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91.
Ji‐Hong Zhao Chun‐Hao Li Zhen‐Hua Lv Ying Xu 《Surface and interface analysis : SIA》2013,45(11-12):1667-1672
The regular micrometer‐scale triangular arrays were formed using ultrafast femtosecond laser irradiation on (111) surface of silicon wafer immersed in KOH solution (0.1 g/ml). At low laser fluence, the resulting surface is covered by triangular pits microstructures, whereas at high laser fluence, the structures are transformed to multilayer‐triangular stacks‐microstructures. The number of triangular stacks layer increased as the laser fluence increased. The formation of triangle microstructure arrays depends on both silicon surface crystallographic orientation and the concentration of KOH solution. Either for lower KOH solution concentration (0.02 g/ml) or other silicon crystallographic orientation, triangle arrays cannot be obtained. We attribute the formation of triangular microstructure arrays to the laser‐assisted chemical etching process. Copyright © 2013 John Wiley & Sons, Ltd. 相似文献
92.
Junnan Lv Yiqun Chen Honglei Pei Wenhan Yang Zhimin Li Bing Dong Yunhe Cao 《Applied biochemistry and biotechnology》2013,169(8):2326-2340
The β-mannanase gene (1,029 nucleotide) from Bacillus subtilis MAFIC-S11, encoding a polypeptide of 342 amino acids, was cloned and expressed in Pichia pastoris. To increase its expression, the β-mannanase gene was optimized for codon usage (mannS) and fused downstream to a sequence-encoding modified α-factor signal peptide. The expression level was improved by 2-fold. This recombinant enzyme (mannS) showed its highest activity of 24,600 U/mL after 144-h fermentation. The optimal temperature and pH of mannS were 50 °C and 6.0, respectively, and its specific activity was 3,706 U/mg. The kinetic parameters V max and K m were determined as 20,000 U/mg and 8 mg/mL, respectively, representing the highest ever expression level of β-mannanase reported in P. pastoris. In addition, the enzyme exhibited much higher binding activity to chitin, chitosan, Avicel, and mannan. The superior catalytic properties of mannS suggested great potential as an effective additive in animal feed industry. 相似文献
93.
Jian-Feng Zhou Xiao-Jun Sun Feng-Wen Lou Meng Lv Lu-Lu Zhang 《Research on Chemical Intermediates》2013,39(3):1401-1408
A series of 3,3′-(4-arylpyridine-2,6-diyl)bis(2H-chromen-2-one) derivatives have been synthesized by the one-pot, three-component reaction of 3-acetylcoumarin, an aromatic aldehyde, and ammonium acetate in acetic acid under microwave irradiation. This procedure has the major advantages of short reaction time, good yields, low energy consumption, easy operation, and environmental friendliness. All of the products were characterized by IR and NMR spectroscopy, MS, and elemental analysis. 相似文献
94.
Dr. Qiuhua Zhu Lan Huang Dr. Zhipeng Chen Sichao Zheng Longyun Lv Dr. Zhibo Zhu Prof. Derong Cao Prof. Huanfeng Jiang Prof. Shuwen Liu 《Chemistry (Weinheim an der Bergstrasse, Germany)》2013,19(4):1268-1280
A new series of C‐6 unsubstituted tetrahydropyrimidines 6 have been directly synthesized via a convenient urea‐catalyzed chemoselective five‐component reaction (5CR) under mild conditions. Compounds 6 show typical aggregation‐induced emission enhancement (AIEE) characteristics because they are practically no emissive in solution but emit blue or green fluorescence in aggregates with fluorescence yield up to 93 %. One of the 5CR products, 6 aa , exhibits blue‐ and green‐fluorescence aggregates (bf‐ and gf‐aggregates). The bf‐ and gf‐aggregates are prepared under different conditions and proved to result from different J‐aggregations by single‐crystal X‐ray analysis. In addition, the bf‐ and gf‐aggregates of 6 aa show unusual size‐independent emission (SIE) characteristics because their maximum emission wavelengths in different sizes (suspension particles, film, powder and crystals) are the same, 434 and 484 nm, respectively. Based on the obtained experimental results, the 5CR mechanism, the origins of AIEE and SIE characteristics are discussed. 相似文献
95.
Chinese regional energy efficiency change and its determinants analysis: Malmquist index and Tobit model 总被引:2,自引:0,他引:2
China becomes the largest energy consumer in 2010 but its energy productivity is well below the world average. To meet China’s fast growing energy using, energy efficiency should be especially emphasized under China’s energy policy. This paper focuses on the regional level of energy efficiency change in China. And we analyze total factor energy efficiency for 30 Chinese provinces over the period 1998–2009 using Malmquist index method and Tobit analysis. The Malmquist estimation results suggest there is a dropping change trend of energy productivity growth. Chinese energy efficiency still faces with huge regional disparity, but the energy technical efficiency reflects convergence in the nationwide and west region. As a result of Tobit regression, we find that industrial structure, energy consumption structure and institutional factor have different influences on energy efficiency. 相似文献
96.
Current research on pedestrian dynamics mainly focuses on the interactions among isolated individuals, the impact of the presence of groups is not fully considered. In recent 5 years, researchers have started to investigate pedestrian group movement. The aim of this work is to explore the local behavior of pedestrian groups by questionnaires and field observation. Survey study focused on pedestrians' psychology when walking in groups, which included five parts: group size, interpersonal distance, spatial relationship among group members, speed adjustment of group members, information transmission, and acid action among group members. Meantime a field observation was carried out to study group movement characteristics, which contained speed, step frequency, offset angle and interpersonal distance. The survey results show that group members have a closer interpersonal distance, faster information transmission and plenty of acid action. Conversely, group walking has a negative influence on pedestrian's speed, step frequency by comparing with the way isolated pedestrian walks. In addition, it is found that for a certain group, the group members are able to keep movement consistent. Also there exists obvious movement diversity among different group types (male dyads, female dyads, couple groups, and ordinary‐friend groups) because of different gender and social relationship. Ultimately the results will be more promising for helping to model the movement of pedestrian groups. © 2014 Wiley Periodicals, Inc. Complexity 20: 87–97, 2015 相似文献
97.
98.
Fengyan Wang Zhang Liu Bing Wang Liheng Feng Libing Liu Fengting Lv Yilin Wang Shu Wang 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2014,126(2):434-438
The development of biomolecular fiber materials with imaging ability has become more and more useful for biological applications. In this work, cationic conjugated polymers (CCPs) were used to construct inherent fluorescent microfibers with natural biological macromolecules (DNA and histone proteins) through the interfacial polyelectrolyte complexation (IPC) procedure. Isothermal titration microcalorimetry results show that the driving forces for fiber formation are electrostatic and hydrophobic interactions, as well as the release of counterions and bound water molecules. Color‐encoded IPC fibers were also obtained based on the co‐assembly of DNA, histone proteins, and blue‐, green‐, or red‐ (RGB‐) emissive CCPs by tuning the fluorescence resonance energy‐transfer among the CCPs at a single excitation wavelength. The fibers could encapsulate GFP‐coded Escherichia coli BL21, and the expression of GFP proteins was successfully regulated by the external environment of the fibers. These multi‐colored fibers show a great potential in biomedical applications, such as biosensor, delivery, and release of biological molecules and tissue engineering. 相似文献
99.
The passive film of iron showed n‐type semiconductor characteristic in borate buffer solution, and its donor concentration increased slightly after tensile strain in the present study. However, comparing with solution‐annealed sample, the anodic passive film formed on tensile‐strained one was highly protective. The more dislocations on tensile‐strained sample promoted the diffusion of iron and oxygen vacancy. Moreover, more donor density (mainly oxygen vacancies) promoted the diffusion of oxygen. They all facilitated tensile‐strained sample to form Fe2O3 and thicker passive film on the surface. More Fe2O3 and thicker passive film on the surface of tensile‐strained iron could improve corrosion resistance. Copyright © 2014 John Wiley & Sons, Ltd. 相似文献
100.
A convenient and regioselective one-pot synthesis of 3-chloride or 3-bromide quinoline derivatives was achieved through a Grignard addition reaction by alkynyl Grignard regent to o-trifluoroacetyl aniline and a Cu(II)-catalyzed cyclization–halogenation tandem reaction with aqueous HCl or HBr as electrophilic reagent. 相似文献