全文获取类型
收费全文 | 1488篇 |
免费 | 215篇 |
国内免费 | 287篇 |
专业分类
化学 | 1202篇 |
晶体学 | 9篇 |
力学 | 96篇 |
综合类 | 20篇 |
数学 | 282篇 |
物理学 | 381篇 |
出版年
2024年 | 3篇 |
2023年 | 12篇 |
2022年 | 24篇 |
2021年 | 42篇 |
2020年 | 39篇 |
2019年 | 36篇 |
2018年 | 48篇 |
2017年 | 26篇 |
2016年 | 64篇 |
2015年 | 51篇 |
2014年 | 87篇 |
2013年 | 108篇 |
2012年 | 113篇 |
2011年 | 103篇 |
2010年 | 97篇 |
2009年 | 85篇 |
2008年 | 100篇 |
2007年 | 80篇 |
2006年 | 82篇 |
2005年 | 99篇 |
2004年 | 95篇 |
2003年 | 86篇 |
2002年 | 113篇 |
2001年 | 117篇 |
2000年 | 48篇 |
1999年 | 38篇 |
1998年 | 38篇 |
1997年 | 17篇 |
1996年 | 24篇 |
1995年 | 11篇 |
1994年 | 12篇 |
1993年 | 8篇 |
1992年 | 16篇 |
1991年 | 10篇 |
1990年 | 16篇 |
1989年 | 9篇 |
1988年 | 5篇 |
1987年 | 5篇 |
1986年 | 6篇 |
1985年 | 9篇 |
1984年 | 1篇 |
1983年 | 2篇 |
1982年 | 2篇 |
1981年 | 1篇 |
1980年 | 1篇 |
1936年 | 1篇 |
排序方式: 共有1990条查询结果,搜索用时 15 毫秒
1.
Peng-Yan Gui Xiao-Hui Yan Wen-Juan Yuan Yuan-Liang Ma Xiao Ding Shuai Liu 《Natural product research》2019,33(19):2830-2836
A new A, D-seco limonoid, named 12-acetyloxyperforatin (1), along with three known ones, were isolated from the leaves of Harrisonia perforata. Their structures were elucidated on the basis of spectroscopic analysis, including extensive NMR techniques and computational modelling. These compounds showed no inhibitory activity against the 11β-HSD1 enzyme. 相似文献
2.
3.
4.
5.
模糊关系矩阵传递闭包的Warshall算法 总被引:8,自引:2,他引:6
通过对照关系的传递闭包和模糊关系的传递闭包,把求关系矩阵的传递闭包的算法完整地推广到模糊关系矩阵上。 相似文献
6.
We investigate the two methods of defining the surface gravity ,κ on the horizon, which are the metric definition and the definition given by the spacetime conformal method. It is found that the latter is of greater generality. By this method, we find that ,κ of η- ξ spacetime is equal to the exponent factor α in the coordinate transformation, which confirms the argument that η- ξ spacetime can be considered as the background spacetime for finitetemperature field theories. The reasons why the metric definition of ,κ can not be applied in η- ξ spacetime are presented. 相似文献
7.
Xin‐Gui Li Run‐Feng Chen Mei‐Rong Huang Mei‐Fang Zhu Qun Chen 《Journal of polymer science. Part A, Polymer chemistry》2004,42(9):2073-2092
A new series of copolymers was synthesized through the oxidative polymerization of pyrrole (PY) and o‐phenetidine (PHT) with inorganic oxidants in acidic media. The polymerization parameters including the mixing method of the oxidant with the comonomer, the comonomer ratio, the time, the temperature, the oxidant, the organic medium, and the acid were systematically optimized for the synthesis of copolymers with high yields, intrinsic viscosities, and solubility. The resultant copolymers were characterized by elemental analysis, infrared, ultraviolet–visible, solution high‐resolution 1H NMR and solid‐state high‐resolution 13C NMR, circular dichroism spectroscopy, and cyclic voltammetry. The results showed that the PY observed content in the copolymers was much higher than the PY feed content. The regular variation of the polymerization yield, intrinsic viscosity, solubility, macromolecular structure, and electroactivity of the resulting polymers with the comonomer ratio, together with the complete solubility of a PY/PHT (10/90) polymer in highly polar solvents, indicated the formation of real random copolymers containing both PY and PHT units rather than a mixture of two homopolymers. However, the polymers containing more than 59 mol % PY were not homogeneous copolymers consisting of soluble and insoluble parts. A semiquantitative relationship between the polymerization yield or solubility of the copolymers and the polarity index of the organic solvents was examined. © 2004 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 42: 2073–2092, 2004 相似文献
8.
Gui Hong YAN Da XING* Shi Ci TAN Institute of Laser Life Science South China Normal University Guangzhou 《中国化学快报》2004,15(1):101-104
Electrochemiluminescence (ECL), like other chemiluminescence technique, offers high signal-to-noise ratio. Furthermore, it has the advantage over other chemiluminescence techniques of being initiated by a voltage potential. Thus, it provides a better-controlled luminescence. This technique has been used in measuring many kinds of organic and inorganic matters, and analyzing many kinds of antigen, antibody and hapten, such as carcinoembryonic antigen and alpha-fetoprotein, etc1-6. The ele… 相似文献
9.
10.
红外光谱对碱土金属二元羧酸盐结构的研究 总被引:16,自引:2,他引:14
研究了三十种二元羧酸金属盐的红外光谱,讨论了金属离子和二元酸的种类对二元酸盐配位结构的影响。发现Mg盐、Ba盐,Sr盐为螯合配位,Ca盐,Zn盐中同时存在螯合配位和桥式配位,二元酸的种类对羧酸盐配位结构没有影响。对羧酸盐在常温和熔融后的栩位方式和结构上的差异的研究结果表明,Mg盐,Ca盐与Sr盐,Ba盐在熔融后的结构变化不同。 相似文献