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E. Best W. Mosch D. Koschel G. W. Wolf W. Schermann K. -H. König W. Brügel H. Schmidkunz W. Ried P. Kratochvíl P. Zuman K. H. Bloss R. Hähnel R. Jaenicke 《Colloid and polymer science》1970,239(1):618-628
Ohne Zusammenfassung 相似文献
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Pascual JI Bihlmayer G Koroteev YM Rust HP Ceballos G Hansmann M Horn K Chulkov EV Blügel S Echenique PM Hofmann P 《Physical review letters》2004,93(19):196802
Quasiparticle interference patterns measured by scanning tunneling microscopy can be used to study the local electronic structure of metal surfaces and high-temperature superconductors. Here, we show that even in nonmagnetic systems the spin of the quasiparticles can have a profound effect on the interference patterns. On Bi(110), where the surface state bands are not spin degenerate, the patterns are not related to the dispersion of the electronic states in a simple way. In fact, the features which are expected for the spin-independent situation are absent and the observed interference patterns can be interpreted only by taking spin-conserving scattering events into account. 相似文献
106.
Molecularly imprinted microparticles for capillary electrochromatography: studies on microparticle synthesis and electrolyte composition. 总被引:1,自引:0,他引:1
The use of molecularly imprinted polymer (MIP) microparticles in a partial filling application of capillary electrochromatography (CEC) has previously been shown successful for the enantiomer separation of propranolol. In this investigation, the influence of some important parameters in the preparation protocol, i.e., template to monomer ratio, type of cross-linker and functional monomers, and the effect of separation condition, i.e., organic modifier content, pH and the temperature of the column, on the electrochromatographic behavior of the MIP microparticles were studied. It was found that ethyleneglycol dimethacrylate (EDMA), having two reactive double bonds, was superior in terms CEC performance to trimethylpropane trimethacrylate (TRIM) and pentaerythritol tetraacrylate (PETEA) having three and four double bonds, respectively. The use of weak functional monomers, i.e., monomers lacking a strong interaction with the template, was shown to increase the separation efficiency. It was found that the template to functional monomer ratio had a pronounced influence on the MIP microparticle partial filling CEC performance as well as the size of the obtained microparticles. The use of a partial filling technique realizes the use of a new MIP phase in every new separation as well as the ability of altering the selectivity of the separation column and length of the MIP without the need for column switching. 相似文献
107.
Relaxation of Small Molecules: an ab initio Study 总被引:6,自引:0,他引:6
The formation mechanism for the equilateral triangle structure of the He3^ cluster is proposed.The curve of the total energy versus the internuclear distance R for this structure has been caclulated by the method of a modified arrangement channel quantum mechanics,The result shows that the curve has a minimal -7.81373 a.u.at R=1.55 a0. The binding energy of He3^ with respect to He He^ He was calculated to be 0.1064 a.u.(about 2.89 eV).This means that the He3^ cluster may be formed in the equilateral triangle structure stable by the interaction of He^ with two helium atoms. 相似文献
108.
Weischenberg J Freimuth F Sinova J Blügel S Mokrousov Y 《Physical review letters》2011,107(10):106601
We report on first-principles calculations of the side-jump contribution to the anomalous Hall conductivity (AHC) directly from the electronic structure of a perfect crystal. We implemented our approach for a short-range scattering disorder model within the density functional theory and computed the full scattering-independent AHC in elemental bcc Fe, hcp Co, fcc Ni, and L1(0) FePd and FePt alloys. The full AHC thus calculated agrees systematically with experiment to a degree unattainable so far, correctly capturing the previously missing elements of side-jump contributions, hence paving the way to a truly predictive theory of the anomalous Hall effect and turning it from a characterization tool to a probing tool of multiband complex electronic band structures. 相似文献
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The shear rheology of adsorbed or spread layers at air/liquid and liquid/liquid phase boundaries is relevant in a wide range of technical applications such as mass transfer, monolayers, foaming, emulsification, oil recovery, or high speed coating. Interfacial shear rheological properties can provide important information about interactions and molecular structure in the interfacial layer. A variety of measuring techniques have been proposed in the literature to measure interfacial shear rheological properties and have been applied to pure protein or mixed protein adsorption layers at air/water or oil/water interfaces. Such systems play for example an important role as stabilizers in foams and emulsions. The aim of this contribution is to give a literature overview of interfacial shear rheological studies of pure protein and protein/surfactant mixtures at liquid interfaces measured with different techniques. Techniques which utilize the damping of waves, spectroscopic or AFM techniques and all micro-rheological techniques will not discuss here. 相似文献