全文获取类型
收费全文 | 741篇 |
免费 | 45篇 |
国内免费 | 139篇 |
专业分类
化学 | 487篇 |
晶体学 | 9篇 |
力学 | 91篇 |
综合类 | 7篇 |
数学 | 142篇 |
物理学 | 189篇 |
出版年
2024年 | 2篇 |
2023年 | 17篇 |
2022年 | 32篇 |
2021年 | 25篇 |
2020年 | 35篇 |
2019年 | 31篇 |
2018年 | 19篇 |
2017年 | 30篇 |
2016年 | 37篇 |
2015年 | 24篇 |
2014年 | 25篇 |
2013年 | 38篇 |
2012年 | 54篇 |
2011年 | 54篇 |
2010年 | 30篇 |
2009年 | 39篇 |
2008年 | 48篇 |
2007年 | 35篇 |
2006年 | 43篇 |
2005年 | 22篇 |
2004年 | 30篇 |
2003年 | 23篇 |
2002年 | 14篇 |
2001年 | 14篇 |
2000年 | 23篇 |
1999年 | 21篇 |
1998年 | 20篇 |
1997年 | 25篇 |
1996年 | 27篇 |
1995年 | 8篇 |
1994年 | 14篇 |
1993年 | 13篇 |
1992年 | 10篇 |
1991年 | 7篇 |
1990年 | 9篇 |
1989年 | 10篇 |
1988年 | 3篇 |
1987年 | 1篇 |
1986年 | 1篇 |
1985年 | 6篇 |
1984年 | 1篇 |
1983年 | 1篇 |
1982年 | 1篇 |
1981年 | 1篇 |
1979年 | 1篇 |
1971年 | 1篇 |
排序方式: 共有925条查询结果,搜索用时 15 毫秒
81.
中国微量元素科学研究现状、意义、问题和对策 总被引:2,自引:2,他引:0
通过"从统计数字看现状"、"从科研成果看意义"、"从社会现象看问题"和"为持续发展想对策"等四个方面高度概括了中国微量元素科学研究走过的30多年历程,为该学科今后的持续发展提供了方向性的意见和讨论的基础。 相似文献
82.
Zhiming Wang Qingyu XuJingzhi Sun Jian PanHe Zhang 《Physica B: Condensed Matter》2011,406(8):1436-1440
Room temperature magnetocaloric effect in La-deficient bulk perovskite manganite La0.7MnO3−δ prepared by conventional solid-state reaction has been reported. The maximum value of the magnetic entropy change (about−1.32 J/kg K) and the refrigerant capacity (approximately close to 37 J/kg) had been obtained at 290 K corresponding to a magnetic field variation of 1 T for La0.7MnO3−δ. It is the strong Jahn-Teller coupling that changes Mn-O bond length and Mn-O-Mn bond angles and then the canted spin arrangement and induces the strong double-exchange coupling to a comparatively high magnetic transition temperature. This Curie temperature near room temperature with easy fabrication and higher chemical stability makes La0.7MnO3−δ a potential candidate as a working substance in magnetic refrigeration technology. 相似文献
83.
In this paper, we propose a well targeted algorithm (GAS algorithm) for detecting communities in high clustered networks by presenting group action technology on community division. During the processing of this algorithm, the underlying community structure of a clustered network emerges simultaneously as the corresponding partition of orbits by the permutation groups acting on the node set are achieved. As the derivation of the orbit partition, an algebraic structure r-cycle can be considered as the origin of the community. To be a priori estimation for the community structure of the algorithm, the community separability is introduced to indicate whether a network has distinct community structure. By executing the algorithm on several typical networks and the LFR benchmark, it shows that this GAS algorithm can detect communities accurately and effectively in high clustered networks. Furthermore, we compare the GAS algorithm and the clique percolation algorithm on the LFR benchmark. It is shown that the GAS algorithm is more accurate at detecting non-overlapping communities in clustered networks. It is suggested that algebraic techniques can uncover fresh light on detecting communities in complex networks. 相似文献
84.
文章利用正规对偶映射的定义,给出了任意Banach空间Lipschitz强伪压缩映射不动点的Ishikawa迭代收敛定理.该定理不仅推广了已知结果,而且还简化了目前相应结果的证明. 相似文献
85.
86.
Yao Qian Zhiyue Han Yinghao Zhang Zhiming Du Yan Zhao Yuezhen Yang Jingchang Zhang 《Journal of heterocyclic chemistry》2016,53(2):651-657
1,5‐diaminotetrazolium chloride (DATC) and 1,5‐diaminotetrazolium sulfate (DATS) were synthesized in this work. The structures of DATS and DATC were characterized. The single crystal of DATS was first cultured, and its structure was analyzed. The thermal behavior of DATS was investigated. The activation energy and pro‐exponential factor were calculated, Ek = 120.86 KJ/mol, Ak = 1012.96 s?1. The density, heat of formation, detonation pressure, and detonation velocity of DATS were first calculated. The detonation pressure and detonation velocity of DATS are P = 11.877 GPa, D = 5.617 km s?1, which are smaller than those of 1,5‐diaminotetrazolium nitrate (DATN) (P = 33.3GPa, D = 8.77 km s?1). 相似文献
87.
以MCl2和配体L(L=1,10-菲罗啉-5,6-二酮)为原料,合成了标题配合物MLCl2,M=NiⅡ,CuⅡ,ZnⅡ,并经元素分析、热谱、IR和摩尔电导表征.三者均为四配位的电中性配合物,热稳定性高于500K,易溶于DMF、DMSO和吡啶,可溶于乙腈和水.它们在DMF中于350nm和315nm附近显示出强的M-L荷移跃迁 相似文献
88.
A novel sulfonated tetraamine, di(triethylammonium)-4,4′-bis(3,4-diaminophenoxy)biphenyl-3,3′-disulfonate (BAPBDS), was successfully synthesized by nucleophilic aromatic substitution of 4,4′-dihydroxybiphenyl with 5-chloro-2-nitroaniline, followed by sulfonation and reduction. A high-temperature polycondensation of sulfonated tetraamine, non-sulfonated tetraamine (4,4′-bis(3,4-aminophenoxy)biphenyl) and 1,4,5,8-naphthalenetetracarboxylic dianhydride (a) or 4,4′-binaphthyl-1,1′,8,8′-tetracarboxylic dianydride (b) gave the poly[bis(benzimidazobenzisoquinolinones)] ionomers SPBIBI-a(x) or SPBIBI-b(x), where x refers to the molar percentage of the sulfonated tetraamine monomer. Flexible and tough membranes of high mechanical strength were obtained by solution casting and the electrolyte properties of the polymers were intensively investigated. The ionomer membranes displayed excellent dimensional and hydrolytic stabilities. Moreover, these novel membranes showed proton conductivities comparable to that of Nafion 117, especially at high temperature. In addition, the proton conductivities of the SPBIBI-a ionomer membranes were found to be higher than those of the SPBIBI-b ones due to the weakened acid–base interactions between the pyridinone ring and the sulfonic acid groups. The highest proton conductivity (0.174 S/cm) was obtained for the SPBIBI-a(100) membrane at 100 °C, with an IEC of 2.65 mequiv./g. A combination of excellent dimensional and hydrolytic stabilities indicated that the SPBIBI ionomers were good candidate materials for proton exchange membrane in fuel cell applications. 相似文献
89.
最初只称单晶短纤维为晶须,稍后结晶较好的多晶纤维也被称为"晶须",现在无定形纤维也归进了晶须专著,通过对晶须概念泛化过程的反思,希能澄清学术著作中10多年来相沿的一个模糊认知。 相似文献
90.
江西宜黄中华秋沙鸭自然保护区鱼类资源初步调查 总被引:1,自引:0,他引:1
2012年7月,对江西宜黄中华秋沙鸭自然保护区的鱼类资源展开初步调查。结果显示,该保护区分布有鱼类4目7科25种,兴凯鱊、棒花鱼、鲫为优势种,且渔获量丰富、鱼类个体较小。同时分析了保护区面临的潜在威胁,并提出了相应的保护措施。更多还原 相似文献