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排序方式: 共有161条查询结果,搜索用时 31 毫秒
21.
Dr. Ruofei Cheng Prof. Dr. Zaozao Qiu Prof. Dr. Zuowei Xie 《Chemistry (Weinheim an der Bergstrasse, Germany)》2020,26(32):7212-7218
Iridium-catalyzed formal alkyne hydroboration with cage B−H of o-carborane has been achieved, leading to the controlled synthesis of a series of 3,6-[trans-(AlkCH=CH)]2-o-carboranes (Alk=alkyl), 3-cis-(ArCH=CH)-o-carboranes (Ar=aryl), and 3-cis-(ArCH=CH)-6-trans-(AlkCH=CH)-o-carboranes in high yields with excellent regio- and very good cis–trans selectivity. The most electron-deficient B(3,6)−H vertices favor oxidative addition on electron-rich metal centers, which is responsible for the regioselectivity. On the other hand, the configuration of the resultant olefinic units is dominated by alkyne substituents. Alkyl groups lead to a trans-configuration whereas bulky aryl substitutions result in cis-configuration. 相似文献
22.
Group 4 metallacycles [eta5:sigma-Me2C(C5H4)(C2B10H10)]Ti[eta2-N(Me)CH2CH2N(Me)] (1a), [eta5:sigma-Me2C(C5H4)(C2B10H10)]Zr[eta2-N(Me)CH2CH2N(Me)](HNMe2) (1b) and [eta5:sigma-Me2C(C5H4)(C2B10H10)]M[eta2-N(Me)CH2CH2CH2N(Me)] (M = Ti (2a), Zr (2b), Hf (2c)) were synthesized by reaction of [eta5:sigma-Me2C(C5H4)(C2B10H10)]M(NMe2)(2) (M = Ti, Zr, Hf) with MeNH(CH2)(n)NHMe (n = 2, 3). These metal complexes reacted with unsaturated molecules such as 2,6-Me2C6H3NC, PhNCO and PhCN to give exclusively M-N bond insertion products. The M-C(cage) bond remained intact. Such a preference of M-N over M-C(cage) insertion is suggested to most likely be governed by steric factors, and the mobility of the migratory groups plays no obvious role in the reactions. This work also shows that the insertion of unsaturated molecules into the metallacycles is a useful and effective method for the construction of very large ring systems. 相似文献
23.
Liu D Dang L Sun Y Chan HS Lin Z Xie Z 《Journal of the American Chemical Society》2008,130(47):16103-16110
A hydrogen-mediated Ru-C to Ru-B bond conversion was observed experimentally and supported by the theoretical calculations. Treatment of [eta(5):sigma(C)-Me(2)C(C(5)H(4))(C(2)B(10)H(10))]Ru(COD) (1) bearing a Ru-C(cage) sigma bond with PR(3) in the presence of H(2) gave Ru-B(cage) bonded complexes [eta(5):sigma(B)-Me(2)C(C(5)H(4))(C(2)B(10)H(10))]RuH(2)(PR(3)) (R = Cy (2), Ph (3)) (sigma(C): Ru-C(cage) sigma bond; sigma(B): Ru-B(cage) sigma bond). Complex 3 was converted to [eta(5):sigma(B)-Me(2)C(C(5)H(4))(C(2)B(10)H(10))]Ru(L(2)) in the presence of L(2) (L(2) = dppe (4), PPh(3)/P(OEt)(3) (5), PPh(3)/pyridine (6)) via liberation of H(2) upon heating. These complexes were fully characterized by various spectroscopic techniques, elemental analyses, and single-crystal X-ray diffraction studies. DFT calculations show that this conversion process is both kinetically and thermodynamically favorable and requires involvement of a hydride ligand. 相似文献
24.
Visible‐Light‐Promoted Photocatalytic B−C Coupling via a Boron‐Centered Carboranyl Radical: Facile Synthesis of B(3)‐Arylated o‐Carboranes
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Dr. Da Zhao Prof. Dr. Zuowei Xie 《Angewandte Chemie (International ed. in English)》2016,55(9):3166-3170
A visible‐light‐mediated in situ generation of a boron‐centered carboranyl radical (o‐C2B10H11 . ) has been described. With eosin Y as a photoredox catalyst, 3‐diazonium‐o‐carborane tetrafluoroborate [3‐N2‐o‐C2B10H11][BF4] was converted into the corresponding boron‐centered carboranyl radical intermediate, which can undergo efficient electrophilic substitution reaction with a wide range of (hetero)arenes. This general and simple procedure provides a metal‐free alternative for the synthesis of 3‐(hetero)arylated‐o‐carboranes. 相似文献
25.
26.
We consider the existence of distributional (or L
2
) solutions of the matrix refinement equation
where P is an r×r matrix with trigonometric polynomial entries.
One of the main results of this paper is that the above matrix refinement equation has a compactly supported distributional
solution if and only if the matrix P
(0) has an eigenvalue of the form 2
n
, . A characterization of the existence of L
2
-solutions of the above matrix refinement equation in terms of the mask is also given.
A concept of L
2
-weak stability of a (finite) sequence of function vectors is introduced. In the case when the function vectors are solutions
of a matrix refinement equation, we characterize this weak stability in terms of the mask.
August 1, 1996. Date revised: July 28, 1997. Date accepted: August 12, 1997. 相似文献
27.
28.
Compactly supported (bi)orthogonal wavelets generated by interpolatory refinable functions 总被引:7,自引:0,他引:7
This paper provides several constructions of compactly supported wavelets generated by interpolatory refinable functions.
It was shown in [7] that there is no real compactly supported orthonormal symmetric dyadic refinable function, except the
trivial case; and also shown in [10,18] that there is no compactly supported interpolatory orthonormal dyadic refinable function.
Hence, for the dyadic dilation case, compactly supported wavelets generated by interpolatory refinable functions have to be
biorthogonal wavelets. The key step to construct the biorthogonal wavelets is to construct a compactly supported dual function
for a given interpolatory refinable function. We provide two explicit iterative constructions of such dual functions with
desired regularity. When the dilation factors are larger than 3, we provide several examples of compactly supported interpolatory
orthonormal symmetric refinable functions from a general method. This leads to several examples of orthogonal symmetric (anti‐symmetric)
wavelets generated by interpolatory refinable functions.
This revised version was published online in June 2006 with corrections to the Cover Date. 相似文献
29.
Wang P Liu CR Sun XL Chen SS Li JF Xie Z Tang Y 《Chemical communications (Cambridge, England)》2012,48(2):290-292
A newly designed PE-supported arsine has been developed as an excellent catalyst for catalytic Wittig-type olefination. Simple ketones, in particular inactive ketones prove to be suitable substrates for the first time. This reaction provides an easy access to di-, tri-, and tetra-substituted olefins in high yield. 相似文献
30.