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61.
Vadim V. Ilyushin Zbigniew Kisiel Heinrich Mäder 《Journal of Molecular Spectroscopy》2010,259(1):26-12194
A new program is described for fitting rotation-torsion energy levels in molecules like toluene, in which the frame (C6H5) has C2v symmetry and the methyl top has C3v symmetry, i.e., for molecules where the internal rotation barrier is expanded in cos6nα, where α is the internal rotation angle and n = 1,2,…. The program is based on the theoretical framework developed by Sørensen and Pedersen in their application of the Longuet-Higgins permutation-inversion group G12 to the microwave spectrum of CH3NO2. It is specifically designed for sixfold barrier molecules, and allows the user to select almost any symmetry-allowed torsion-rotation term for inclusion in the fitting Hamiltonian. This program leads to a very successful fit of transitions in the microwave spectrum of toluene characterized by J ? 30, Ka ? 12, and by the free-rotor quantum number ∣m∣ ? 3. In these fits we included both published and rather extensive unpublished new measurements, for which fits using other torsion-rotation programs have not been very successful. The fit presented here uses 28 parameters to give an overall standard deviation of 7.4 kHz for 372 line frequencies, and results in a much improved value for the sixfold barrier for toluene, V6 = 13.832068(3) cal mol−1. 相似文献
62.
63.
Two types of biomolecules were tested in the comparison of usefulness of two ways of formation of the intermediate layers at electrodes: a 20‐nucleotide DNA sequence and glucose oxidase. Chronocoulometric, amperometric, electrochemical impedance and PM‐IRRAS experiments proved that the layers obtained by electroreduction of diazonium salts are much more stable and more efficient in the accumulation of biomolecules compared to layers obtained by self‐assembling of appropriate thiols. 相似文献
64.
65.
Zbigniew GrobelnyAndrzej Stolarzewicz Barbara Morejko-Bu?Adalbert Maercker 《Journal of organometallic chemistry》2002,660(1):6-13
The linear ether bond was exclusively cleaved in benzyl glycidyl ether and triphenylmethyl glycidyl ether under the influence of K−, K+(15-crown-5)2 (1), whereas the strongly strained three-membered oxacyclic ring remained undisturbed. Potassium glycidoxide and benzylpotassium were found as the primary reaction products of benzyl glycidyl ether with 1. Subsequently, benzylpotassium reacted with benzyl glycidyl ether giving the next potassium glycidoxide molecule and bibenzyl. Benzyl phenyl ether was used as a model compound to explain the mechanism of bibenzyl formation. The reaction of triphenylmethyl glycidyl ether with 1 resulted in potassium glycidoxide and stable triphenylmethylpotassium. After treating with a quenching agent a new glycidyl ether or glycidyl ester was obtained from potassium glycidoxide. These results were found when the reaction occurred at the excess of glycidyl ether. In another case, i.e. at the excess of 1 further reactions took place with the participation of potassium anions and various new compounds were observed in the reaction mixture after benzylation or methylation. Thus, the method of substrates delivery influences the course of studied processes in a decisive way. 相似文献
66.
Zusammenfassung Die Bestimmungsmethode für Mikromengen elementaren, in Sulfiden enthaltenen Schwefels mit Natriumazid und Jod wurde modifiziert. Der Analyse geht die Aufspaltung des S8-Ringes voraus, die man dank der nukleophilen Wirkung von N3
– in DMF-Lösung erreicht. Diese Methode wurde auf die Bestimmung des Schwefels in Indium-, Blei-, Antimon- und Wismutsulfid angewandt. Sie ist einfach und empfindlich. Ihre Fehlergrenze liegt bei ± 4%.
Determination of microamounts of sulfur after cleavage of the S8 king in indium, lead, antimony and bismuth sulfides by means of an induced reaction of sodium azide with iodine
Summary The determination of microamounts of elemental sulfur contained in sulfides using sodium azide and iodine was modified. The analysis was preceded by cleavage of the S8 ring, which is achieved by virtue of the nucleophilic action of N3 – in DMF solution. This method was applied to the determination of sulfur in indium, lead, antimony and bismuth sulfides. It is simple and sensitive. Its limit of error is ±4%.相似文献
67.
Zbigniew J. Jurek 《Journal of multivariate analysis》1983,13(4):578-604
Let
= {Ut: t > 0} be a strongly continuous one-parameter group of operators on a Banach space X and Q be any subset of a set
(X) of all probability measures on X. By
(Q;
) we denote the class of all limit measures of {Utn(μ1 * μ2*…*μn)*δxn}, where {μn}Q, {xn}X and measures Utnμj (j=1, 2,…, n; N=1, 2,…) form an infinitesimal triangular array. We define classes Lm(
) as follows: L0(
)=
(
(X);
), Lm(
)=
(Lm−1(
);
) for m=1, 2,… and L∞(
)=m=0∞Lm(
). These classes are analogous to those defined earlier by Urbanik on the real line. Probability distributions from Lm(
), m=0, 1, 2,…, ∞, are described in terms of their characteristic functionals and their generalized Poisson exponents and Gaussian covariance operators. 相似文献
68.
We show that if u is a plurisubharmonic function defined on an open subset of 2 then the Monge-Ampère measure (ddcu)2 can be well defined if and only if u belongs to the Sobolev space W1,2loc().Partially supported by KBN Grant #2 P03A 028 19 相似文献
69.
Let K be the field of real or complex numbers. Let (X K2n,) be a symplectic vector space and take 0 < k < n,N =. Let L1,...,LN X be 2k-dimensionallinear subspaces which are in a sufficiently general position.It is shown that if F : X X is a linear automorphism whichpreserves the form k on all subspaces L1,...,LN, then F is ank-symplectomorphism (that is, F* = k, where ). In particular, if K = R and k is odd then F mustbe a symplectomorphism. The unitary version of this theoremis proved as well. It is also observed that the set Al,2r ofall l-dimensional linear subspaces on which the form has rank 2r is linear in the Grassmannian G(l,2n), that is, there isa linear subspace L such that Al,2r = L G(l, 2n). In particular,the set Al,2r can be computed effectively. Finally, the notionof symplectic volume is introduced and it is proved that itis another strong invariant. 相似文献
70.
Stachurski ZH 《Physical review letters》2003,90(15):155502
It is proposed that two ideal amorphous structures, type I and type II, based on maximally random jammed packing of spheres of equal size, form a distinct class of ideal amorphous solids. The ideal amorphous structures contain wide variations in local density, limited by the condition of solidity. Four distinct characteristics, based on statistical geometry and topology, are shown to define this class. Voronoi tessellations carried out on simulated cells of random packed spheres and amorphous polymers give a broad distribution of individual volumes, skewed, with a tail at the high volume end. 相似文献