CSR-LINAC IH-RFQ的高频电磁设计

中国科学院近代物理研究所在CSR-LINAC项目中设计了一台108.48 MHz的IH型RFQ直线加速器。该RFQ可以将质荷比为3~7的离子从4 keV/u加速到300 keV/u。在完成束流动力学设计的基础上,主要针对RFQ腔体的高频电磁设计展开了研究,同时利用了电磁场仿真和束流动力学模拟来研究腔体的四极场不平整度和二极场及其动力学影响。未经调谐的情况下,腔体的谐振频率为108.15 MHz,腔体空载品质因子Q₀为5 910,腔体功耗为123 kW。通过在支撑板两端增加底切的设计,将腔体的四极场不平整度由-21%~ 12%优化至±2.5%,满足了束流动力学要求。腔体的二极场为-3%~ -2.2%,使得束流在垂直方向小幅振荡,RFQ的垂直方向接受度减小5%。为了保证功率馈入时反射较小,将耦合器设置在临界耦合状态,耦合面积为940 mm2。为了补偿腔体的频率偏差和漂移,设计了调谐量分别为707和132 kHz的固定调谐器和可动调谐器。The 108.48 MHz IH type RFQ for CSR-LINAC project is under design at Institute of Modern Physics, Chinese Academy of Sciences. This RFQ can accelerate heavy ions with mass to charge ratio of 3~7 from 4 keV/u to 300 keV/u. According to the beam dynamics requirement, the RF structure design has been finished. The quadrupole field unflatness and dipole field of the cavity were studied by electromagnetic simulation and beam dynamics simulation. The frequency of the cavity without tuning is 108.15 MHz, the Q₀ of the cavity is 5910, and the RF power loss is 123 kW. The quadrupole field unflatness of ±2.5%,which was -21%~12% before optimizing, is achieved to meet dynamics requirement through the undercuts in cavity supporters. The dipole field of -3%~ -2.2% causes the oscillation of the beam center and acceptance reduction of 5%. The power coupler must be in critical coupling state with the coupling area of 940 mm2 for minimum reflection coefficient. The tuners, consist of coarse and fine tuners with frequency shift of 707 and 132 kHz respectively, is used for tuning of frequency deviation of the cavity.     

AOTF在光谱分析中的应用研究——3.AOTF在原子发射光谱分析中的应用

本文报道了一台以声光可调滤光器(AOTF)为分光元件的自装ICP原子发射光谱仪.其硬件及软件系统均为自行设计.采用的TeO2晶体为Brimrose TEAF5-0.36-0.52-S.波长校正采用了Ca,Y,Li,Eu,Sr和Ba等六个元素的十四条谱线,经十次拟合后波长值误差小于0.1 nm.不同PMT电压下测定的峰值偏差小于0.04 nm.Ba,Y,Eu,Sc和Sr等五个元素的校正曲线平均相关系数为0.999 1,检出限在0.051～0.97 μg*mL-1范围. 在488 nm处半峰高宽度约为2.1 nm,如不采取增强分辨率的措施,该仪器在原子发射光谱分析中的应用有一定的局限性.     

On Ranks of Matrices Associated with Trees

A sign pattern matrix is a matrix whose entries are from the set {+,–,0}. The purpose of this paper is to obtain bounds on the minimum rank of any symmetric sign pattern matrix A whose graph is a tree T (possibly with loops). In the special case when A is nonnegative with positive diagonal and the graph of A is star-like, the exact value of the minimum rank of A is obtained. As a result, it is shown that the gap between the symmetric minimal and maximal ranks can be arbitrarily large for a symmetric tree sign pattern A. Supported by NSF grant No. DMS-00700AMS classification: 05C50, 05C05, 15A48     

单圈图的第二大Balaban指数(Sum-Balaban指数)

Balaban指数和Sum-Balaban指数被广泛的应用于结构活性关系和结构性质关系的研究中. 本文分别研究了所有 $n$ 阶单圈图的第二大Balaban指数和Sum-Balaban指数.     

土钉支护结构的施工监测与变形控制

结合某软岩高边坡工程 ,对土钉支护结构的受力和位移进行了监测。通过对实验数据分析了土钉支护的结构原理和受力状态 ,表明土钉支护工作原理既不同于锚杆结构 ,又不同于土钉墙。同时根据施工过程中对边坡水平位移的监测 ,及时调整了边坡的支护参数、开挖深度和支护时间 ,控制了施工过程中边坡的变形 ,保证了软岩高边坡的整体稳定     

聚酰基氨基脲类多孔有机聚合物的制备及其在糖肽富集中的应用

通过均苯三甲酰肼(BTZ)和对苯二异氰酸酯(PDI)的聚合反应制备了一种新型的聚酰基氨基脲类多孔有机聚合物(POP)。采用傅里叶变换红外光谱(FT-IR)、交叉极化魔角自旋碳13核磁共振(CP-MAS13C NMR)、氮气物理吸附/脱附实验和水接触角等手段对POP-1的物理性质进行表征。其中比表面积为166 m~2/g,水接触角为46.4°,表明这种多孔材料具有良好的亲水性。因此,尝试将POP-1应用于标准蛋白质和复杂生物样品中糖肽的亲水色谱富集。通过基质辅助激光解吸电离飞行时间质谱(MALDI-TOF/MS)分析,从500 fmol人血清免疫球蛋白G(IgG)酶解液中共鉴定到19条典型的N-连接糖肽;通过毛细管液相色谱-串联质谱(c LC-MS/MS)分析,从100μg鼠肝蛋白酶解液中共鉴定到属于605个糖蛋白的1 919个糖肽的1 350个N-糖基化位点。这些结果表明POP-1在糖蛋白质组学研究中具有较强的应用潜力。     

Quantitative K-Cl-S chemistry in thermochemical conversion processes using in situ optical diagnostics

The sulfation of gas-phase KOH and KCl was investigated in both oxidizing and reducing atmospheres at temperatures of 1120 K, 1260 K, 1390 K, and 1550 K. Well-defined gas environments were generated in a laminar flame burner fuelled with CH₄/air/O₂/N₂. Atomized K₂CO₃ and KCl water solution fog and SO₂ were introduced into the hot gas as sources of potassium, chlorine, and sulfur, respectively. The in situ concentrations of KOH, KCl, and OH radicals were measured using broadband UV absorption spectroscopy, and the concentration of K atom was measured using TDLAS at 769.9 nm and 404.4 nm. The nucleated and condensed K₂SO₄ aerosols were visualized as illuminated by a green laser sheet. With SO₂ addition, reduced concentrations of KOH, KCl, and K atom were measured in the hot gas. The sulfation was more significant for the low temperature cases. KOH was sulfated more rapidly than KCl. K₂SO₄ aerosols, formed by homogeneous nucleation, were observed at temperatures below 1260 K. At 1390 K, no aerosols were formed, indicating that the consumed KOH was transformed into gaseous KHSO₄ or K₂SO₄. K atoms formed in the hot flue gas with KOH addition enhanced the consumption of OH radicals except at the high-temperature case at 1550 K. At 1120 K and 1260 K, the sulfation of KOH with SO₂ seeding reduced the concentration of K atom, resulting in less OH radical consumption. Studies were also conducted in a hot reducing environment at 1140 K, with the flame at an equivalence ratio of 1.31. Similar to the observation in the oxidizing atmosphere, the concentrations of KOH and K atom decreased dramatically with SO₂ seeding. An unknown absorption spectrum observed was attributed to UV absorption by KOSO. The experimental results were used to evaluate a detailed K-Cl-S reaction mechanism, and a reasonable agreement was obtained.     

Temporal temperature measurement on burning biomass pellets using phosphor thermometry and two-line atomic fluorescence

We report accurate in-situ optical measurements of surface temperature, volatile gas temperature, and polycyclic aromatic hydrocarbon (PAH) emission over the whole burning history of individual biomass pellets in various combustion atmospheres. Two biomass fuels, wood and straw, were prepared in cylindrical pellets of ～300 mg. The pellets were burned in a well-controlled combustion atmosphere provided by a laminar flame burner with temperature ranging from 1390 K to 1840 K, and oxygen concentration from zero to 4.5%. The surface temperature of burning biomass pellets was accurately measured, for the first time, using phosphor thermometry, and the volatile gas temperature was measured using two-line atomic fluorescence thermometry. PAH emission was monitored using two-dimensional laser-induced fluorescence. During the devolatilization stage, a relatively low surface temperature, ～700 K, was observed on the burning pellets. The volatile gas temperature was ～1100 K and ～1500 K 5 mm above the top of the pellets in a gas environment of ～1800 K with 0.5% and 4.5% oxygen, respectively. PAH mainly released when the temperature of the pellet exceeded ～600 K with the highest concentration close to the surface and being consumed downstream. The weight of the released PAH molecules shifted towards lighter with a reduction of gas environment temperature. The wood and straw pellets had almost the same surface and volatile gas temperature but different compositions in the released volatile gases. The temperature information provided in the present work aids in revealing the reactions in the burning biomass fuels regarding species release, such as various hydrocarbons, nitrogen compounds, and potassium species, and is valuable for further development of biomass thermal conversion models.     

Eigenvalue distribution of certain ray patterns

In this paper, the eigenvalue distribution of complex matrices with certain ray patterns is investigated. Cyclically real ray patterns and ray patterns that are signature similar to real sign patterns are characterized, and their eigenvalue distribution is discussed. Among other results, the following classes of ray patterns are characterized: ray patterns that require eigenvalues along a fixed line in the complex plane, ray patterns that require eigenvalues symmetric about a fixed line, and ray patterns that require eigenvalues to be in a half-plane. Finally, some generalizations and open questions related to eigenvalue distribution are mentioned.     

Erratum on “Complexation of radionuclide 152+154Eu(III) with alumina-bound fulvic acid studied by batch and time-resolved laser fluorescence spectroscopy”

Science China Chemistry - In the above referenced publication [1], the Figure 5 and data in Table 1 are correct, but we ignored to present the final pH values of the system, which is very important...