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51.
CO是碳氢燃料不完全燃烧的重要产物,常常被作为反应燃烧效率的标志物,燃烧场CO组分浓度的精确测量对提高燃烧效率、减少污染物排放具有重要意义。离轴积分腔输出光谱(OA-ICOS)是一种利用物质对激光的特异性吸收,实现对该物质分析和测量的技术,具有非接触、稳定和高灵敏度等优点。针对燃烧场CO浓度低,背景信号干扰强等特点,采用分布反馈式(DFB)激光器搭建基于离轴积分腔输出光谱的CO浓度测量系统,通过直接吸收光谱的测量方法实现对高温燃烧场CO浓度测量。利用仿真模拟的方法,在所用激光器中心波长的附近选出了常温下谱线强度较为突出,高温下不受其他燃烧产物干扰的第一泛频带R(10)吸收谱线。通过固定光程池对比吸光度的方法标定了OA-ICOS系统的有效光程;通过比较不同扫描频率下吸收谱线的信噪比和线型拟合残差标准差,得到最佳波长扫描频率;通过测量不同浓度CO混合气体的吸收信号分析了系统误差。探究了不同燃烧情况下CH4/Air预混平焰炉上CO的产生情况,根据燃烧场测量区域温度分布情况描述了温度分布不确定度对CO测量结果的影响。当量比为1.0时,在10 ms的测量时间分辨率下,噪声等... 相似文献
52.
投影寻踪分类建模理论的新探索与实证研究 总被引:2,自引:0,他引:2
从理论上分析了正确的投影向量系数(权重)约束条件是∑_(j=1)~2a_j~2=1和1≥0_j≥-1;从理论和实证两个视角证实采用约束条件∑_(j=1)~p a_j~2=1和1≥a_j≥0时逆向指标或对正向指标采用了错误的归一化方式时的权重必定等于"0"。采用正确的约束条件,针对同一密度窗宽R值,实证分析发现和从理论上证明了在投影寻踪分类(PPC)建模中改变指标归一化方式前后,权重是互为相反数的重要特性等三个定理和二个推理,改变指标归一化方式不影响任意两样本投影值之间的距离和投影指标函数值。提出了正确使用PPC进行建模的基本原则和步骤、判定指标属性(正向指标或者逆向指标)的准则等,实现了投影寻踪探索性研究和验证性分析的有机统一。 相似文献
53.
A variety of DNA-based probes are utilized for the detections of multiple analytes and DNA nanotechnology has been thriving for recent decades and achieving numerous nanostructures,mainly focusing on DNA morphology modulation and multifunctional systems engineered into to the complicated works.Among the numerous detections,fluorescence method is a non-invasive,highly selective and sensitive means for varieties of applications,but their emissions are often compromised by the aggregation-caused quenching(ACQ)effect,which weakens their applications.The aggregation induced emission luminogens(AIEgens)are created with non emissive or weakly emissive in a low concentration but emit strong fluorescence in a high concentration with aggregated states.Herein,numerous functionalized AIEgens have been emerged and used for detection and imaging and DNA-modified AIEgen probes are introduced.In this vein,here we report the progress on DNA-modified AIEgen probes in recent years and highlight their conjugation strategies including covalent bonding,electrostatic interaction and their applications of biosensing.Moreover,multiple DNA strands are needed to introduce into the DNA-modified AIEgen probes for more purposes.At the end,some challenges are mentioned to discuss the new trend of DNA-modified AIEgen probes. 相似文献
54.
楼启正 《光谱学与光谱分析》2007,27(5):924-927
采用毛细管气相色谱-傅里叶变换红外光谱联用技术法(气红联用,GC-FTIR),结合计算机检索对标准桃金娘油化学成分进行分析和鉴定,用气相色谱面积归一化法测定各组分的相对百分含量;经毛细管色谱从标准桃金娘油中分离出12个峰,并且采用FTIR法确认了所含的化合物。标准桃金娘油主要成分为三种单萜,分别为1,8-桉叶素、D-柠檬烯和α-蒎烯,含量分别为46.35%,36.83%和14.70%,三者占总量的97.88%,分析结果与GC-MS分析相一致。由于GC-FTIR分析能确定出经气相色谱分离后的有机物的异构体,故与GC-MS分析相比较,此法具有更广泛的应用价值。该研究可为综合利用开发桃金娘科植物提供科学依据。 相似文献
55.
General expressions used for transforming raw laser-induced fluorescence (LIF) intensity into the population and alignment parameters of a symmetric top molecule are derived by employing the density matrix approach. The molecular population and alignment are described by molecular state multipoles. The results are presented for a general excitation-detection geometry and then applied to some special geometries. In general cases, the LIF intensity is a complex function of the initial molecular state multipoles, the dynamic factors and the excitation-detection geometrical factors. It contains a population and 14 alignment multipoles. How to extract all initial state multipoles from the rotationally unresolved emission LIF intensity is discussed in detail. 相似文献
56.
57.
Ci-bo LOU Li-qin TANG Dao-hong SONG Xiao-sheng WANG Jing-jun XU Zhi-gang CHEN 《Frontiers of Physics in China》2008,3(1):1-12
The study of wave propagation in periodic systems is at the frontiers of physics, from fluids to condensed matter physics,
and from photonic crystals to Bose-Einstein condensates. In optics, a typical example of periodic system is a closely-spaced
waveguide array, in which collective behavior of wave propagation exhibits many intriguing phenomena that have no counterpart
in homogeneous media. Even in a linear waveguide array, the diffraction property of a light beam changes due to evanescent
coupling between nearby waveguide sites, leading to normal and anomalous discrete diffraction. In a nonlinear waveguide array,
a balance between diffraction and self-action gives rise to novel localized states such as spatial “discrete solitons” in
the semi-infinite (or total-internal-reflection) gap or spatial “gap solitons” in the Bragg reflection gaps. Recently, in
a series of experiments, we have “fabricated” closely-spaced waveguide arrays (photonic lattices) by optical induction. Such
photonic structures have attracted great interest due to their novel physics, link to photonic crystals, as well as potential
applications in optical switching and navigation. In this review article, we present a brief overview on our experimental
demonstrations of a number of novel spatial soliton phenomena in light-induced photonic bandgap structures, including self-trapping
of fundamental discrete solitons and more sophisticated lattice gap solitons. Much of our work has direct impact on the study
of similar discrete phenomena in systems beyond optics, including sound waves, water waves, and matter waves (Bose-Einstein
condensates) propagating in periodic potentials.
相似文献
58.
Dielectric Properties of Multilayered Ba0.5Sr0.5TiO3 Thin Films Deposited on ITO-Coated Corning 1737 Glass by rf Magnetron Sputtering 总被引:1,自引:0,他引:1 下载免费PDF全文
A new stacking method via variation ofsubstrate temperature in rfmagnetron sputter is used to fabricate polycrystalline/polycrystalline Ba0.5Sr0.5TiO3 thin films with higher dielectric constant, higher breakdown strength and lower leakage current densities than those prepared by a conventionM deposition method. The improved figure of merit G (ε0εrEb) of the Ba0.5Sr0.5TiO3 thin films implies that they are a feasible insulation layer for thin film electroluminescent devices. 相似文献
59.
利用奇性流形的任意性,选用不同的展开函数及非标准截断展开于KdV方程,得到了许多用复杂隐函数表示的精确解.
关键词: 相似文献
60.
导数光谱法测定污水中十二烷基苯磺酸钠 总被引:2,自引:0,他引:2
本文介绍了用导数分光光度法直接定量分析污水中十二烷基苯磺酸钠的方法。本法消除了混浊背景干扰,操作简便快速。应用于实际污水样品的分析,获得了良好的结果,十二烷基苯磺酸钠的校准曲线线性范围为0-82mg/L。 相似文献