High pressure infiltration sintering behavior of WC-Co alloys

In this paper, two average tungsten carbide particle sizes of 2, 0.5?μm are placed respectively, in contact with a WC-16Co substrate, pressed at the pressure of 4.5–5.5?GPa, and heated to temperatures ranging from 1350°C to 1500°C in a large-volume cubic press. During the process Co was forced out of the WC-16Co substrate into the compressed powder. The resulting infiltrated samples were characterized using X-ray diffraction (XRD), scanning electron microscope (SEM), Vickers hardness and cutting performance tests. The results of XRD confirmed that the sintered bulks have WC and Co phases. The scanning electron microscopy (SEM) analysis reveals that the WC grains in well-sintered alloys are round in shape and cobalt with lower content is uniformly dispersed in the WC grain boundaries. The sintered sub-micron WC-Co alloy with a cobalt content of 3.8?wt% exhibits a prominent combination of high hardness value of 23.1?GPa and a large fracture toughness value of 8.6?MPa?m^½. The high-speed cutting tests indicating its cutting performance is significantly superior to the commercial YG6X (WC-6?wt%Co with WC grain size of 0.5?μm).     

非均匀介质对强激光传播的影响

以强激光应用在化学工程中所遇到的物理问题为背景，研究介质的热透镜效应、吸收强弱、吸收饱和程度以及介质的流动等因素对激光传播的影响。根据一组简化模型，提出了描述光场行为的方程组，给出了不同情况下介质的温度分布情况、光线在介质中的变化行为以及激光光强的分布化情况。所得结果，对光化学工程设计有一定的参考价值。     

抚顺页岩油的高分辨核磁共振研究

用高分辨液体核磁共振氢谱、碳谱、二维碳氢相关谱和DEPT谱(无畸变极化转移增强法)对我国抚顺页岩油的不同组分进行了详细研究,得出了一些结构信息和变化规律。     

用有效折射率／有限元法设计1．55μmTi：LiNbO_3单模条波导及其方向耦合器

应用有效折射率／有限元法（ＥＩ－ＦＥＭ），考虑到ＬｉＮｂＯ３晶体和Ｔｉ扩散的各向异性，折射率增量与寻常光、非寻常光及波长色散的关系，设计了１．５５μｍ光波长下工作的ｚ切ｙ传播Ｔｉ：ＬｉＮｂＯ３单模条波导的制备参数，计算和分析了其单模特性、模式场分布及其变化规律．扩展了ＥＩ－ＦＥＭ，将其用于求解耦合波导系统，确定了方向耦合器的耦合长度及其波长色散特性．     

Influence of the phase coherence length on ballistic transport

The characteristic length scales for the transport in disordered metals are discussed. Based on a phenomenological model of phase randomising scattering processes, the influence of the phase coherence length on the conductance of ballistic systems is studied. It is argued that the frequency dependence of the conductance of quasi-one dimensional systems can be used in order to determine not only the statistical average but the whole distribution function of the phase coherence length. Various cases of distributions, the -function, the exponential, and the Gamma distribution, are discussed. It is shown that due to quantum coherence effects deviations from the classical (Drude) behavior of the conductance exist. For independent scattering processes the probability distribution function is given by the Poisson distribution function. In this case an expression for the conductance can be derived which contains the ballistic transport, and the result for the exponential distribution.     

平行共轴线圈的磁场特征研究与实验设计

通过计算机及相关的传感器和数据采集接口辅助,研究了平行共轴双线圈间距分别为0.5R,R,1.5R时,轴线方向磁场强度的分布规律及特征.从平行共轴双线圈间距为R的亥姆霍兹线圈所形成的均匀磁场出发,结合理论推导,自己设计并组装了三线圈实验装置,实现了平行共轴三线圈均匀磁场区域扩大、强度增强的实验设计,在一定程度上弥补了传统亥姆霍兹线圈磁场测量的不足并有助于对其深入的理解和研究.     

先位粉末套管法制备MgB2/Fe线材的超导性能研究

采用先位法将MgB2粉装入纯铁管中,制备出MgB2/Fe超导线材.用X射线衍射仪和扫描电子显微镜分析了样品的物相组成和显微结构;用SQUID测量了样品的超导转变温度;用标准四引线法测量了短样的临界电流.结果显示,超导样品的临界转变温度约为38.3 K,在4.2 K/4 T下MgB2/Fe线材的临界电流密度为～104A/cm2.研究结果表明,高温退火有效地减少了冷加工过程中产生的应力,改善了晶粒连接性,提高了芯材的致密度,可以显著地提高先位法制备线材的临界电流密度.     

Effect of Surface Structure of Nano-CaCO3 Particles on Mechanical and Rheological Properties of PVC Composites

To study the effect of different surface structures on resultant mechanical and rheological properties, nano-CaCO₃ particles were treated with isopropyl tri-stearyl titanate (H928), isopropyl tri-(dodecylbenz-enesulfonyl) titanate (JN198), and isopropyl tri-(dioctylpyrophosphato) titanate (JN114). Scanning electron microscopy (SEM) and dynamic mechanic analysis (DMA), carried out to characterize the effective interfacial interaction between the nano-CaCO₃ particles and a poly(vinyl chloride) (PVC) matrix, indicated that JN114 treated nano-CaCO₃ particles had the strongest interfacial interaction with a PVC matrix, while H928 treated nano-CaCO₃ had the weakest. The rheological and mechanical properties of PVC/nano-CaCO₃ composites were investigated as a function of surface structure and filler volume fraction. The tensile yield stress and elongation at break decreased with the increasing of calcium carbonate content while tensile modulus increased. PVC filled with JN114 treated nano-CaCO₃ had the highest tensile modulus and tensile yield stress, while those filled with H928 treated nano-CaCO₃ had the highest elongation at break at the same filler content. The impact strength of PVC/nano-CaCO₃ composites increased with the increasing of CaCO₃ content, and PVC composites filled with JN198 treated nano-CaCO₃ particle had a higher impact strength than those with JN114 or H928 treated, with the value reaching 23.9 ± 0.7 kJ/m² at 11 vol% CaCO₃, four times as high as that of pure PVC. Rheological properties indicated that a suitable interfacial interaction and a good dispersion of inorganic filler in a PVC matrix could reduce the viscosity of PVC/nano-CaCO₃ composites. The interfacial interaction was quantitatively characterized by semiempirical parameters calculated from the tensile strength of PVC/nano-CaCO₃ composites to confirm the results from the SEM and DMA experiments.     

Crystallization,Flame Retardancy and Mechanical Properties of Poly(Butylene Terephthalate)/Brominated Epoxy/Nano-Sb2O3 Composites Dispersed By High Energy Ball Milling

Nano-Sb2O3 particles and brominated epoxy resin (BEO) powders were dispersed in poly (butylene terephthalate) (PBT) by high energy ball milling (HEBM). Then the nanocomposites were prepared by a twin screw extruder. The influence of the nano-Sb2O3 particles on the crystallization, thermal stability, flame retardancy and mechanical properties of the PBT/BEO/nano-Sb2O3 composites were investigated by X-ray diffraction (XRD), differential scanning calorimetry (DSC), thermogravimetric analysis (TGA), limiting oxygen index (LOI), UL-94 tests and scanning electron microscopy (SEM). The results showed that the nano-Sb2O3 particles improved the crystallizability, thermal stability and flame retardancy properties of the PBT/BEO/nano-Sb2O3 composites. When the content of nano-Sb2O3 particles was 2.0?wt%, the LOI of nano-Sb2O3/BEO/PBT composites increased from 22.0 to 27.8 and the tensile strength reached its maximum value (62.44?MPa), which indicated that the optimum value of flame retardancy and mechanical properties of PBT/BEO/nano-Sb2O3 composites were obtained.