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101.
Characterizations of self-combustion reactions (SCR) for the production of nanomaterials used as advanced cathodes in Li-ion batteries 总被引:1,自引:0,他引:1
Ortal Haik Surendra K. Martha Hadar Sclar Zvi Samuk-Fromovich Ella Zinigrad Boris Markovsky Daniela Kovacheva Nikolay Saliyski Doron Aurbach 《Thermochimica Acta》2009,493(1-2):96-104
In this work, self-combustion reactions (SCR) for the preparation of important cathode materials for rechargeable Li-ion batteries were investigated by thermal analytical tools (DSC, ARC, TGA), electron microscopy, XRD, various spectroscopies (MS, Raman, FTIR) and elemental analysis by ICP. The systems studied include solutions containing metal nitrates at the right stoichiometry and sucrose as a fuel, for the preparation of LiMn0.5Ni0.5O2 (layered), LiMn1.5Ni0.5O4 (spinel), LiMn0.33Ni0.33Co0.33O2 (layered), and LiMn0.4Ni0.4Co0.2O2 (layered). Similar products, which do not depend on the atmosphere of the processes (air or inert) were obtained by spontaneous SCR and the gradual heating of the same solutions by DSC, ARC, and TGA. The reactions involve the partial caramelization of sucrose, complicated by red-ox reactions with the nitrates that form solid products, whose organic part is finally decomposed around 400 °C. The presence of cobalt ions has a stabilizing effect, which is expressed by the low dissolution rates of Li ions from the solid products thus formed, into aqueous solutions. The reaction mechanisms are discussed herein. 相似文献
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105.
Atsushi Minato Nobuo Sugimoto Zvi Bleier George C. Hunter James Paul 《Optical Review》1995,2(4):319-322
A 50-cm diameter hollow cube-corner retroreflector for a space application was tested with a 60-cm interferometer. To separate the effect of sag due to gravity, the interferograms were taken at six rotational positions, with the retroreflector mounted horizontally. The zero-gravity dihedral angles and the effect of sag were estimated from the interferograms. 相似文献
106.
Zvi Drezner 《The Journal of the Operational Research Society》1985,36(4):333-334
In this paper we present an algorithm for the solution of the minisum location problem on the sphere. The algorithm is finite for the solution within a given accuracy of the optimal solution. 相似文献
107.
Electron-hole pair excitation and ionization probabilities are calculated for atomic collisions with metal surfaces at high incident energies. The method adopted is based on a Sudden Collision Approximation, and a realistic model is employed for the bound and continuum electronic states involved. The parameters used in the calculations are for Ar, He, H atoms impinging on a Li surface at 300 eV. The main results are: (1) Only single electron-hole pair excitations are important; multiple pair contributions are small. (2) The transitions are dominated by the behavior of the electronic wavefunctions in the tunneling region and may serve as a probe of this regime. (3) The excitation efficiency is in the order H ? Ar ? He, the effectiveness of hydrogen being due to its stronger, longer-range coupling. (4) The maximum excitation probabilities are for electrons ejected with relatively low excess energies. (5) Total transition probabilities are about 0.5 per collision for H, and about 0.1 for Ar, indicating that these are important, easily detectable processes. Experiments in this field should provide important information on electronic wavefunctions at the metal-gas interface, and on gas-metal interactions at high energies. 相似文献
108.
In this paper we present a finite horizon single product single machine production problem. Demand rate and all the cost patterns do not change over time. However, end of horizon effects may require production rate adjustments at the beginning of each cycle. It is found that no such adjustments are required. The machine should be operated either at minimum speed (i.e. production rate = demand rate; shortage is not allowed), avoiding the buildup of any inventory, or at maximum speed, building up maximum inventories that are controlled by the optimal production lot size. 相似文献
109.
Zvi Drezner George O. Wesolowsky 《The Journal of the Operational Research Society》1995,46(6):735-746
This paper considers two basic location problems — the Weber problem and the minimax problem-on a regular grid of alternating one-way routes or streets. Both the facility to be located and the demand points are restricted to any point on the network. The one-way restriction is often used for efficiency in traffic flow, but complicates the distances in the system. 相似文献
110.
Zvi Drezner 《Computational Optimization and Applications》1995,4(2):159-165
In this paper we prove that the Classical Gilmore-Lawler lower bound for the quadratic assignment problem is equivalent to a solution of a certain linear programming problem. By adding additional constraints to this linear programming problem we derive a lower bound which is at least as good as the Gilmore-Lawler lower bound.Some of this research was done while the author was on sabbatical leave at the Department of Management, The Hong Kong University of Science and Technology, Kowloon, Hong Kong. 相似文献