纠缠态与反聚束效应

纠缠和非经典效应是经典理论所不能解释的非经典现象，两者是否具有关系引起了人们的研究兴趣，已有的研究表明：纠缠和压缩存在着一定关系，有压缩时存在着纠缠，但有纠缠时不一定存在着压缩。但纠缠是否与反聚束效应有关还未研究。本文主要研究了两种形式的纠缠相干态，通过concurrence的方法计算它们的纠缠度、压缩效应和反聚束效应。通过数值计算可以发现一个有意思的现象：这两种形式的纠缠相干态，在适当的条件下，有压缩效应时，没有反聚束效应，有反聚束效应时，没有压缩效应，特别是第二种形式的纠缠相干态，纠缠的大小分别与压缩效应和反聚束效应的强弱存在着一一对应的关系。     

Er~(3+)/Tm~(3+)共掺铋硅酸盐玻璃2.0μm光谱性质（英文）

用高温熔融法制备了Er~(3+)/Tm~(3+)共掺杂无铅铋硅酸盐玻璃.测试了玻璃的吸收光谱和荧光光谱,分析和表征了Er~(3+)、Tm~(3+)离子之间的能量传递机制和传递效率,结果表明:在800 nm和1 550 nm光源泵浦下,Er~(3+)的掺入能够增强Tm~(3+)离子1.8μm发光,相应的最大发射截面分别为6.7×10~(-21)cm~2和7.3×10~(-21)cm~2,荧光带宽达到250 nm.根据Dexter-Foster模型,得到Er~(3+):~4I_(13/2)能级到Tm~(3+):~3F_4能级的直接能量传递系数为16.8×10~(-40)cm~6/s,为1 550 nm泵浦下获得较强的1.8μm发光奠定了基础.     

Single- and multi-shot laser-induced damages of Ta_2O_5/SiO_2 dielectric mirrors at 1064 nm

Ta2O5/SiO2 dielectric mirrors deposited by ion beam sputtering (IBS) are studied. The multi-shot laserinduced damage threshold (LIDT) and its dependence on the number of shots are investigated, after which we find that the multi-shot LIDT is lower than that of single-shot. The accumulation effects of defects play an important role in the multi-shot laser damage. A simple model, which includes the conduction band electron production vsa multiphoton and impact ionizations, is presented to explain the experimental phenomena.     

1-环丙基-6-氟-7-(4-酰基-1-哌嗪基)-1,4-二氢-4-氧代喹啉-3-羧酸的合成及其抗菌活性研究

以1-环丙基-6-氟-7-氯-1, 4-二氢-4-氧代喹啉-3-羧酸为原料经过两步反应合成出了16个新的1-环丙基-6-氟-7-(4-酰基-1-哌嗪基)-1, 4-二氢-4-氧代喹啉-3-羧酸, 并利用IR, ¹H NMR, ¹³C NMR, MS谱及元素分析对其结构进行了表征. 初步体外抗菌活性研究表明, 大部分目标化合物对大肠杆菌有一定的抑菌活性, MIC值在0.312～20 g/mL之间, 但活性低于对照物环丙沙星和氧氟沙星; 目标化合物对绿脓杆菌无抑菌活性, 最低抑菌浓度(MIC)均大于20 g/mL.     

铋化物发光玻璃中银表面等离激元对铒离子的发光增强作用

局域表面等离激元可以由自由空间的光直接激发,这也是局域表面等离激元的优点所在。研究铋化物发光玻璃中纳米银颗粒的表面等离激元对铒离子发光的增强效应、进一步的提高铋化物发光玻璃中铒离子的发光性能很有意义。首先,测量了(A)Er 3+(0.5%)Ag(0.5%):铋化物发光玻璃与(B)Er 3+(0.5%):铋化物发光玻璃样品的吸收谱,发现(A)Er 3+(0.5%)Ag(0.5%):铋化物发光玻璃在约600.0 nm处有一个较弱的宽的银表面等离激元共振吸收峰。同时发现两者都有典型的铒离子的吸收峰,它们的吸收几乎完全一样:在波峰形状、峰值强度和峰值波长等方面都很相近。测量了(A)Er 3+(0.5%)Ag(0.5%):铋化物发光玻璃和(B)Er 3+(0.5%):铋化物发光玻璃样品的激发谱,发现有位于379.0,406.0,451.0,488.0和520.5 nm的5个550.0 nm可见光的可见激发谱峰,和位于379.0,406.5,451.0,488.5,520.5,544.0,651.5和798.0 nm的8个1531.0 nm红外光的红外激发谱峰,容易指认出依次为Er 3+的4I 15/2→4G 11/2,4I 15/2→2H 9/2,4I 15/2→(4F 3/2,4F 5/2),4I 15/2→4F 7/2,4I 15/2→2H 11/2,4I 15/2→4S 3/2,4I 15/2→4F 9/2和4I 15/2→4I 9/2跃迁的吸收峰,通过测量发现(A)Er 3+(0.5%)Ag(0.5%):铋化物发光玻璃相对于(B)Er 3+(0.5%):铋化物发光玻璃样品的可见和红外激发谱的最大增强依次分别是238%和133%。最后,测量了它们的发光谱,发现有位于534.0,547.5和658.5 nm的三组可见发光峰,容易指认出依次为Er 3+的2H 11/2→4I 15/2,4S 3/2→4I 15/2,4F 9/2→4I 15/2荧光跃迁。还发现红外发光峰位于978.0和1531.0 nm,依次为Er 3+的4I 11/2→4I 15/2和4I 13/2→4I 15/2的荧光跃迁。通过测量发现(A)Er 3+(0.5%)Ag(0.5%):铋化物发光玻璃相对于(B)Er 3+(0.5%):铋化物发光玻璃样品的可见和红外发光谱的最大增强依次分别是215%和138%。对于银表面等离激元增强铒离子发光的机理,认为主要为纳米银颗粒的局域表面等离激元共振,造成金属纳米结构附近产生的局域电场的强度要远大于入射光的电场强度,从而导致了金属纳米结构对入射光产生强烈的吸收和散射,进而导致了荧光的增强;即局域表面等离子体共振局域场的场增强效应。     

Comparative Molecular Field Analysis （CoMFA） of Curcumin-related Compounds for Anticancer Activity

Three-dimensional （3D） quantitative structure-activity relationship （QSAR） studies of 44 curcumin-related compounds have been carried out based on our previously reported result for their anticancer activity against pancreas cancer Panc-I cells and colon cancer HT-29 cells. The established 3D-QSAR models from the comparative molecular field analysis （CoMFA） in training set showed not only significant statistical quality, but also satisfying predictive ability, with high correlation coefficient values （R12= 0.911, R22= 0.985） and cross-validation coefficient values （q2= 0.580, q22= 0.722）. Based on the CoMFA contour maps, some key structural factors responsible for anticancer activity of these series of compounds were revealed. The results provide some useful theoretical references for understanding the mechanism of action, designing new curcumin-related compounds with anticancer activity and predicting their activities prior to synthesis.     

Strain Induced Insulator-Metal Transition in Single Wall Carbon Nanotubes

In terms of a single-π orbital model, an analytical expression of the lowest-lying conduction-band and the highestlying valence-band is derived for single wall carbon nanotubes under both the uniaxial and torsional strains. We observe not only semiconductor-metal transitions in primary metallic tubes, but also insulator-metal transitions     

Accumulation effect of SiO_2 protective layer on multi-shot laser-induced damage in high-reflectivity HfO_2/SiO_2 coatings

The accumulation effects in high-reflectivity(HR) HfO2/SiO2 coatings under laser irradiation are investigated.The HR HfO2/SiO2 coatings are prepared by electron beam evaporation at 1 064 nm.The laser-induced damage threshold(LIDT) are measured at 1 064 nm and at a pulse duration of 12 ns,in 1-on-1 and S-on-1 modes.Multi-shot LIDT is lower than single-shot LIDT.The laser-induced and native defects play an important role in the multi-shot mode.A correlative theory model based on critical conduction band electron density is constructed to elucidate the experimental phenomena.     

激光脉冲能量对激光烧蚀保护气体电离的影响

用Ar气作保护气体 ,气压保持在一个标准大气压 ,用Nd :YAG脉冲激光烧蚀Al靶获得等离子体。利用时空分辨技术 ,采集了激光脉冲能量在 5 2 ,92 ,115和 14 5mJ情况下等离子体辐射的时空分辨谱。详细描述了 115mJ时等离子体的辐射特征 ,简要分析了其他脉冲能量下Ar的特征辐射规律。根据这些脉冲能量下Ar 特征谱线的分布规律 ,简要论述了Ar气体电离与激光脉冲能量的关系。讨论了环境气体电离机制 ,并对结果进行了简单解释。结果发现 ,在本实验采用的能量范围内 ,较高的脉冲能量更容易使环境气体电离 ,产生较强的Ar 离子辐射 ,且Ar 辐射持续时间较长。     

X射线自由电子激光在物理学中的应用

在原子/分子空间尺度直接探测微观世界的飞秒量级动态复杂过程一直是科学家追求的梦想。2009年,X射线自由电子激光装置的出现使得这个梦想成为可能。文章将介绍近年来利用X射线自由电子激光装置在凝聚态物理、非线性光学、高压物理等研究领域取得的一些突破性进展,并展望其未来在解决重大物理问题中的可能应用。