A facile route to polysubstituted indoles via three-component reaction of 2-ethynylaniline, sulfonyl azide, and nitroolefin

A copper-catalyzed three-component reaction of 2-ethynylaniline, sulfonyl azide, and nitroolefin is reported. This reaction generates functionalized indoles in good yields and proceeds smoothly under mild conditions. Some hits as an HCT-116 inhibitor are found from the preliminary biological screening.     

Diversity-oriented approach to 1,2-dihydroisoquinolin-3(4H)-imines via copper(I)-catalyzed reaction of (E)-2-ethynylphenylchalcone, sulfonyl azide and amine

A three-component reaction of (E)-2-ethynylphenylchalcone, sulfonyl azide, and amine catalyzed by copper(I) chloride (5 mol%), in the presence of triethylamine, under mild conditions is described. This transformation proceeds efficiently to generate 1,2-dihydroisoquinolin-3(4H)-imines in good to excellent yields.     

Unique fusiform alumina nanotubes fabricated by combined anodization

Alumina nanotubes (ANTs) with unique fusiform morphologies were synthesized via a simple electrochemical route; the fluctuation of the electronic current density during the anodization process is considered to be the main reason for the formation of such new alumina nanostructures.     

High-rate cathode based on Li3V2(PO4)3/C composite material prepared via a glycine-assisted sol–gel method

Carbon-coated monoclinic Li₃V₂(PO₄)₃ (LVP/C) cathode material has been successfully prepared by a novel glycine-assisted sol–gel method. The product is investigated by X-ray diffraction (XRD), high-resolution transmission electron microscopy (HR-TEM) and electrochemical method. In the range of 3.0–4.3 V, the LVP/C electrode presents excellent rate capability. It is 125.4 mAh g^{− 1} that can be delivered at 1 C charge–discharge rate and 99.5 mAh g^{− 1} is still obtained at 20 C charge–discharge rate. These results demonstrate that the carbon-coated LVP/C composite material prepared via a glycine-assisted sol–gel method has great potential for use in high-power lithium ion batteries.     

Stepsize domain confirmation and optimum of ZeaD formula for future optimization

Numerical Algorithms - Future optimization, which is also known as discrete-time time-variant optimization problem, is an important issue in scientific fields. Recently, Guo et al. have proposed a...     

巨共振激发的相对论效应

在相对论量子场论(QHD)的框架下,得到了相对论线性Vlasov方程.基此计算了球形核¹⁶O、⁴⁰Ca、⁹⁰Zr及²⁰⁸Pb的巨偶极共振的强度函数分布.计算得到的巨共振中心能量,与实验结果比较有较好的符合.对计算结果作了简要的讨论,发现核子有效质量m^*和平均场自旋轨道耦合力对巨共振能量有着重要的效应.     

时变元法及其应用

研究了一类特殊的变形体－增长体的粘弹性力学问题，建立了基于移动网格的时变元模型及其数值方法。作为算例，分别计算了高度随时间变化的柱体以及内径随时间变化的厚壁筒的应力应变历程。     

液体光击穿阈值的研究

运用声学基础理论,讨论了激光入射到液体中,激光能量与声信号强度间的变化关系.发现激光能量与声信号强度之间存在着对数线形关系.根据液体中光声信号的连续性,得到了一种求取液体光击穿阈值的新方法.