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81.
Kilár A Dörnyei Á Bui A Szabó Z Kocsis B Kilár F 《Journal of mass spectrometry : JMS》2011,46(1):61-70
The structural variations in the rough-type endotoxins [lipopolysaccharides (LPSs)] of Shigella sonnei mutant strains (S. sonnei phase II-4303, R41, 562H and 4350) were investigated by Matrix-assisted laser desorption/ionization time-of-flight mass spectrometry (MALDI-TOF-MS) and tandem MS. A series of S. sonnei mutants had previously been the subject of analytical studies on the biosynthesis of heptose components in the core oligosaccharide region of LPSs. This study gives a complete overview on the structures of the full core and lipid A of S. sonnei mutant strains by MS. We found that the LPSs of the isogenic rough mutants were formed in a step-like manner containing 0:1:2:3 heptose in the deep core region of 4350, 562H, R41 and 4303, respectively, and the longest LPS from the mutant S. sonnei 4303 contained also five hexoses. The structural variations in the lipid A moiety and in the oligosaccharide part of the intact LPS were followed by MALDI-TOF-MS/MS. For the dissolution and the ionization of the samples, 2,5-dihydroxybenzoic acid in citric acid solution was applied as matrix. The detailed evaluation of the mass spectra indicates heterogeneity in the lipid part due to the differences in the phosphate and fatty acid composition. 相似文献
82.
Molnár A Kapros A Párkányi L Mucsi Z Vlád G Hermecz I 《Organic & biomolecular chemistry》2011,9(19):6559-6565
The palladium-catalyzed Suzuki-Miyaura cross-coupling reactions of halo derivatives of 4H-pyrido[1,2-a]pyrimidin-4-one with (het)arylboronic acids allow easy access to (het)aryl and vinyl derivatives of this bicycle in good to excellent yields, even from chloro derivatives. The sequence of reactivity of the halogen in the different positions of the ring system was also investigated. 6-Phenyl-4H-pyrido[1,2-a]pyrimidin-4-one could be prepared by thermal cyclization of isopropylidene (6-phenylpyrid-2-ylamino)methylenemalonate, together with a small amount of 7-phenyl-1,4-dihydro-1,8-naphthyridin-4-one. 相似文献
83.
A question of Yves Meyer motivated the research concerning “time” subordinations of real functions. Denote by B1a{\mathcal {B}}_{1}^{\alpha} the metric space of functions with Lipschitz constant 1 defined on [0,1], equipped with the complete metric defined via the
supremum norm. Given a function g ? B1ag\in {\mathcal {B}}_{1}^{\alpha} one obtains a time subordination of g simply by considering the composite function Z=g○f, where f∈ℳ:={f:f(0)=0, f(1)=1 and
f
is a continuous nondecreasing function on [0,1]}. The metric space Ea=M×B1a\mathcal {E}^{\alpha}=\mathcal {M}\times {\mathcal {B}}_{1}^{\alpha} equipped with the product supremum metric is a complete metric space. In this paper for all α∈[0,1) multifractal properties of g○f are investigated for a generic (typical) element (f,g)∈ℰ
α
. In particular we determine the generic H?lder singularity spectrum of g○f. 相似文献
84.
In this paper we establish direct and inverse theorems for Stancu operator. Some other approximation properties of these operators are also given. 相似文献
85.
Shiro Kubuki Norifumi Kawakami Takamitsu Kamikawa Masayuki Fukagawa Toshiharu Nishizumi Tetsuaki Nishida Zoltán Homonnay Ernő Kuzmann 《Hyperfine Interactions》2005,166(1-4):429-436
A relationship between the structure and water purifying ability of waste glass prepared from household garbage and Fe2O3 was examined by 57Fe-Mössbauer and induced coupled plasma (ICP) measurements. From the Debye temperature of waste glass, FeII proved to be loosely bound in the glass network as a network modifier. Dissolution amount of FeIII into artificial drain can be controlled from 0.14 to 0.35 mg/l by changing the Fe2O3 content. It proved that chemical oxygen demand (COD) decreases in proportion to the content of FeIII, indicating that iron causes decomposition of organic and phosphorus compounds. 相似文献
86.
87.
Zoltán Füredi 《Archiv der Mathematik》1991,56(3):300-312
88.
Zoltán Varga Jen Hancsók Dénes Kalló árpád Stumpfc 《Reaction Kinetics and Catalysis Letters》2006,88(1):19-26
Summary The hydrodesulfurization (HDS) of dibenzothiophene (DBT), 4-methyl-dibenzothiophene (4 M-DBT), 4,6-dimethyldibenzothiophene
(4,6 DM-DBT) and 4,6-diethyldibenzothiophene (4,6 DE-DBT) as real gas oil components on NiMo/Al2O3 catalyst was investigated. On the basis of the first order rate constants of HDS of the individual sulfur compounds calculated
by both integral and differential evaluations the reactivities of the investigated compounds decreased in the order DBT >>
4 M-DBT > 4,6 DE-DBT ? 4,6 DM-DBT. Additionally, results showed that product inhibition during HDS does not take place. 相似文献
89.
90.
Zoltán Füredi 《Graphs and Combinatorics》1988,4(1):115-206
Almost all combinatorial question can be reformulated as either a matching or a covering problem of a hypergraph. In this paper we survey some of the important results. 相似文献