国际核能应用及其前景展望与我国核电的发展

核能的和平利用始于20世纪50年代，那时美国、前苏联等工业发达国家在进行核军备竞赛的同时，也竞相发展核电站．1954年，前苏联建成电功率为5千千瓦的试验性原子能电站，为世界上首座核电站；1957年，美国建成电功率为9万千瓦的希平港原型核电站；这些成就证明了利用核能发电的技术可行性．国际上把上述试验性和原型核电机组称为第一代核电机组．     

光的偏振特性在机动车安全驾驶中的应用

根据光的偏振特性,利用偏振片制作机动车前大灯和偏振片眼镜,实践证明,可以提高机动车夜间行车的安全性.     

Adaptive Runge–Kutta discontinuous Galerkin method for complex geometry problems on Cartesian grid

A Cartesian grid method using immersed boundary technique to simulate the impact of body in fluid has become an important research topic in computational fluid dynamics because of its simplification, automation of grid generation, and accuracy of results. In the frame of Cartesian grid, one often uses finite volume method with second order accuracy or finite difference method. In this paper, an h‐adaptive Runge–Kutta discontinuous Galerkin (RKDG) method on Cartesian grid with ghost cell immersed boundary method for arbitrarily complex geometries is developed. A ghost cell immersed boundary treatment with the modification of normal velocity is presented. The method is validated versus well documented test problems involving both steady and unsteady compressible flows through complex bodies over a wide range of Mach numbers. The numerical results show that the present boundary treatment to some extent reduces the error of entropy and demonstrate the efficiency, robustness, and versatility of the proposed approach. Copyright © 2013 John Wiley & Sons, Ltd.     

Resonance problems for the p-Laplacian systems

Two existence theorems of the solutions are obtained for the p-Laplacian systems at resonance under a Landesman-Lazer-type condition by critical point theory.     

参数曲线的全局凸性判别条件

基于平面曲线的二次微商,导出了二重点的判别条件,结合参数曲线的局部凸性条件,得到了参数闭曲线的充要条件。给出了参数曲线的拐点判别条件,从而得到了参数曲线局部凸的充要条件。     

Bay区取代苝二酰亚胺分子构型及聚集调控:邻位甲基位阻效应

设计并合成了2种苝二酰亚胺分子PBI1和PBI2,研究了bay区的苯氧基团邻位甲基取代对分子构型及分子聚集的影响.通过对单晶结构的分析,发现邻位甲基的引入明显影响苝二酰亚胺分子构型,使得4个苯氧基呈中心对称分布.由于甲基的空间位阻效应,有效地减弱了分子间π-π相互作用,从而提高了分子的溶解性与溶液加工成膜性.研究结果表明,在π共轭分子结构中的关键位置引入小的甲基取代基能够显著调控分子的聚集行为,有效减少光电材料分子中非光电活性(增溶性基团)的含量,对光电材料分子的设计合成具有重要的指导意义.     

Progress in fluorene-based wide-bandgap steric semiconductors

Molecular bulks are favorable for the thermal and morphological stability in organic wide-bandgap semiconducting polymers with potential applications in both information and energy electronics. In this review, we present our progress in the design of fluorene-based bulky semiconductors with a fractal four-element pattern. Firstly, we established one-pot methods to spirofluorenes, especially spiro[fluorene-9,9′-xanthene](SFX) serving as the next-generation spiro-based semiconductors. Secondly, we observed the supramolecular forces at the bulky groups and discovered the supramolecular steric hindrance(SSH) effect on polymorphisms, nanocrystals as well as device performance. Thus, a synergistically molecular attractor-repulsor theory(SMART) was proposed for the control of nanocrystal morphology, thin film phase and morphology. Thirdly, the third possible type of defects has been identified to generate green band(g-band) emission in widebandgap semiconductors by the introduction of molecular strain design of cyclofluorene. Finally, the first bulky polydiarylfluorene with highly crystalline and β conformation was achieved by an attractor-repulsor design of tadpole-shape monomer, which offered an effective platform to fabricate stable wide-bandgap semiconducting devices. All the discoveries offer the solid basis to break through bottlenecks of organic/polymer wide-bandgap semiconductors by the improvements of overall performances.