Analysis of hybrid donor layer in organic solar cells based on SubPc and rubrene

In this paper, photovoltaic characteristics of ITO/PEDOT:PSS/SubPc:Rubrene (mixed ratio R by weight)/C₆₀/Bphen/Ag organic solar cells (OSCs) are analyzed in detail. The intrinsic properties of a SubPc:rubrene doped layer on device performance were discussed based on theoretical analysis of the experimental OSCs. The ratio R was 0, 0.25, 0.5, and 0.75,1, respectively. The results showed that when R was 0.75 performing the best, which owned the highest short circuit current (J _sc ) 6.61 mA/cm² and highest power conversion efficiency (PCE) 2.44%, the FF was 41% and the open circuit current (V _oc ) was 0.905 V. The suitable HOMO level, absorption capacity, carrier transport ability and exciton diffusion length (L _D ) of organic material are very important for the performance of the device.     

TBAI/K2S2O8-facilitated reaction of sulfonylhydrazides with alkynes: Facile synthesis of (E)-β-iodovinyl sulfones

An efficient and convenient approach for the construction of various (E)-β-iodovinyl sulfones has been developed through potassium persulfate/tetrabutylammonium iodide-facilitated reaction of sulfonylhydrazides with alkynes. The products were obtained in good to excellent yields. The salient features of this reaction are the applications of a new iodine source, environmentally benign, safer solid oxidant, and shorter reaction time.     

糖基亚苄基NaBH_3 CN-HCl选择性开环过程中乙酰基迁移现象的研究

用NaBH3CN HCl/Et2 O对 3 O 乙酰基 4,6 O 亚苄基 β D 吡喃半乳糖乙硫苷 (2 )进行还原开环 ,发现有乙酰基迁移至 2 位的产物生成 ;进一步的实验表明 ,室温条件下 ,NaBH3CN与 2的作用导致乙酰基的迁移     

电脉冲沉积铝化物及铝化物-Y_2O_3涂层

采用电脉冲沉积技术在 2 0碳钢表面上获得了冶金结合的晶粒尺寸约为几十到几百纳米的铝化物和铝化物 弥散Y2 O3复合微晶涂层。60 0℃空气中氧化 10 0h的结果表明 ,电脉冲沉积获得的两种涂层均可显著地降低 2 0碳钢的氧化速率并提高氧化层的抗剥落性能。用AFM ,SEM ,EDS和XRD对铝化物涂层及氧化层进行了分析 ,并讨论了两种涂层提高抗氧化性能的作用机制     

Microcalorimetric Character of Inhibition of Salicylaldehyde Glucosamine Schiff Base SG on Bacterial Metabolism

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壳聚糖富集FAAS法测定水中痕量Cu（Ⅱ）

了以壳聚糖作富集柱，稀H2SO4为洗脱剂，稀NaOH为再生剂，火焰原子吸收光谱法简便，快速分离集测定水中痕量Cu(Ⅱ）的方法，于波长325nm处测定，检出限为为20ng.ml^0-1，线性范围为10－20μg.ml^-1。     

An improved optimization strategy and its application to clustering analysis.

In this paper, a new optimization strategy is put forward which locates as many potential unimodal regions as possible in the search space. The potential optima can be further explored by a global optimization method for searching in the identified unimodal regions. The proposed strategy was evaluated by the optimization of test functions. The results obtained by this approach are comparable with those achieved by variable step size generalized simulated annealing (VSGSA) and a genetic algorithm (GA). Finally, we used this strategy in a clustering analysis of a tobacco data set.     

Connectivity correlations in three topological spaces of urban bus-transport networks in China

In this paper, an empirical investigation is presented, which focuses on unveiling the universality of connectivity correlations in three spaces （the route space, the stop geographical space and bus-transferring space） of urban bustransport networks （BTNs） in four major cities of China. The underlying features of the connectivity correlations are shown in two statistical ways. One is the correlation between the （weighted） average degree of all the nearest neighbouring vertices with degree k, （Knn^w,（k）） Knn（k）, and k, and the other is the correlations between the assortativity coefficient r and, respectively, the network size N, the network diameter D, the averaged clustering coefficient C, and the averaged distance （l）. The obtained results show qualitatively the same connectivity correlations of all the considered cities under all the three spaces.     

大气激光通信链路的性能仿真

大气衰减和大气湍流严重影响着大气激光通信的链路质量。建立了大气信道的激光通信链路模型，研究了衰减信道和湍流信道中光链路的传输影响，对最大通信速率、链路功率余量和误码率进行了分析和计算。结果表明，大气湍流严重影响系统误码率，当大气闪烁指数斫是0．07时，可达到的最小误码率为10^-9。分析结果可为系统设计提供参考依据。