Corrosion inhibition of ammonium molybdate for AA6061 alloy in NaCl solution and its synergistic effect with calcium gluconate

The corrosion inhibition of ammonium heltamolybdate (AH) and calcium gluconate (CG) for AA6061 alloy in 3% NaCl solution was investigated by the electrochemical measurements. It indicates that AH inhibits the corrosion of AA6061 alloy and acts as an anodic inhibitor. Maximum inhibition efficiency reaches 74.3% at the concentration of 1 × 10^?4 mol.l^?1 AH. The results of the electrochemical studies reveal AH is physically adsorbed on the AA6061 alloy surface and the adsorption follows Langmuir isotherm. The combination of AH and CG enhances the inhibition efficiency to 95.9%. The enhanced inhibition is attributed to the promotion of AH adsorption by CG. The mixture of AH and CG is a mixed‐type inhibitor and renders the corrosion potential to more positive values. Copyright © 2011 John Wiley & Sons, Ltd.     

离散差分变分Hamilton系统的Lie对称性与Noether守恒量

研究离散差分Hamilton系统的Lie对称性与Noether守恒量. 根据扩展的时间离散力学变分原理构建Hamilton系统的差分动力学方程.定义离散系统运动差分方程在无限小变换群下的不变性为Lie对称性, 导出由Lie对称性得到系统离散Noether守恒量的判据. 举例说明结果的应用. 关键词： 离散力学 差分Hamilton系统 Lie对称性 Noether守恒量     

Copolymerization of styrene and norbornene with β‐diketiminato nickel/methylaluminoxane catalytic system

Styrene–norbornene (S‐N) copolymerizations were carried out using β‐diketiminato nickel complexes CH{C(CF₃)NAr}₂NiBr (Ar = 2,6‐ⁱPr₂C₆H₃, 1 ; Ar = 2,6‐Me₂C₆H₃, 2 ) in the presence of methylaluminoxane. The influence of the comonomer feed content and polymerization temperature on the conversion and composition of the copolymers with the catalytic system was investigated. An increase in the feed ratio of S/N led to an increase in the incorporated styrene content of the resulting copolymer. NMR characterization of the copolymers generated with the catalytic systems showed that the random S‐N copolymers are produced. Differential scanning calorimetric determination of the copolymers shows higher T_g values than polystyrene, and gel permeation chromatographic measurements have shown that the copolymers possess rather narrow molecular weight distributions, suggesting that the copolymerization take place at a single active site. Copyright © 2012 John Wiley & Sons, Ltd.     

Biological evaluation of novel selenazole‐based compounds as potential thioredoxin reductase inhibitors

Recently, thioredoxin reductase as a target for treatment of tumors has attracted the attention of scientists. 1,2‐[Bis(1,2‐benzisoselenazolone‐3(2 H)‐ketone)]ethane (ethaselen, BBSKE, PCT: CN02/00412), designed and synthesized previously, is an effective thioredoxin reductase inhibitor; presently it is in phase II clinical trials, targeting gastric cancer, lung cancer and colon cancer. To seek more novel and effective anticancer drugs, we have developed many selenazole‐based compounds. Evaluation of the thioredoxin reductase inhibitory effect and investigation of the mechanism of anticancer drugs require abundant thioredoxin reductase, but since commercial thioredoxin reductase is expensive its use is often limited. Therefore, the preparation of thioredoxin reductase is necessary. Base on the above investigation, in this work we have prepared thioredoxin reductase and evaluated selenazole‐based compounds, and found that 44 compounds have high inhibitory effect on thioredoxin reductase with IC₅₀ < 10 µ m , of which 16 compounds have IC₅₀ values below 1 µ m . This is helpful in investigating and elucidating the mechanism of this kind of compound. Copyright © 2012 John Wiley & Sons, Ltd.     

Cyclopalladated ferrocenylimine as an efficient catalyst for the syntheses of diarylmethane derivatives

The cyclopalladated ferrocenylimine adducts Ia , Ib , Ic were evaluated in the Suzuki cross‐coupling reaction of benzyl halides with arylboronic acids. The tricyclohexylphosphine adduct Ia exhibited highly catalytic activity for the coupling of aryl and heteroaryl boronic acids containing various functional groups with benzylic bromides and chlorides (up to 99% yield), furnishing diarylmethane derivatives with low catalyst loading (1 mol%). It is worth noting that catalyst Ia can be reused eight times without losing its catalytic activity. Copyright © 2012 John Wiley & Sons, Ltd.     

Analytical Solution to Subsurface Air Pressure in a Three-Layer Unsaturated Zone with Atmospheric Pressure Changes

In this study, a solution to one-dimensional vertical airflow induced by the time-dependent atmospheric pressure fluctuations is developed in a three-layer unsaturated zone. The discrete atmospheric pressure data are transformed into a continuous boundary condition using the Fourier series analysis. The solution is applied to interpret the field air pressure data in a three-layer unsaturated zone reported in previous studies. The new solution improves the previous solution by reducing the required data measurement and input. The new solution is found to be accurate enough for the purpose of this study by comparing with a numerical solution developed in COMSOL Multiphysics. Given the necessary hydrogeological parameters, the new solution is capable of calculating the air permeability of each layer above a specified depth where the air pressures are known. Sensitivity analysis of the new solution shows that location, thickness, and air permeability of the less permeable layer impose large influence on the propagation of the atmospheric pressure fluctuations. Variations of air-filled porosity in soil layers in/below the less permeable layer may lead to greater amplitude attenuation and phase lag of air pressure than those in soil layers above the less permeable layer.     

Modified characteristic finite difference fractional step method for moving boundary value problem of percolation coupled system

For the coupled system with moving boundary values of multilayer dynamicsof fluids in porous media,a characteristic finite difference fractional step scheme appli-cable to the parallel arithmetic is put forward.Some techniques,such as the change ofregions,the calculus of variations,the piecewise threefold quadratic interpolation,themultiplicative commutation rule of difference operators,the decomposition of high orderdifference operators,and the prior estimates,are adopted.The optimal order estimatesin the l2norm are derived to determine the error in the approximate solution.This nu-merical method has been successfully used to simulate the flow of migration-accumulationof the multilayer percolation coupled system.Some numerical results are well illustratedin this paper.     

Penalty finite element method for Navier–Stokes equations with nonlinear slip boundary conditions

The penalty finite element method for Navier–Stokes equations with nonlinear slip boundary conditions is investigated in this paper. Since this class of nonlinear slip boundary conditions include the subdifferential property, the weak variational formulation is a variational inequality problem of the second kind. Using the penalty finite element approximation, we obtain optimal error estimates between the exact solution and the finite element approximation solution. Finally, we show the numerical results which are in full agreement with the theoretical results. Copyright © 2011 John Wiley & Sons, Ltd.