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21.
Marek Daszkiewicz Zbigniew Staszak Adam Pietraszko Wiesława Bronowska Maria Cieślak-Golonka 《Structural chemistry》2006,17(6):599-608
Two polymeric complexes: catena(μ-CrO4-O,O′)[Co(HIm)3H2O] (1) and catena(μ-CrO4-O,O′)[Co0.43Ni0.57(HIm)3H2O] (2) (where HIm=imidazole) with a cis-bridging coordination mode of the CrO4
2− anion have been synthesized and characterized by X-ray and spectroscopic methods. These crystals were isolated from nine
systems of varying reagent molar ratios and three excluding anions: Cl−, NO3
− and SO4
2− exclusively as mer [M(HIm)3O3]-type isomers. The unit cell of these isostructural complexes (monoclinic crystal system P21
/n) contains two independent helixes, left- and right handed, stabilized by intrahelical and interhelical hydrogen bonding and
π–π interaction between pairs of the imidazole rings from neighbouring helixes. The Raman spectra at 77 K of 1 and 2 deconvoluted into lorentzian components revealed the block-type polymeric structure of the complexes. Moreover, the solution
studies at millimolar concentrations of 1 and 2 indicated their complete decomposition in water. Four K electronic spectral analysis of the crystals (band deconvolution
into gaussian components) enhanced with the data obtained in the polarized light allowed for assignment of the bands to the
respective d–d transition (D4h symmetry). It was found that the metallic centres are independently absorbing species, which supports the suggestion of a
block-type structure of the polymers. The respective crystal field parameters for Co and Ni were calculated. 相似文献
22.
The compatibility of cycloaliphatic and aromatic multifunctional epoxides with several epoxide resins allows the development of a wide range of cationic radiation‐curable formulations. The influence of different “epoxide resin‐monomer” systems UV‐cured in the presence of suitable cationic photoinitiators on the resulting physicochemical film properties was studied, and the results are stated. Copyright © 2004 John Wiley & Sons, Ltd. 相似文献
23.
J. Graczyk L. B. Jonker G. Świątek F. M. Tangerman J. J. P. Veerman 《Communications in Mathematical Physics》1995,173(3):599-622
We study weakly order preserving circle maps with a flat interval, which are differentiable even on the boundary of the flat interval. We obtain estimates on the Lebesgue measure and the Hausdorff dimension of the non-wandering set. Also, a sharp transition is found from degenerate geometry to bounded geometry, depending on the degree of the singularities at the boundary of the flat interval.Partially supported by KBN grant Iteracje i Fraktale #210909101. 相似文献
24.
One-parameter semigroups occurring in operator-limit distributions are investigated. The topological-algebraic background of the relevant monoids is discussed and Lie semigroup theory is applied to the Urbanik Decomposability Semigroup. 相似文献
25.
Zbigniew Michalewicz 《Journal of Heuristics》1996,1(2):177-206
Evolutionary computation techniques, which are based on a powerful principle of evolution—survival of the fittest, constitute an interesting category of heuristic search. In other words, evolutionary techniques are stochastic algorithms whose search methods model some natural phenomena: genetic inheritance and Darwinian strife for survival.Any evolutionary algorithm applied to a particular problem must address the issue of genetic representation of solutions to the problem and genetic operators that would alter the genetic composition of offspring during the reproduction process. However, additional heuristics should be incorporated in the algorithm as well; some of these heuristic rules provide guidelines for evaluating (feasible and infeasible) individuals in the population. This paper surveys such heuristics and discusses their merits and drawbacks.An abridged version of this paper appears in the volume entitled META-HEURISTICS: Theory & Application, edited by Ibrahim H. Osman and James P. Kelly, to be published by Kluwer Academic Publishers in March 1996. 相似文献
26.
Zbigniew Olszak 《Periodica Mathematica Hungarica》1996,33(2):105-113
LetM be a 3-dimensional quasi-Sasakian manifold. On such a manifold, the so-called structure function is defined. With the help of this function, we find necessary and sufficient conditions forM to be conformally flat. Next it is proved that ifM is additionally conformally flat with = const., then (a)M is locally a product ofR and a 2-dimensional Kählerian space of constant Gauss curvature (the cosymplectic case), or (b)M is of constant positive curvature (the non cosymplectic case; here the quasi-Sasakian structure is homothetic to a Sasakian structure). An example of a 3-dimensional quasi-Sasakian structure being conformally flat with nonconstant structure function is also described. For conformally flat quasi-Sasakian manifolds of higher dimensions see [O1] 相似文献
27.
This paper is devoted to a discussion of the notion of localizability for phonons, i.e., quasiparticles arising from the harmonic vibrations of a system ofn atoms bound to one another by elastic forces. The natural tools for the analysis of localizability are the projection operatorsÊ() acting on the Hilbert space of one-phonon states, where is an arbitrary subset of the set that consists ofn vectors specifying the equilibrium positions ofn atoms. The expectation value ofÊ() is the probability that the phonon belongs to the atoms whose equilibrium positions are characterized by the elements of . For a strongly localizable phonon all of the projection operatorsÊ() commute with one another, whereas in the case of a weakly localizable phonon the operatorsÊ(1) andÊ(2) do not commute when 1 and 2 overlap. With the aid of the Jauch-Piron quantum theory of localization in space, the present paper describes the method of obtainingÊ() and also shows that if in the system ofn atoms there exist normal modes of zero frequency, then the phonon is only weakly localizable. Given the explicit expression forÊ(), one can define the number-of-phonons operator as well as the quasiparticle analogue (given in a companion paper) of the Wigner distribution function. 相似文献
28.
Structure of colloid silica determined by viscosity measurements 总被引:3,自引:0,他引:3
The viscosity of nanosized colloid silica suspensions, used as binders in the investment casting, was determined as a function of their weight fraction reaching 52%. A new capillary viscometer was used whose construction eliminated sedimentation effects. The experiments have been carried out at fixed pH 10.0 and controlled ionic strength. It was found that for a low silica concentration range (weight fraction below 5%) the suspension viscosity increased more rapidly than the Einstein theory predicts. This anomalous behavior could not be explained in terms of the primary electroviscous effect predicted to be a few orders of magnitude smaller as observed. This discrepancy was accounted for by postulating a fuzzy, gel-like structure of colloid silicas used in our experiments. Hence, the apparent hydrodynamic radius of silica particles in aqueous suspensions was found to be larger than the primary particle size in accordance with previous observations. Based on this postulate, an apparent density of the silica sols was found to be 1.32-1.37 g/cm(3) instead of 2.2-2.32 g/cm(3) as determined from the suspension dilution method. This behavior was interpreted in terms of the core/shell model with high shell porosity, reaching 85%. Similarly, for higher concentration ranges, silica viscosity increased more rapidly with increased sol concentration than predicted by the Batchelor model derived for hard particles. The deviation was attributed to the secondary electroviscous effect stemming from the electrostatic interactions among silica particles in sheared suspensions. This effect has quantitatively been interpreted in terms of Russel's theory. On the other hand, for the high concentration range the experimental results were well accounted for by the Dougherty-Krieger model. By exploiting our experimental findings a sensitive method of determining the structure and apparent density of silica sols in aqueous media was proposed. 相似文献
29.
Zbigniew Gregorowicz und Franz Buhl 《Fresenius' Journal of Analytical Chemistry》1960,173(2):115-121
Zusammenfassung Es wird eine volumetrische Methode zur Bestimmung von Cyanid- und Quecksilber(II)-ionen mit titrierter Quecksilber(II)-nitratlösung gegen Variaminblau als Indicator beschrieben. Das Verfahren liefert genaue, wenig streuende Werte.Vorgetragen auf der III. Arbeitstagung für analytische Chemie in Prag am 1. September 1959. 相似文献
30.
Zbigniew Gregorowicz Barbara Piwowarska Franciszek Buhl und Krystyna Kania 《Fresenius' Journal of Analytical Chemistry》1968,237(5):347-351
Zusammenfassung Es wurde eine UV-spektrophotometrische Methode zur Bestimmung der 2,2-Dicinchoninsäure beschrieben. Messung erfolgt bei pH 10 bei dem Absorptionsmaximum von 260 nm. Der Bestimmungsbereich beträgt 1,71–20,52 g der 2,2-Dicinchonin-Ionen in 25 ml Lösung. Ba2+, Sr2+, Ca2+, Mg2+, Ni2+, Co2+, Zn2+, Hg2+ und Al3+ in 100fachem sowie Pb2+ in 10fachem Überschuß verursachen keine Störungen. Blei in 20 fachem sowie Ag+ und Hg2
2+ in einfachem Überschuß verursachen Ausscheidung von Niederschlägen.
Summary An UV-spectrophotometric method for the determination of 2,2-dicinchonic acid is described. The absorption is measured in a solution of pH 10 at the maximum of 260 nm.The range of application of the method was 1,71 to 20,52 g of DC2– ions in 25 ml of solution. Ba2+, Sr2+, Ca2+, Mg2+, Ni2+, Co2+, Al3+, Zn2+, Hg2+ ions present in hundredfold excess do not interfere with the determination. Ag+, Hg2 2+ ions in one-fold and Pb2+ ion in twenty-fold excess cause the deposition of a precipitate, but five-fold and ten-fold excess of Pb2+ does not interfere.相似文献