分级结构多酸微米管的合成及对阿霉素的吸附

通过简单的无模板法,由三缺位α-SiW9多金属氧酸盐制得了饱和Keggin结构SiW12多金属氧酸盐的微米管状晶体,并通过红外光谱、热重分析和X射线粉末衍射对其进行了表征.采用光学显微镜和扫描电子显微镜观察到所合成的分级结构管状晶体具有微米级空腔和管壁的纳米级孔隙.将阿霉素(DOX)吸附于所制备的SiW12微米管中,得到了负载阿霉素的DOX@SiW12微米管,其在紫光和绿光的激发下可显示阿霉素的特征红光.     

十二氢十二硼酸双(二烷基-5-氨基四唑)盐的晶体结构及性能分析

制备了11种十二氢十二硼酸双(二烷基-5-氨基四唑)盐晶体, 采用X射线单晶衍射仪对其单晶结构进行了表征, 利用EXPLO5软件计算了11种化合物的爆轰性能. 结果表明, 11种化合物的密度在1.097~1.229 g/cm³之间, 当取代基位置相同时, 随着烷基取代基碳原子数的增大化合物的密度下降; 这些盐晶体的空间晶型主要受取代基位置的影响, 晶体结构有三斜晶系和单斜晶系2种; 晶胞尺寸与晶胞内分子数有关, 化合物中阳离子取代烷基中碳原子的个数对与四唑相连的C—N键长无明显影响. 对于同一取代位置的化合物, 生成热和爆热随着烷基取代基的碳原子数的增多而下降.     

A new synthesis of 3′-deoxy-3′-fluoroadenosine,a key intermediate of cyclic dinucleotide

A new synthesis of 3′-deoxy-3′-fluoroadenosine for use as an important intermediate of antitumor-active cyclic dinucleotide is disclosed. The synthesis started with the known 5-O-TBDPS-D-lyxofuranose 1,2-acetonides, which was first transformed into a fluorinated compound after the DAST reaction. Desilylation and acidic methanolysis were then finished in one pot. After a sequence of triflation, displacement by OBz as well as benzoylation, perbenzoylated 3-deoxy-3-fluoro-D-ribofuranoside was obtained, which would be transformed to 3′-deoxy-3′-fluoroadenosine as the key intermediate of cyclic dinucleotide after ammonolysis.     

Memory-augmented adaptive flocking control for multi-agent systems subject to uncertain external disturbances

This paper presents a novel flocking algorithm based on a memory-enhanced disturbance observer.To compensate for external disturbances,a filtered regressor for the double integrator model subject to external disturbances is designed to extract the disturbance information.With the filtered regressor method,the algorithm has the advantage of eliminating the need for acceleration information,thus reducing the sensor requirements in applications.Using the information obtained from the filtered regressor,a batch of stored data is used to design an adaptive disturbance observer,ensuring that the estimated values of the parameters of the disturbance system equation and the initial value converge to their actual values.The result is that the flocking algorithm can compensate for external disturbances and drive agents to achieve the desired collective behavior,including virtual leader tracking,inter-distance keeping,and collision avoidance.Numerical simulations verify the effectiveness of the algorithm proposed in the present study.     

硼化合物研究■——一些新的螺型螯合物2-β-二酮-1,3,2-苯并二杂(硫、氧)硼环戊烷的合成与性质

8种1,3,2-苯并二杂(硫、氧)硼环戊烷-2-β-二酮衍生物已经合成,其中IA-ID和ⅡB系首次报道。IR及~1H NMR光谱数据表明,这些化合物具有相似螯合结构,其分子内部,配体β-二酮骨架π电子广泛离域化。     

含空心球涂层粒子复合材料界面的脱粘应力分析

在球对称拉伸载荷作用下针对空心球涂层复合材料分析了空心球涂层粒子增强复合材料的局部应力场，得到了界面临界脱粘应力的解析表达式．讨论了各相几何参数对非均匀涂层空心球粒子临界脱粘应力的影响，比较了均匀涂层和非均匀涂层的脱粘应力．结果表明：在球对称拉伸下界面脱粘更容易发生在涂层相与基体相界面间，空心球的壁厚和涂层厚度是影响界面临界脱粘应力的重要因素，因而选择适当的空心球、涂层厚度和提高界面粘结能将有利于提高界面的临界脱粘应力．     

胞体椭球比对泡沫塑料力学性能的影响

本文通过数值法研究了胞体椭球比对材料模量及泊松比的影响；在单向受力情况下，研究了变形对材料孔隙度、椭球比、杨氏模量和泊松比等材料参数的影响。     

DETERMINATION OF EFFECTIVE MODULI FOR FOAM PLASTICS BASED ON THREE PHASE SPHEROIDAL MODEL

The relations of bulk modulus,shear modulus,Young's modulus and the Poisson's ra-tio with porosity of foam plastics are determined by a three phase spheroidal model commonly used inComposite Mechanics.The results are compared with those using differential scheme.It is shownthat the material properties derived from the present model normally are larger than those obtained bydifferential scheme for foam plastics with identical porosity.The differences in shear moduli andYoung's moduli obtained by the two methods are small,but they are larger for bulk moduli of incom-pressible matrix and Poisson's ratios.The Young's moduli of high density foam plastics derived by thepresent model agree better with experimental ones.     

泡沫塑料力学性能研究综述

本文对泡沫塑料静、动态力学性能的研究文献进行了综述，重点介绍近期的研究进展，并简单介绍作者在这一领域的一些工作．