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31.
Jian Zhang Prof. Xiu‐Ling Jiao Dr. Yu‐Guo Xia Fang‐Fang Liu Ying‐Ping Pang Xin‐Fu Zhao Prof. Dai‐Rong Chen 《Chemistry (Weinheim an der Bergstrasse, Germany)》2016,22(27):9321-9329
A facile liquid‐phase exfoliation method to prepare few‐layer FeOCl nanosheets in acetonitrile by ultrasonication is reported. The detailed exfoliation mechanism and generated products were investigated by combining first‐principle calculations and experimental approaches. The similar cleavage energies of FeOCl (340 mJ m?2) and graphite (320 mJ m?2) confirm the experimental exfoliation feasibility. As a Fenton reagent, FeOCl nanosheets showed outstanding properties in the catalytic degradation of phenol in water at room temperature, under neutral pH conditions, and with sunlight irradiation. Apart from the increased surface area of the nanosheets, the surface state change of the nanosheets also plays a key role in improving the catalytic performance. The changes of charge density, density of states (DOS), and valence state of Fe atoms in the exfoliated FeOCl nanosheets versus plates illustrated that surface atomistic relationships made the few‐layer nanosheets higher activity, indicating the exfoliation process of the FeOCl nanosheets also brought about surface state changes. 相似文献
32.
本文从理论上分析了正弦抖动偏频激光陀螺速率阈值特性,提出了一种用于测试抖动偏频激光陀螺速率阈值的试验方案,结果表明激光陀螺在零速率处存在与理论相符合的小死区,动态锁区值与陀螺速率阈值具有确定的对应关系。 相似文献
33.
A scheme for teleporting an arbitrary and unknown three-particle state from a sender to either one of two receivers is proposed. The quantum channel is composed of a two-particle non-maximally entangled state and two three-particle non-maximally entangled W states. An arbitrary three-particle state can be perfectly teleported probabilistically if the sender performs three generalized Bell-state measurements and sends to the two receivers the classical result of these measurements, and either one of the two receivers adopts an appropriate unitary transformation conditioned on the suitable measurement outcomes of the other receiver. All kinds of unitary transformations are given in detail. 相似文献
34.
Scheme for the implementation of 1→3
optimal phase-covariant quantum cloning in ion-trap systems 下载免费PDF全文
This paper proposes a scheme for the implementation of 1→ 3 optimal phase-covariant quantum cloning with trapped ions. In the present protocol, the required time for the whole procedure is short due to the resonant interaction, which is important in view of decoherence. Furthermore, the scheme is feasible based on current technologies. 相似文献
35.
Lithium iron phosphate (LiFePO4) doped with magnesium was hydrothermally synthesized from commercial LiOH, FeSO4, H3PO4 and MgSO4 with glucose as carbon precursor in aqueous solution. The samples were characterized by X-ray powder diffraction, scanning electron microscopy and constant charge-discharge cycling. The results show that the synthesized powders have been in situ coated with carbon precursor produced from caramel reaction of glucose. At ambient temperature (28±2℃), the electrochemical performances of LiFePO4 prepared exhibit the high discharge capacity of 135 mAh g^-1 at 5C and good capacity retention of 98% over 90 cycles. The excellent electrochemical performances should be correlated with the intimate contact between carbon and LiFePO4 primary and secondary particles, resulting from the in situ formation of carbon precursor/carbon, leading to the increase in conductivity of LiFePO4. 相似文献
36.
Ke Xin Huang Yu Bing Feng Wei Yao Lei Xiang Yang Feng Wang Hai Bo Li Su Zeng Jing Xu Gong Ming Hui Hu Yu Zhao Xiu Mei Wu Xiao Kun Li Jia Qu 《中国化学快报》2009,20(10):1187-1190
Four naturally rare 5,6,7-trimethoxy-2,3-cis-dihydroflavonols(3-6) and two 5,6,7-trimethoxy-2,3-trans-dihydroflavonols(7-8) were designed and synthesized.Their antioxidative properties were evaluated by way of examining their scavenging capacities towards DPPH and O_2~(·-) free radicals,as well as by measuring their inhibitory ability against LPO.Both the 2,3-trans and the 2,3- cis conformers exhibited certain quenching abilities to DPPH and O_2~(·-) radicals,while most of the synthetic dihydroflavonols ... 相似文献
37.
运用离子印迹技术,以3-氯丙基三乙氧基硅烷为锚定剂,将功能单体直链聚乙烯亚胺(PEI)接枝在MCM-41分子筛表面,选择镱离子作为模板离子,以环氧氯丙烷交联制备出基于MCM-41表面的镱离子印迹聚合物Yb(Ⅲ)-IIP-PEI/MCM-41,并以同样的方法制备非离子印迹聚合物(NIP-PEI/MCM-41)。 利用傅里叶变换红外光谱仪和扫描电子显微镜等技术手段对Yb3+印迹聚合物进行表征,采用静态吸附法确定了Yb(Ⅲ)-IIP-PEI/MCM-41对Yb3+的最佳吸附条件及选择性吸附性能。 结果表明,Yb(Ⅲ)-IIP-PEI/MCM-41和NIP-PEI/MCM-41的最大吸附量分别为229.93和99.27 mg/g;印迹材料对Yb3+的吸附符合Langmuir模型;吸附平衡在40 min的时候基本可以达到,可以利用准二级动力学模型来描述其吸附过程;Yb(Ⅲ)-IIP-PEI/MCM-41对Yb3+具有较强的选择性,同时也具有很好的重复使用性能。 成功地将MCM-41和离子印迹聚合物的优点结合起来,制备出一种对稀土Yb离子既有高吸附量又有高选择性的吸附材料,为进一步将其应用在处理实际废水,分离回收低浓度稀土废水中的稀土元素等方面打下了基础。 相似文献
38.
Ring-opening suspension polymerization of p-dioxanone(PDO) in supercritical carbon dioxide(scCO2) was investigated in the presence of poly(caprolactone)-perfluropolyether-poly(caprolactone)(PCL-PFPE-PCL).The molecular weight,yield and particle morphology of poly(p-dioxanone)(PPDO) were studied.The stabilizer was effective to stabilize the ring-opening polymerization(ROP) of PDO in scCO2,leading to the formation of resorbable microparticles in a"one pot"procedure.The mean size of PPDO microparticles obtained from suspension polymerizations was sensitive to the rate of agitation and the stabilizer concentration.The method to generate PPDO microparticles has overcome its unprocessable drawback with common organic solvents and provided new product form for biomedical applications. 相似文献
39.
Two new complexes, {[Co(INAIP) · H2O] · 2H2O}n ( 1 ), and {[Cu(INAIP)] · H2O}n ( 2 ) [H2INAIP = 5‐(isonicotinamido)isophthalic acid] were synthesized under hydrothermal conditions, and characterized by single‐crystal X‐ray structure determination, thermogravimetric analysis, X‐ray powder diffraction, and magnetic studies. In complex 1 both CoII atoms and INAIP2– ligands act as four‐connected node, whereas in 2 both CuII atoms and INAIP2– ligands act as three‐connected node. 相似文献
40.
Xiu Ling ZHANG Wei Min GONG* Bin DAI Chang Hou LIU Plasma Chemistry Laboratory Dalian University of Technology Dalian Center of Analysis Dalian Institute of Light Industry Dalian 《中国化学快报》2002,(2)
The oxidative coupling of methane (OCM) to C2 hydrocarbons using carbon dioxide as oxidant is an attractive process from environmental point of view. Only a few research papers reported for it1-3. In general, the yield of C2 hydrocarbons was about 6%. This indicated that the method of catalytic activation was unfavorable to the reaction. It is necessary for us to find a new method in order to activate reaction and improve C2 hydrocarbon yield. Non-equilibrium plasma is a cold plasma in… 相似文献