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31.
In this Note, a numerical investigation of laminar convection wake above a heated plate placed in a channel is carried out. An analytical study based on a three region structure is proposed in the immediate neighbourhood of the trailing edge. Velocity and temperature at the centerline channel as well as the pressure gradient are presented in asymptotic expressions. Comparison of these results with numerical solutions enhances the analytical study. To cite this article: Z. Doulfoukar, A. Achiq, C. R. Mecanique 333 (2005).  相似文献   
32.
** Email: belhach{at}poncelet.univ-metz.fr*** Email: bucur{at}math.univ-metz.fr**** Email: jmse{at}math.univ-metz.fr We study the Neumann–Laplacian eigenvalue problem in domainswith multiple cracks. We derive a mixed variational formulationwhich holds on the whole geometric domain (including the cracks)and implements efficient finite-element discretizations forthe computation of eigenvalues. Optimal error estimates aregiven and several numerical examples are presented, confirmingthe efficiency of the method. As applications, we numericallyinvestigate the behaviour of the low eigenvalues in domainswith a large number of cracks.  相似文献   
33.
We propose two nutrient-phytoplankton models with instantaneous and time delayed recycling, investigate the dynamics and examine the responses to model complexities. Instead of the familiar specific uptake rate and growth rate functions, we assume only that the nutrient uptake and phytoplankton growth rate functions are positive, increasing and bounded above. We use geometrical and analytical methods to find conditions for the existence of none, one, or at most two positive steady states and analyze the stability properties of each of these equilibria. With the variation of parameters, the system may lose its stability and bifurcation may occur. We study the occurrence of Hopf bifurcation and the possibility of stability switching. Numerical simulations illustrate the analytical results and provide further insight into the dynamics of the models, biological interpretations are given.  相似文献   
34.
Interaction of high-pressure CO2 gas with a silicone elastomer, and to a lesser extent, with a nitrile rubber and a PTFE have been investigated. Sorptive dilations of the polymers were measured with the help of custom-made piezoelectric ultrasonic transducers under gas pressures of up to ca. 22 MPa at 42°C. The gas mass sorption was determined by a vibrating reed probe. For the silicone elastomer system the dilation isotherm mimics the sorption isotherm. The partial molar volume (PMV) of the absorbed CO2 gas in the silicone elastomer has been computed. A significant drop in the PMV value is observed when the CO2 gas becomes supercritical. In the transition region, the transmission of ultrasonic signals through the specimen indicated the formation of discrete small (estimated as about 60 μm in diameter) high density zones of CO2 in the rubber matrix. The plasticization effects of the absorbed high pressure CO2 gas have been identified from the interpretation of the changes in the acoustic longitudinal modulus obtained from ultrasonic transmission measurements. The effects of rapid gas decompression on the structural integrity of the various polymers have also been determined. Significant inflation of certain specimens occur toward the latter stages of the decompression cycle. The initiation and development of internal cracks or bubbles was followed by monitoring the ultrasonic signal attenuation.  相似文献   
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Aequationes mathematicae - Given two functions $$f,g:I\rightarrow \mathbb {R}$$ and a probability measure $$\mu $$ on the Borel subsets of [0, 1], the two-variable mean $$M_{f,g;\mu...  相似文献   
37.
This paper is the follow-up of Gloria (Math Models Methods Appl Sci 21(8):1601–1630, 2011). One common drawback among numerical homogenization methods is the presence of the so-called resonance error, which roughly speaking is a function of the ratio (frac{varepsilon }{rho }), where (rho ) is a typical macroscopic lengthscale and (varepsilon ) is the typical size of the heterogeneities. In the present work, we make a systematic use of regularization and extrapolation to reduce this resonance error at the level of the approximation of homogenized coefficients and correctors for general non-necessarily symmetric stationary ergodic coefficients. We quantify this reduction for the class of periodic coefficients, for the Kozlov subclass of almost-periodic coefficients, and for the subclass of random coefficients that satisfy a spectral gap estimate (e.g., Poisson random inclusions). We also report on a systematic numerical study in dimension 2, which demonstrates the efficiency of the method and the sharpness of the analysis. Last, we combine this approach to numerical homogenization methods, prove the asymptotic consistency in the case of locally stationary ergodic coefficients, and give quantitative estimates in the case of periodic coefficients.  相似文献   
38.
    
At the core of carbon monoxide dehydrogenase (CODH) active site two metal ions together with hydrogen bonding scheme from amino acids orchestrate the interconversion between CO2 and CO. We have designed a molecular catalyst implementing a bimetallic iron complex with an embarked second coordination sphere with multi-point hydrogen-bonding interactions. We found that, when immobilized on carbon paper electrode, the dinuclear catalyst enhances up to four fold the heterogeneous CO2 reduction to CO in water with an improved selectivity and stability compared to the mononuclear analogue. Interestingly, quasi-identical catalytic performances are obtained when one of the two iron centers was replaced by a redox inactive Zn metal, questioning the cooperative action of the two metals. Snapshots of X-ray structures indicate that the two metalloporphyrin units tethered by a urea group is a good compromise between rigidity and flexibility to accommodate CO2 capture, activation, and reduction.  相似文献   
39.
    
An organic-inorganic compound of tetraethylammonium dihydrogenarsenate bis(arsenic acid) salts of formula (NEt4)(H2AsO4)(H3AsO4)2, a potential new nonlinear optical material, was prepared by a slow evaporation technique and characterized by IR and Raman spectroscopy accomplished with DFT calculation and electrical-dielectrical measurements. The structure has been solved using direct method and refined by least-squares analysis. In this case, the structure consists of infinite parallel two-dimensional planes built of mutually H2AsO4?, H3AsO4 tetrahedra connected by strong O–H?O hydrogen bonding giving birth to trimers. The geometry, first hyperpolarizability and harmonic vibrational wavenumbers were calculated by means of density functional theory (DFT) with the B3LYP/6-31G(d) level of theory. Good consistency was found between the calculated and the experimental structure, IR, and Raman results. The first hyperpolarizability βtot of the title compound is about 1.75 times more than that of the reference crystal KDP. The complex impedance has been investigated in relation to the temperature and frequency ranges 297 and 373 K and 1 to 100 KHz, respectively. The conductivity temperature variation shows a typical Arrhenius-type behavior with a linear dependence on logarithm of conductivity. Transport properties in this material appear to be due to proton hopping mechanism.  相似文献   
40.
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