An Efficient Solid-State Synthesis of N-Aryl-2-phenyldiazenecarboxamides

The subject of organic solid-state synthesis is a fascinating one. It has many advantages such as high efficiency and selectivity, easy separation and purification, mild reaction conditions, and environmental acceptability1. In recent years, this method has been widely used in a variety of organic reactions including substitution2, condensation3, oxidation-reduction4, rearrangement5 and elimination6. However, the solid state reaction using K3Fe(CN)6/KOH to oxidize substituted semicarbazides…     

VCSEL with reticular electrode and larger emitting aperture and its optoelectronic characteristics

The enlargement of the emitting aperture is usually one of the important methods of increasing vertical- cavity surface-emitting laser （VCSEL） optical output power. However, in a VCSEL with a larger aperture, the inhomogeneity in the injected current often causes inhomogeneous or even no emission. To solve this problem and to increase VCSEL output power, as well as to improve its thermal characteristics, we develop a new type of injected VCSEL with a larger aperture and a reticular electrode, where the conventional circular injection electrode of the P side is turned into a reticular one, and the heat sink is on the N side. The tests of the new VCSEL show an improvement in homogeneity in not only the injected current but also the emission intensity. The optical output power is also considerably increased, and the device optoelectronic performance is improved.     

A Novel Palladium-Catalyzed Reaction and Its Application in Preparation of Derivatives of Stilbazols

Many derivatives of stilbazoles have strong biological activities and pharmacological actions. For instance, (-substituent-(E)-4-styrylpyridines can be used as cytokinin analogues1. A series of N-substituted tetrahydro (phenylethenyl) pyridine derivatives were reported in vitro against both nicotinic and muscarinic receptors derived from rat cerebral cortax2. Therefore they can be used as candidates to develop new drugs for treatment of some diseases. On the other hand, this kind of compounds…     

Photochemical Reduction of Aromatic Imines by 2-Phenyl-N, N-dimethylbenzimidazoline

Reduction of C=N double bonds has been recognized as an important reaction both in organic chemistry and bio-chemistry1. Hantzsch 1,4-dihydropyridine (HEH, one of NADH model compounds) has been reported as a reductive reagent for imines2. However, application of dihydropyridines as practical reducing reagents in organic synthesis is limited because of their instability3. Like NADH models, 2-phenyl-N, N-dimethylbenzimidazoline (PDMBI) is an efficient electron and hydrogen donor (Eox = 0…     

半导体激光器的超高频调制

本文从理论上分析了半导体激光器的超高频调制特性和脉动电流引起的张弛振荡现象。分析了国产DHGaAlAs半导体激光器调制过程中出现的一些问题。实验证明,采用微带匹配技术,可使这类激光器的调制频率达1.3GHz。     

WEAK CONVERGENCE OF SOME DIRICHLET SERIES

1 Besicovitch Inner ProductIll this paper, we consider Dirichlet serie8where an, tL = 1, 2,' ', are complex nunlbers. They are Besicovitch almost periodic functionsWe see the 8ystenl {e.(t); e.(t) = e--it Iog 1l, 71 = l, 2,' .} fOrnis a1l orthollor11la1 systelll witl1respect to tI1e BesicovitcI1 iIl1ler productThell we call fOrm the gelleralized trigouolnetrical polynolIlialsAccording to tl1e idea developed il1 [l],[2], auy Dirichlet seriesis weakly convergent over K witll respect to …     

Synthesis and Characterization of A Novel Cholesteric Liquid Crystalline Containing Carboxyl Group

A novel liquid crystal compound with a carboxyl group at one end, cholest-5-en-3-ol-(3β) hydrogen decanedioate (1) was successfuly prepared by the reaction of cholesterol with sebacoxl chloride. Its chemical structure and liquid crystalline properties were characterized by FTIR.CNMR,HNMR,POM and DSC. The compound with an active carboxyl group shows themortropic liquid crystalline behaviour.     

氟代糖的合成

本文综述了氟代糖合成的新进展及利用选择性氟化合成具有生物活性的物质。     

FeCl_3·6H_2O Catalyzed Reaction of Aromatic Aldehydes with 5, 5-Dimethyl-1, 3-cyclohexandione in Ionic Liquids

Room temperature ionic liquids with low melting point (<100℃) salts represent a new class of non-molecular, ionic solvents. Especially those based on the 1-N-alkyl-3- methylimidazolium cations, have shown great promise as an attractive alternative to conventional solvents for catalytic reactions1. On the other hand, FeCl3·6H2O was considered to be an environmentally benign Lewis acid and has been used successfully in several kinds of organic reactions2. Recently we have focused our interes…