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11.
Asymmetric catalytic activity of the chiral spiroborate esters 1 – 9 with a O3BN framework (see Fig. 1) toward borane reduction of prochiral ketones was examined. In the presence of 0.1 equiv. of a chiral spiroborate ester, prochiral ketones were reduced by 0.6 equiv. of borane in THF to give (R)‐secondary alcohols in up to 92% ee and 98% isolated yields (Scheme 1). The stereoselectivity of the reductions depends on the constituents of the chiral spiroborate ester (Table 2) and the structure of the prochiral ketones (Table 1). The configuration of the products is independent of the chirality of the diol‐derived parts of the catalysts. A mechanism for the catalytic behavior of the chiral spiroborate esters (R,S)‐ 2 and (S,S)‐ 2 during the reduction is also suggested. 相似文献
12.
玻璃纤维增强聚氨酯泡沫塑料的压缩力学性能研究 总被引:12,自引:0,他引:12
本文研究了两种不同密度的玻璃纤维增强聚氨酯泡沫塑料在准静态压缩下的力学性能。给出了与相应密度的普通泡沫塑料力学性能的比较,实验结果表明:两种增强泡沫塑料在压缩载荷作用下,具有不同于普通泡沫塑料的应力-应变特性,压缩模量和强度一般均有不同程度的提高,而且对相同纤维含量的增强泡沫塑料来说,密度较高的材料增强效果较好。 相似文献
13.
针对水化硅酸钙纳米压痕模型忽视了压头与基底之间相互作用的问题,由尺寸差异引起的金刚石压头难以计算的问题,以及Wittmann模型无法得到实际接触面积的问题,提出了新的模型与计算方法.结合分子动力学方法,采用金刚石压头-Wittmann模型基底的组合方式构建无定形态水化硅酸钙纳米压痕试验模型.在建模阶段,考虑到压头模型与基底模型粒子间尺寸差异,提出了等比例替换模型,通过公式推导并就不同尺寸模拟结果验证了等比例替换模型的可行性.在计算阶段,提出了局部前处理的弛豫方法进行模拟.确定最大荷载位置处的接触面积为546 nm2,进而求出水化硅酸钙模型硬度H为0.84 GPa、折合模量Er为30.52 GPa.并通过纳米压痕试验,验证了模拟结果的准确性,证明了模型的科学性,对今后水化硅酸钙(C-S-H)纳米层面的模拟具有重要借鉴意义. 相似文献
14.
A series of 9-(cycloheptatrienylidene)fluorene derivatives were synthesized in good yields through the Suzuki or Sonogashira cross-coupling reactions. Fluorescence "off-on" behaviors of these compounds were investigated on the basis of variable acid concentrations. These compounds were shown to be acid-sensing fluorophores with utility as indicators in acidic environments. 相似文献
15.
2,7-Bis(4-dimethylaminophenyl)-9-(cycloheptatrienylidene)fluorene (1) was synthesized and characterized. 1 could be used as a fluorescent sensor either for pH or for pyridinium halide. Integrated with the ratiometric method and an NOR logic gate, a tunable two-input/multi-output system was presented on the basis of this single molecule. [structure: see text] 相似文献
16.
An improved and practical approach to (R)- and (S)-BINOLs has been developed. The rac-BINOL and (S)-proline were refluxed in acetonitrile for several hours, and the resulting white precipitate was recrystallized in ethanol to afford colorless crystals consisting of (S)-BINOL and (S)-proline, which were analyzed by single crystal X-ray structural analysis. Essentially enantiopure (S)- and (R)-BINOLs were obtained in high yields after decomposition of the colorless crystalline complex and evaporation of the acetonitrile mother liquor removed from the complex precipitate and successive crystallization. The (S)-proline can be recovered and reused without any decrease in efficiency. 相似文献
17.
Vinylene-linked covalent organic frameworks(COFs) are a class of promising porous organic materials that feature fully π-conjugated structures, high crystallinity, permanent porosity, ultrahigh chemical stability, and extraordinary optoelectronic properties. Over the past 5 years, this kind of material has been witnessed rapid development either in chemical synthesis or in potential applications. In this review, we summarize the chemistry to synthesize vinylene-linked COFs, especially the synthetic strategies involving activation of aryl methyl groups for condensation reaction. We then scrutinize the state-of-the-art development in properties and functions of this kind of COFs. Our own opinions on the further development of the vinylene-linked COFs are also presented for discussion. 相似文献
18.
C2‐Chiral 1,1,4,4‐tetraaryl‐ or 1,1,4,4‐tetraalkyl‐substituted butanetetraols have been conveniently synthesized via arylation or alkylation of unprotected diethyl (2R,3R)‐ and (2S,3S)‐tartrates with Grignard reagent. The chiral 1,1,4,4‐tetrasubstituted butanetetraols were characterized by IR, 1H‐ and 13C‐NMR, as well as LC/MS. 相似文献
19.
Sterically hindered C2 chiral (3R,4R)- and (3S,4S)-2,2,5,5-tetraphenyltetrahydrofuran-3,4-diols have been conveniently prepared in a very high yield via heterogeneous intramolecular selective 1,4-cyclocondensation of (2R,3R)- and (2S,3S)-1,1,4,4-tetraphenylbutanetetraol in concentrated hydrohalic acids, respectively. Preliminary examination of additives for the Barbas–List reaction showed that in certain cases, the hindered C2 chiral tetrahydrofuran-3,4-diols were better chiral auxiliaries than enantiopure (R)- and (S)-1,1′-bi-2-naphthols. 相似文献
20.
Xiaoyun Hu Rui Zhang Jinsheng Xie Zhongqiang Zhou Zixing Shan 《Tetrahedron: Asymmetry》2017,28(1):69-74
A novel sterically hindered chiral cyclic phosphoric acid derived from l-tartaric acid was designed and synthesized based on highly regioselective cyclosulfitation of chiral 1,1,4,4-tetraphenylbutanetetraol. The asymmetric Biginelli reaction catalyzed by this newly synthesized chiral phosphoric acid was examined, and enantioselectivities up to 99% ee was obtained. 相似文献