垂直场下磁性薄膜中的铁磁共振现象

将铁磁共振频率看成外磁场的函数, 讨论了垂直场下磁性膜中的铁磁共振现象. 结果显示: 当外磁场平行于膜面, 并考虑磁膜具有垂直磁晶各向异性情形时, 其磁共振频率随外磁场的变化分为高频支和低频支两种情况, 具体的依赖关系取决于磁膜内磁晶的各向异性; 当外磁场垂直于膜面, 其磁共振频率随外磁场的关系仅存在一支, 一般地, 磁共振频率随外磁场的增加单调地非线性减小, 但当立方磁晶各向异性场H_k1 与单轴磁晶各向异性场H_a之比值介于2/3 < H_k1/H_a <1时, 其磁共振频率随外磁场的增加单调增加, 这与相关的实验结果一致. 研究结果表明: 磁薄膜中有无垂直于膜面的磁各向异性可以通过其磁共振谱的测量进行辨析.     

Ga掺杂对ZnO纳米结构可见光发射的抑制效应

采用碳热还原反应和原位掺杂的方法制备了不同Ga掺杂浓度的ZnO纳米结构. X射线衍射 显示掺杂纳米结构中为单一的氧化锌纤锌矿结构. 扫描电子显微镜 观测发现随掺杂浓度的增大, 纳米结构的形貌逐渐从纳米六棱柱变为纳米锥.光致发光 和X射线光电子能谱 测量分别发现随着掺杂浓度升高, 纳米结构的可见发光强度和其中空位 氧峰相对强度逐渐减小直至消失, 两者存在很强的相关性. 上述结果为ZnO可见光发射的氧空位机理提供了新的实验证据. 对Ga掺杂抑制纳米结构中氧空位的原因进行了分析.     

Optimized growth and dielectric properties of barium titanate thin films on polycrystalline Ni foils

Barium titanate(BTO) thin films were deposited on polycrystalline Ni foils by using the polymer assisted deposition(PAD) technique.The growth conditions including ambient and annealing temperatures were carefully optimized based on thermal dynamic analysis to control the oxidation processing and interdiffusion.Crystal structures,surface morphologies,and dielectric performance were examined and compared for BTO thin films annealed under different temperatures.Correlations between the fabrication conditions,microstructures,and dielectric properties were discussed.BTO thin films fabricated under the optimized conditions show good crystalline structure and promising dielectric properties with εr～ 400 and tan δ < 0.025 at 100 kHz.The data demonstrate that BTO films grown on polycrystalline Ni substrates by PAD are promising in device applications.     

Fractional charges and fractional spins for composite fermions in quantum electrodynamics

By using the Faddeev-Senjanovic path integral quantization method, we quantize the composite fermions in quantum electrodynamics (QED). In the sense of Dirac’s conjecture, we deduce all the constraints and give Dirac’s gauge transformations (DGT). According to that the effective action is invariant under the DGT, we obtain the Noether theorem at the quantum level, which shows the fractional charges for the composite fermions in QED. This result is better than the one deduced from the equations of motion for the statistical potentials, because this result contains both odd and even fractional numbers. Furthermore, we deduce the Noether theorem from the invariance of the effective action under the rotational transformations in 2-dimensional (x, y) plane. The result shows that the composite fermions have fractional spins and fractional statistics. These anomalous properties are given by the constraints for the statistical gauge potential.     

Synthesis, structure, and biological activity of novel (oxdi/tri)azoles derivatives containing 1,2,3-thiadiazole or methyl moiety

To develop novel inhibitors of ketol-acid reductoisomerase, a series of (oxdi/tri)azoles derivatives was synthesized and characterized by (1)H NMR, MS, elemental analyses, and crystallography. According to the biological activities of these compounds obtained both in vivo and in vitro, compound 4-cyclopropyl-3-((4-fluorobenzyl)thio)-5-methyl-4H-1,2,4-triazole showed excellent KARI inhibitory activity (100% at 100?μg?mL?(-1) in vitro). In addition, most of the title compounds exhibited good herbicidal activity against Brassica campestris in vivo.     

The 1/f noise in multiwalled carbon nanotubes

The $1/f$ noise in multiwalled carbon nanotubes bundles has been investigated between the frequency range of 0.1 to 30 Hz. At room temperature the noise spectrum is standard 1/f, and its level is proportional to the square of the bias voltage. With decreasing temperature the noise level also decreases. At 4.2 K the noise level follows a non-monotonic dependence against the bias voltage, showing a peak at a certain bias voltage, meanwhile its frequency dependence also deviates from the 1/f trend. This anomalous behaviour is discussed within the picture of environmental quantum fluctuation of charge transport in the samples.     

Measurements of NO2 mixing ratios with topographic target light scattering-differential optical absorption spectroscopy system and comparisons to point monitoring technique

A topographic target light scattering-differential optical absorption spectroscopy(ToTaL-DOAS) system is developed for measuring average concentrations along a known optical path and studying surface-near distributions of atmospheric trace gases.The telescope of the ToTaL-DOAS system points to targets which are located at known distances from the measurement device and illuminated by sunlight.Average concentrations with high spatial resolution can be retrieved by receiving sunlight reflected from the targets.A filed measurement of NO2 concentration is performed with the ToTaL-DOAS system in Shijiazhuang in the autumn of 2011.The measurement data are compared with concentrations measured by the point monitoring technique at the same site.The results show that the ToTaL-DOAS system is sensitive to the variation of NO2 concentrations along the optical path.     

表面润湿法合成β沸石体系中晶种作用的研究

系统研究了表面润湿法合成β沸石的体系中,干晶种、润湿态晶种、异晶晶种(Y沸石、ZSM 5沸石)以及碱处理β沸石晶种在此晶化体系中的作用.采用β沸石产品及异晶作晶种时,可使产品的相对结晶度稍有提高,但对沸石微晶核的结构导向作用不明显.经浓碱液处理20min后的β沸石产品(碱处理晶种)作晶种引入晶化体系后,可以显著提高产品的相对结晶度,降低模板剂的用量,缩短晶化诱导期,成为表面润湿法合成β沸石体系的有效晶种形式.     

Electronic structure and magnetic properties of metastable SmCo_7 compound

1 Introduction The rare-earth transition-metal intermetallic compounds have been widely investi-gated for many years, among them the Sm-Co series compounds with 1:5 and 2:17 crys-tal structures. These compounds have been used as sintered and bonded permanent magnets since the 1960s[1,2]. Interest recently has been focused on the TbCu7-type struc-ture Sm-Co intermetallic compounds with a strong uniaxial magnetocrytalline anisot-ropy and a low temperature coefficient (β = ?0.11%)[3―6] due t…     

20 keV质子在聚碳酸酯微孔膜中传输的动态演化过程

测量了20 ke V质子穿过倾斜角为+1?的聚碳酸酯微孔膜后,出射粒子的位置分布、相对穿透率以及电荷纯度随时间的演化.实验发现,能量电荷比E/q≈10~1k V的质子穿过绝缘纳米微孔的物理机理与E/q≈10~0k V和E/q≈10~2k V区域离子有显著不同.对于E/q≈10~1k V的质子穿过绝缘纳米微孔,存在一段相当长的导向建立之前(导向前)的过程,在该时期内出射质子及氢原子的特性和导向建立后的特性有很大差异.在导向前的演化过程中,我们可以观察到出射质子的峰位逐渐向孔轴向附近转移;出射氢原子由束流方向的尖峰以及孔轴向的主峰构成,峰位角保持基本不变且尖峰逐渐消失.这一过程的主要机理为微孔内表面以下的多次随机二体碰撞和近表面镜面反射两种传输方式逐步向电荷斑约束下的"导向效应"过渡的过程.对E/q≈10~1k V区间离子"导向前过程"的完整观测,使得对低能向中能过渡区间离子穿过绝缘微孔膜物理机制和图像有更深入和完整的认识,有助于约10 ke V离子微束的精确控制和应用.