications are included in the last section of the paper. 相似文献
45.
V. D. Fedotov N. P. Obuchov R. A. Zadikhanov J. Spěváček J. Straka 《Applied magnetic resonance》1993,4(4):491-511
The combined analysis of1H and13C NMR relaxation data in solid lysozyme and some typical homopolypeptides was carried out by using “model-free” approach. Three types of relaxation transitions (γ’, γ and β) were revealed in the temperature range investigated. The microdynamical parameters of these motions were determined. From the comparison of these parameters with those of selected synthetic polymers it follows that the molecular motions in proteins and synthetic polymers are of the same nature. All these motions show pronounced anisotropic character. In the investigated temperature range no molecular motions corresponding to α-relaxation (liquid-like) transition were revealed. The hydration effects on parameters of the motions in proteins were considered. The most pronounced effect takes place for β-transition. The effect of Brownian rotation of protein molecule in solution on measured correlation function of local motions was also discussed. 相似文献
46.
Given disjoint setsP
1,P
2, ...,P
d
inR
d
withn points in total, ahamsandwich cut is a hyperplane that simultaneously bisects theP
i
. We present algorithms for finding ham-sandwich cuts in every dimensiond>1. Whend=2, the algorithm is optimal, having complexityO(n). For dimensiond>2, the bound on the running time is proportional to the worst-case time needed for constructing a level in an arrangement
ofn hyperplanes in dimensiond−1. This, in turn, is related to the number ofk-sets inR
d−1
. With the current estimates, we get complexity close toO(n
3/2
) ford=3, roughlyO(n
8/3
) ford=4, andO(n
d−1−a(d)
) for somea(d)>0 (going to zero asd increases) for largerd. We also give a linear-time algorithm for ham-sandwich cuts inR
3 when the three sets are suitably separated.
A preliminary version of the results of this paper appeared in [16] and [17]. Part of this research by J. Matoušek was done
while he was visiting the School of Mathematics, Georgia Institute of Technology, Atlanta, and part of his work on this paper
was supported by a Humboldt Research Fellowship. W. Steiger expresses gratitude to the NSF DIMACS Center at Rutgers, and his
research was supported in part by NSF Grants CCR-8902522 and CCR-9111491. 相似文献
47.
P E S?rensen R A McClelland R D Gandour 《Acta chemica Scandinavica (Copenhagen, Denmark : 1989)》1991,45(6):558-566
The ring-chain tautomerism in aqueous solution of some aryl-substituted morpholinium salts (bromides), has been studied and equilibrium constants are reported. In the crystals the substrates exist entirely in their cyclic forms as hemiacetals, but in aqueous solution NMR measurements reveal that an equilibrium is established between the cyclic (hemiacetal) and the noncyclic (ketone) form, the degree of ring-opening being more pronounced with electron-donating aryl substituents at the carbonyl carbon. The kinetics of the ring-chain interconversion in water has been investigated spectrophotometrically by a 'pH jump' stopped-flow technique. General base catalysis is observed with a Br?nsted beta value apparently independent of substituent and equal to 0.60. The Hammett rho values for various base catalysts are close to those for very similar intermolecular reactions involving hemiacetal breakdown, leading to the suggestion of a 'normal' class n mechanism for base catalysis. For acid catalysis, however, a quite different situation is encountered, since no general acid but only (weak) catalysis by the hydronium ion can be detected. We believe this deviation from 'normal' general acid catalysis is caused by an electrostatic interaction, and we suggest that it might result from a change in the usual class e mechanism for general acid catalysis by a situation in which rate-limiting concerted proton transfer is replaced by rate-limiting preprotonation. This is supported by the observed drastic change in Hammett rho value for catalysis by the hydronium ion, compared with the 'normal' case. An interesting case is encountered for the 4-aminophenyl-substituted substrate, in which the amino group becomes protonated in acid solution, thus representing a new substituent. Despite this complication, the various equilibrium and rate constants may also be evaluated experimentally for this substrate. 相似文献
48.
49.
F. Cannata J. P. Dedonder L. Le?niak 《Zeitschrift für Physik A Hadrons and Nuclei》1992,343(4):451-460
We investigate the origin of the attraction in theK¯K channel around the threshold by introducing an additional channel to theππ andK¯K channels in a separable potential formalism assuming, in general, no direct interaction in theK¯K channel. To reproduce the features of the data, we find that the threshold of the additional channel is much above thef 0(975) meson position. We show that this three-channel problem can be reduced to an effective two-channel problem where thef 0(975) behaves as if it were aK¯K molecule bound by the coupling to the exotic channel. This picture is also supported by the fact that a single pole only, in the complexK¯K momentum plane, is associated to thef 0(975) meson. Various physical observables, like the decay branching ratio and theK¯K scattering length, are then discussed in an effective two-channel framework. 相似文献
50.
Dorota G?azowska Janusz Matkowski 《Journal of Mathematical Analysis and Applications》2007,331(2):1187-1199
The invariance of the geometric mean G with respect to the Lagrangian mean-type mapping (Lf,Lg), i.e. the equation G○(Lf,Lg)=G, is considered. We show that the functions f and g must be of high class regularity. This fact allows to reduce the problem to a differential equation and determine the second derivatives of the generators f and g. 相似文献