Aminated polystyrene membranes for a fiber optic pH sensor based on reflectance changes accompanying polymer swelling

We have prepared toughened, porous, aminated polystyrene membranes that undergo an increase in reflectance as the pH increases from 6.8 to 8.0. Vinylbenzyl chloride (VBC) is copolymerized with divinylbenzene (DVB) in the presence of a toughening agent, Kraton G1652, a styrene-ethylene, butylene-styrene triblock copolymer, and a porogenic solvent, xylene/ dodecane. The optimum formulation for sensing is 2% DVB (mol DVB/mol VBC), 2% Kraton (g Kraton/g VBC) and 40% (v/v) 21 xylene: dodecane. Benzoyl peroxide is used as the initiator. The components are partially polymerized at 85 °C to a viscosity of 600–800 centipoise. The polymerization is then stopped by reducing the temperature. A drop of the partially polymerized solution is confined between two microscope slides and the polymerization reaction is completed. The resulting membrane is then swollen in 1,4-dioxan and reacted with diethanolamine. These membranes have been incorporated into a pH sensor based on changes in reflected intensity measured through a bifurcated bundle of twenty unbuffered 50/55 core/cladding glass-on-glass optical fibers with numerical apertures of 0.57. The resulting sensor is stable and requires inexpensive optical components, a red-emitting LED as the source and a silicon photodiode as the detector.     

Heat transfer in pool boiling of binary and ternary non-azeotropic mixtures

Heat transfer coefficients in nucleate pool boiling of binary and ternary non-azeotropic hydrocarbon mixtures were obtained experimentally using a vertical electrically heated cylindrical carbon steel surface at atmospheric pressure with several surface roughness. The fluids used were Methanol/1-Pentanol and Methanol/1-Pentanol/1,2-Propandiol at constant 1,2-Propandiol mole fraction of 30%. Heat fluxes were varied in the range 25–235 kW/m². The cylindrical heater surface was polished to an average surface roughness of 0.2 μm, and sandblasted yielding surface roughness of 2.98 and 4.35 μm, respectively. The experimental results were compared to available prediction correlations, indicating that the correlations based on the boiling range are in better qualitative agreement than correlations based on the phase envelope. Increasing surface roughness resulted in an increase in the heat transfer coefficient, and the effect was observed to be dependent on the heat flux and fluid composition.     

Anisotropic damage–plasticity model for concrete

A material model for concrete is proposed here within the framework of a thermodynamically consistent elasto-plasticity–damage theory. Two anisotropic damage tensors and two damage criteria are adopted to describe the distinctive degradation of the mechanical properties of concrete under tensile and compressive loadings. The total stress tensor is decomposed into tensile and compressive components in order to accommodate the need for the above mentioned damage tensors. The plasticity yield criterion presented in this work accounts for the spectral decomposition of the stress tensor and allows multiple hardening rules to be used. This plastic yield criterion is used simultaneously with the damage criteria to simulate the physical behavior of concrete. Non-associative flow rule for the plastic strains is used to account for the dilatancy of concrete as a frictional material. The thermodynamic Helmholtz free energy concept is used to consistently derive dissipation potentials for damage and plasticity and to allow evolution laws for different hardening parameters. The evolution of the two damage tensors is accounted for through the use of fracture-energy-based continuum damage mechanics. An expression is derived for the damage–elasto-plastic tangent operator. The theoretical framework of the model is described here while the implementation of this model will be discussed in a subsequent paper.     

A thermomechanical model accounting for the behavior of shape memory alloys in finite deformations

Shape memory alloys (SMA) comport an interesting behavior. They can undertake large strains and then recover their undeformed shape by heating. In this context, one of the aspects that challenged many researchers was the development of a mathematical model to predict the behavior of a known SMA under real-life conditions, or finite strain. This paper is aimed at working out a finite strain mathematical model for a Ni–Ti SMA, under the superelastic experiment conditions and under uniaxial mechanical loading, based on the Zaki–Moumni 3D mathematical model developed under the small perturbations assumption. Within the current article, a comparison between experimental findings and calculated results is also investigated. The proposed finite strain mathematical model shows good agreement with experimental data.     

Surfactant-mediated capillary electrochromatography with octadecyl-silica- packed capillary columns for the separation of nonpolar compounds. Case of pyrethroid insecticides

Capillary electrochromatography (CEC) with octadecyl-silica-packed capillary columns was evaluated in the separation of nonpolar compounds, e.g., pyrethroid insecticides, using surfactant-rich mobile phases. This novel concept is referred to as surfactant-mediated capillary electrochromatography (SM-CEC), and is based on including a charged surfactant, namely sodium di-2-ethylhexyl sulfosuccinate (DOSS), in the mobile phase. Under these conditions, DOSS plays the role of a slowly moving pseudostationary phase so that solutes are partitioned between a mobile phase, a fixed stationary phase and a slowly moving pseudostationary phase. The SM-CEC system was investigated with pyrethroid insecticides over a wide range of DOSS and acetonitrile concentrations in the mobile phase. Pyrethroid insecticides, which are very hydrophobic solutes consisting of geometric isomers and diastereomers, were better resolved in SM-CEC than in straight CEC.     

Spectral renormalization method for computing self-localized solutions to nonlinear systems

A new numerical scheme for computing self-localized states--or solitons--of nonlinear waveguides is proposed. The idea behind the method is to transform the underlying equation governing the soliton, such as a nonlinear Schr?dinger-type equation, into Fourier space and determine a nonlinear nonlocal integral equation coupled to an algebraic equation. The coupling prevents the numerical scheme from diverging. The nonlinear guided mode is then determined from a convergent fixed point iteration scheme. This spectral renormalization method can find wide applications in nonlinear optics and related fields such as Bose-Einstein condensation and fluid mechanics.     

WIDE SENSE STABILITY OF COMPLEX SYSTEMS OF DIFFERENTIAL EQUATIONS OF ARBITRARY DIMENSION

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On a fully nonlinear degenerate parabolic system modeling immiscible gas–water displacement in porous media

In this paper, we are interested in the simultaneous flow of two immiscible fluid phases within a porous medium. We consider a two-phase flow model where the fluids are immiscible and there is no mass transfer between the phases. The medium is saturated by compressible/incompressible phase flows. We study the gas–water displacement without simplified assumptions on the state law of gas density. We establish an existence result for the nonlinear degenerate parabolic system based on new energy estimate on pressures.     

Tracing pore-space heterogeneities in X-type zeolites by diffusion studies

Pore-space homogeneity of zeolite NaX was probed by pulsed field gradient (PFG) NMR diffusion studies with n-butane as a guest molecule. At a loading of 0.75 molecules per supercage, a wide spectrum of diffusivities was observed. Guest molecules in the (well-shaped) zeolite crystallites were thus found to experience pore spaces of quite different properties. After loading enhancement to 3 molecules per supercage, however, molecular propagation ideally followed the laws of normal diffusion in homogeneous media. At sufficiently high guest concentrations, sample heterogeneity was thus found to be of no perceptible influence on the guest mobilities anymore.     

Controlling retention, selectivity and magnitude of EOF by segmented monolithic columns consisting of octadecyl and naphthyl monolithic segments--applications to RP-CEC of both neutral and charged solutes

Monolithic capillaries made of two adjoining segments each filled with a different monolith were introduced for the control and manipulation of the electroosmotic flow (EOF), retention and selectivity in reversed phase-capillary electrochromatography (RP-CEC). These columns were called segmented monolithic columns (SMCs) where one segment was filled with a naphthyl methacrylate monolith (NMM) to provide hydrophobic and π-interactions, while the other segment was filled with an octadecyl acrylate monolith (ODM) to provide solely hydrophobic interaction. The ODM segment not only provided hydrophobic interactions but also functioned as the EOF accelerator segment. The average EOF of the SMC increased linearly with increasing the fractional length of the ODM segment. The neutral SMC provided a convenient way for tuning EOF, selectivity and retention in the absence of annoying electrostatic interactions and irreversible solute adsorption. The SMCs allowed the separation of a wide range of neutral solutes including polycyclic aromatic hydrocarbons (PAHs) that are difficult to separate using conventional alkyl-bonded stationary phases. In all cases, the k' of a given solute was a linear function of the fractional length of the ODM or NMM segment in the SMCs, thus facilitating the tailoring of a given SMC to solve a given separation problem. At some ODM fractional length, the fabricated SMC allowed the separation of charged solutes such as peptides and proteins that could not otherwise be achieved on a monolithic column made from NMM as an isotropic stationary phase due to the lower EOF exhibited by this monolith.