排序方式: 共有51条查询结果,搜索用时 31 毫秒
21.
Zekeriya Altaç Mesut Tekkalmaz 《Journal of Quantitative Spectroscopy & Radiative Transfer》2004,83(1):115-117
The effects of variable medium properties on radiation transfer in participating and anisotropically scattering one-dimensional spherical medium were investigated by Tsai et al. (JQSRT 42(3) (1989) 187). The discrete ordinates method solutions they provided for hollow spherical medium cases are incorrect. The correct DOM S8 and the integral transfer equation solutions are provided. 相似文献
22.
Zekeriya Altaç 《Journal of Quantitative Spectroscopy & Radiative Transfer》2007,104(3):310-325
Generalized exponential integral functions (GEIF) are encountered in multi-dimensional thermal radiative transfer problems in the integral equation kernels. Several series expansions for the first-order generalized exponential integral function, along with a series expansion for the general nth order GEIF, are derived. The convergence issues of these series expansions are investigated numerically as well as theoretically, and a recurrence relation which does not require derivatives of the GEIF is developed. The exact series expansions of the two dimensional cylindrical and/or two-dimensional planar integral kernels as well as their spatial moments have been explicitly derived and compared with numerical values. 相似文献
23.
Osman Ra?it I?ikMehmet Sezer Zekeriya Güney 《Applied mathematics and computation》2011,217(16):7009-7020
In this study, a new collocation method based on the Bernstein polynomials is introduced for the approximate solution of a class of linear Volterra integro-differential equations with weakly singular kernel. If the exact solution is polynomial, then the exact solution can be obtained. If the exact solution is not a polynomial, then an accurate solution can be obtained with a combination of choice in the number of nodes and the number of digits in the solver. In addition, the method is presented with error and stability analysis. 相似文献
24.
Ali Veysel Tunc Bernhard Ecker Zekeriya Dogruyol Sabrina Jüchter Ahmet Lütfi Ugur Ali Erdogmus Sait Eren San Jürgen Parisi Elizabeth von Hauff 《Journal of Polymer Science.Polymer Physics》2012,50(2):117-124
In this study, we demonstrate how the intrinsic properties of a polymer can influence the electrical characteristics of organic field‐effect transistors (OFETs). OFETs fabricated with three batches of poly[2‐methoxy,5‐(3′,7′‐dimethyl‐octyloxy)]‐p‐phenylene vinylene (MDMO‐PPV) were investigated. The properties of the polymers were initially investigated using Fourier transform infrared spectroscopy (FTIR), impedance spectroscopy (IS), gel permeation chromotography (GPC), and cyclic voltammetry (CV), respectively. The structure and purity of the polymer batches were found to be very comparable, but the molecular weight (Mn and Mw) and polydispersity (PDI = Mw/Mn), varied between the samples and the HOMO and LUMO levels of the polymers were found to depend on the molecular weight properties. OFETs were then fabricated with the polymers and electrically characterized. It was observed that the channel current and the field‐effect mobility increase with increasing polymer molecular weight. The output characteristics of the transistors, on the other hand, were found to depend on the PDI of the polymer. Saturation of the channel current occurs at higher source–drain voltages and short‐channel behavior was observed to start at longer channel lengths for polymers with a higher PDI. This behavior is observed to be thickness dependent, and the short‐channel behavior was more pronounced for thicker MDMO‐PPV films. These results are explained in terms of influences of chain packing and ordering and high bulk currents on the FET output and transistor parameters. © 2011 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 50: 117–124, 2012 相似文献
25.
In this study, nonperipherally tetra‐substituted ( 2 ), peripherally tetra‐substituted ( 3 ), and peripherally octa‐substituted ( 4 ) zinc(II) phthalocyanines were synthesized as sensitizers for dye‐sensitized solar cells (DSSCs) in which 3‐pyridin‐3‐ylpropoxy substituent acts as anchoring unit to bind TiO2 surface. The optical results indicated that there is an interaction between the dyes and the TiO2 surface. The photovoltaic performances of the DSSCs based on these dyes were found to depend on both the position and number of the substituents. Despite the more red‐shifted absorption, the DSSC based on 2 showed the conversion efficiency of 0.68%, which is lower than 1.36% and 0.92% for 3 and 4 , respectively, under one sun (AM 1.5G). The vertical orientation of the dye on TiO2 surface could be the main reason for the higher photovoltaic performance of complex 3 , which is beneficial for not only injecting the electrons into the conduction band of TiO2 but also reducing the charge recombination. Overall, these results demonstrate that the peripherally tetra‐substituted 3‐pyridin‐3‐ylpropoxy zinc(II) phthalocyanine complex ( 3 ) as a sensitizer can more efficiently utilize the photons in the red/near‐infrared region with respect to the other complexes studied. 相似文献
26.
Molecular Diversity - Since the outbreak emerged in November 2019, no effective drug has yet been found against SARS-CoV-2. Repositioning studies of existing drug molecules or candidates are... 相似文献
27.
Novel Ni(II), Zn(II), Co(II) and Cu(II) phthalocyanines with four peripheral 4-[methyleneoxy(18-crown-6)] groups have been synthesized via the cyclic tetramerization of 4-[{(18-crown-6)-yl}methyleneoxy]phthalonitrile and the corresponding metal salts (NiCl2, Zn(CH3COO)2, CoCl2 and CuCl2). The thermal stabilities of the metal-free and metallophthalocyanine compounds were determined by thermogravimetric analysis. The structures of the target compounds were confirmed using elemental analysis, IR, 1H-NMR, 13C-NMR, UV–Vis and MS spectral data. Voltammetric and in situ spectroelectrochemical measurements show that while the cobalt phthalocyanine complex gives both metal-based and ring-based redox processes, the metal-free, nickel, zinc and copper phthalocyanines show only ring-based reduction and oxidation processes. An in situ electrocolorimetric method has been applied to investigate the color of the electro-generated anionic and cationic forms of the complexes. 相似文献
28.
Zekeriya Ustaoglu 《Mathematical Methods in the Applied Sciences》2023,46(1):167-179
Inversion of a generalized Radon transform (GRT) of seismic type is investigated by employing the algebraic iterative methods ART and SIRT, which require discrete formulations of the reconstruction problem. To this aim, two discretization procedures are proposed: a direct discretization and a discretization via the relation of GRT with the regular Radon transform (RT). The feasibility and the semi-convergence behavior of the proposed methods are analyzed and compared by discussing the effect of noisy data. 相似文献
29.
Ayşe Aktaş Kamiloğlu İrfan Acar Zekeriya Biyiklioglu 《Journal of inclusion phenomena and macrocyclic chemistry》2017,88(3-4):219-228
Metal free (6), cobalt(II) (7), copper(II) (8) and manganese(III) (9) phthalocyanines, which are tetra substituted at the peripheral positions with 2-[2-(1,1′:3′,1′′-terphenyl-2′-yloxy)ethoxy]ethoxy groups, were synthesized and characterized by IR, 1H-NMR,13C-NMR, UV–Vis and mass spectroscopy. Electrochemistry of the phthalocyanines were studied with voltammetric measurements by using cyclic voltammetry and square wave voltammetry techniques in DCM/TBAP electrolyte on a Pt working electrode. Electrochemical measurements exhibit that incorporation of redox active metal ions, CoII and MnIII, into the phthalocyanine core extends the redox capabilities of the Pc ring including the metal-based reduction couples of the metal. While MnIIIClPc showed only metal based reduction reactions, CoIIPc showed metal based and ligand based reduction reactions as expected. Cyclic and square wave voltammetric studies showed that phthalocyanines have reversible/quasireversible/irreversible redox processes, which are the main requirement for the technological usage of these compounds. 相似文献
30.
Turgut KELE Dilek ÜNLÜER Zekeriya BIYIKLIOLU Yasemin ÜNVER 《Turkish Journal of Chemistry》2021,45(1):17
3-[5-(diethylamino)-2-formylphenoxy]phthalonitrile ( n-TY-CN ), metallophthalocyanines n-TY-Co , n-TY-Cu , and n-TY-Mn bearing [5-(diethylamino)-2-formylphenoxy] groups at nonperipheral positions were prepared for the first time. These compounds were characterized with IR, NMR (only for n-TY-CN ), mass and UV-vis (except n-TY-CN ) spectroscopy. Voltammetric characterizations of n-TY-Co , n-TY-Cu , and n-TY-Mn revealed that while n-TY-Co , n-TY-Cu , and n-TY-Mn showed characteristic Pc ring and/or metal-based reduction reaction, n-TY-Co , n-TY-Cu , and n-TY-Mn were coated on the working electrode during the oxidation processes owing to the cationic electropolymerizations of the [5-(diethylamino)-2-formylphenoxy] substituents. 相似文献