Acoustic waves of GaN nitride nanowires

Acoustic waves of GaN nanowires are studied. The materials have a wurtzite structure and thus the elastic anisotropy is included. We use the xyz-algorithm originally employed in the analysis of resonant ultrasound spectroscopy results. We have considered hexagonal cross-section nanowires as those experimentally grown. We have studied also circular cross-section nanowires (nanotubes) for comparison. It was found that the lower frequency modes have a very similar dispersion relation both in shape and frequency value, but higher frequency modes exhibit more important differences. The nanowires are solid or hollow and the influence of the thickness on the dispersion relation and the elastic displacement pattern is considered. Nanowires with a zinc-blende structure have also been considered because of theoretical studies allowing for their existence. We have studied also the squared displacement vectors to see the spatial distribution of the different modes in the nanowires. It was found that there are many modes whose elastic displacement components concentrate around the borders of the nanowire and they do not penetrate almost in the inner part of the nanowire.     

Carbon nanotube-carbon black hybrid counter electrodes for dye-sensitized solar cells and the effect on charge transfer kinetics

In this work, the catalytic activity of carbon nanotubes (CNTs), carbon black (CB), and CNT-CB counter electrodes in the I⁻/I₃⁻ reduction reaction is reported and compared with the Pt counter electrode. The fabricated counter electrodes were evaluated in dye-sensitized solar cells (DSSCs). The results indicate that the best cathodes were made from CNT₁₀ (240 μm) and CB with a charge transfer resistance (R_CT) of 2.70 Ω, and when the complete device shows 19.83 Ω of internal series resistance (R_S), the photovoltaic parameters of these cells were J_SC = 10.47 mA cm⁻²; V_OC = 0.70 V; and FF = 57.90, with an efficiency of 4.29%, indicating a better interaction between the CNT₁₀ in the 3D network of the counter electrode, generating a good charge transfer kinetics, in comparison with only CNT₁₀ or CB.

     

Determination of amino acids in apple extracts by high performance liquid chromatography

Summary A rapid and sensitive method for the simultaneous determination of primary amino acids in apple is described. After sample preparation, amino acids were derivatized with o-phthaldialdehyde/2-mercaptoethanol and separated on a reversed phase column with a gradient of phosphate buffer-tetrahydrofuran-methanol as the mobile phase. Detection was carried out with a fluorescence detector at excitation and emission wavelengths of 340 nm and 425 nm respectively. Recovery studies showed good results for all substances (91–109%) (with coefficients of variation ranging, from 0.1 to 9.0%). This method was applied to the monitoring of amino acids during the ripening of apples.     

Imaginary quadratic function fields

In Bautista-Ancona and Diaz-Vargas (2006) [B-D] a characterization and complete listing is given of the imaginary quadratic extensions K of k(x), where k is a finite field, in which the ideal class group has exponent two and the infinite prime of k(x) ramifies. The objective of this work is to give a characterization and list of these kind of extensions but now considering the case in which the infinite prime of k(x) is inert in K. Thus, we get all the imaginary quadratic extensions of k(x), in which the ideal class group has exponent two.     

The Relationship Between Various Filter Notions on aGL-Monoid

The notion of a generalised filter is extended to the setting of aGL-monoid. It is shown that there exists a one-to-one correspondence between the collection of generalised filters on a setXand the collection of strongly stratifiedL-filters onX. Specialising to the case whereLis the closed unit interval [0, c] viewed as a Heyting algebra, we show that any strongly stratified [0, c]-filter onXcan be uniquely identified with a saturated filter onI^Xwith characteristic valuec. In this way, the notion of a generalised filter unifies various filter notions. In particular, necessity measures and finitely additive probability measures are specific examples of generalised filters.