ChemInform Abstract: Cyclic Boron Clusters Enclosing Planar Hypercoordinate Cobalt,Iron, and Nickel

ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.     

预测搜索算法在图像相关中的应用

数字散斑相关方法在亚像素测量过程中运算量大,在对实时性要求较高的系统中该方法的应用受到了限制。提出了一种原理简单、搜索速度快、精度高的预测搜索算法,介绍了预测搜索算法的原理,并给出预测位移的公式。通过实验验证了对算法的精度、效率和鲁棒性,说明对数字散斑相关方法进行优化后,既不损失亚像素位移的计算精度又提高了图像处理的效率。     

利用改进的ADI方法实现单机千万节点的油水两相渗流数值模拟

针对实际油藏的非均质分布特征及其复杂的边界条件,本文通过引入迭代参数的压缩因子和放大因子,对现有的交替方向迭代法(ADI)进行改进,提出一种适用于大规模油藏数值模拟的新算法．改进的ADI 方法计算精度可靠,且与现有的算法相比计算效率有所提高．更为关键的是,ADI 算法将求解三维压力方程的七对角矩阵分解为三个方向的三对角矩阵依次迭代求解,所需的运算存储量大幅减少,最大的计算规模有了大幅的提升．使用改进的ADI 方法,在单机上成功实现了千万节点的油水两相渗流数值模拟．计算实例表明,在同等单机硬件条件下,改进ADI 算法的最大计算规模是现有算法的1.7 倍以上．     

单分散磁性纳米颗粒的制备及生物高分子在其上的组装

磁性纳米颗粒因其潜在的生物医学应用价值而成为纳米生物材料领域研究的前沿。本文综述了单分散磁性纳米颗粒的制备方法以及生物高分子在磁性纳米颗粒上的组装的研究进展。     

Poisson Structures for Dispersionless Integrable Systems and Associated W-Algebras

In analogy to the KP theory, the second Poisson structure for the dispersionless KP hierarchy can be defined on the space of commutative pseudodifferential operators . The reduction of the Poisson structure to the symplectic submanifold gives rise to W-algebras. In this Letter, we discuss properties of this Poisson structure, its Miura transformation and reductions. We are particularly interested in the following two cases: (a) L is pure polynomial in p with multiple roots and (b) L has multiple poles at finite distance. The w-algebra corresponding to the case (a) is defined as , where means the multiplicity of roots and to the case (b) is defined by where is the multiplicity of poles. We prove that -algebra is isomorphic via a transformation to U(1) with m= . We also give the explicit free fields representations for these W-algebras.     

Phase-transfer catalyzed glycolate conjugate addition

Cinchonine based phase-transfer catalysts were developed for enantioselective conjugate additions to electron deficient alkenes, including acylates, acrylonitrile, and chalcone. N-Trifulorobenzyl cinchoninium bromide 6 catalyst (20 mol %) in THF at −40 °C promoted the conjugate addition of arylketone glycolate 1 generating S-product 2 in good yields and selectivities. Catalyst, solvent, and base variations are presented along with conditions to convert the products to intermediates useful for multistep applications.     

Enhanced electrochemical performance of LiNi0.83Co0.12Mn0.05O2 cathodes with a fast-ion conductor Li0.33La0.56TiO3 coating layer

Journal of Solid State Electrochemistry - Ni-rich layered cathode materials LiNixCoyMn(1-x–y)O2 (x ≥ 0.8) suffer from capacity decay due to structural deterioration during...     

电感耦合等离子体质谱(ICP-MS)法测定农产品地土壤中铅、镉、铬消解方法的改进

采用赶酸电热板消解农产品地土壤中的重金属,电感耦合等离子体质谱(ICP-MS)法同时测定土壤中的铅、镉、铬。研究了酸体系及酸用量、赶酸电热板的升温程序,确定了最佳消解条件。通过统计50个批次土壤样品中加入的质控样,做出质控图,结果表明:各元素测定值均落在中心附近、上下警告线之内,批次内平行样品各元素相对标准偏差均小于5%。方法克服了传统的电热板消解法的缺点,弥补了高压罐消解法和微波消解法的不足,方法快速、准确,适合于大批量样品的分析。