全文获取类型
收费全文 | 10931篇 |
免费 | 2331篇 |
国内免费 | 4652篇 |
专业分类
化学 | 8198篇 |
晶体学 | 555篇 |
力学 | 869篇 |
综合类 | 692篇 |
数学 | 1695篇 |
物理学 | 5905篇 |
出版年
2024年 | 31篇 |
2023年 | 93篇 |
2022年 | 351篇 |
2021年 | 356篇 |
2020年 | 357篇 |
2019年 | 384篇 |
2018年 | 388篇 |
2017年 | 544篇 |
2016年 | 368篇 |
2015年 | 544篇 |
2014年 | 680篇 |
2013年 | 928篇 |
2012年 | 834篇 |
2011年 | 982篇 |
2010年 | 945篇 |
2009年 | 1054篇 |
2008年 | 1160篇 |
2007年 | 1114篇 |
2006年 | 1009篇 |
2005年 | 860篇 |
2004年 | 684篇 |
2003年 | 510篇 |
2002年 | 581篇 |
2001年 | 601篇 |
2000年 | 618篇 |
1999年 | 391篇 |
1998年 | 209篇 |
1997年 | 131篇 |
1996年 | 126篇 |
1995年 | 120篇 |
1994年 | 125篇 |
1993年 | 128篇 |
1992年 | 112篇 |
1991年 | 75篇 |
1990年 | 73篇 |
1989年 | 76篇 |
1988年 | 67篇 |
1987年 | 54篇 |
1986年 | 44篇 |
1985年 | 38篇 |
1984年 | 39篇 |
1983年 | 33篇 |
1982年 | 25篇 |
1981年 | 23篇 |
1980年 | 7篇 |
1979年 | 18篇 |
1976年 | 3篇 |
1966年 | 3篇 |
1964年 | 2篇 |
1959年 | 5篇 |
排序方式: 共有10000条查询结果,搜索用时 5 毫秒
151.
152.
Barium strontium titanate nanoparticles with spherical and rod-like morphologies were synthesized in water/Triton X-100/n-hexanol/cyclohexane quaternary reverse microemulsion solution. The influences of the molar ratio of water to surfactant (ω0) and the concentration of reactants on the morphology and size of barium strontium titanate nanoparticles were studied. The structure, compositions and morphology of the prepared products were characterized by XRD, SAED, ICP, EDS and TEM. The results show that the obtained Ba0.7Sr0.3TiO3 spherical nanoparticles with diameters of 20~100 nm and the Ba0.7Sr0.3TiO3 nanorods with diameters of 70~120 nm and lengths up to 600~800 nm are a single crystal, with a cubic phase. The molar ratio for barium, strontium and titanate in products is about 0.7:0.3:1. 相似文献
153.
研究了6种水煤浆分散剂在14种不同变质程度煤上的吸附作用特征。结果表明,多数分散剂在煤粒表面达到单层饱和吸附后,又形成多层吸附,单层饱和吸附量与煤的变质程度、比表面积以及分散剂的性质有关。在相同粒度分布下,煤的变质程度越低,表面含氧亲水官能团的比例越高,孔隙率越高,比表面积越大,这对增大吸附量有利。煤的变质程度越高,其表面疏水区面积的比例越高,分散剂通过疏水基团紧密吸附在煤表面的比例越大,这对增加高阶煤的吸附量有利。对不同煤,是变质程度还是比表面积为吸附分散剂的主控因素,主要依赖于分散剂的结构与性质。对同种煤,疏水与亲水基团呈线型分立分布的分散剂,吸附量明显高;而疏水与亲水基团呈线型间隔分布的分散剂,吸附量明显小。 相似文献
154.
The DNA fragment corresponding to the tissue plasminogen activator (tPA) sequence 174-262 (Kringle-2 domain) has been synthesized by using the solid phase phosphotriester method. The Kringle-2 domain of human tPA was expressed in Escherichia colt by secretion into the periplasmic space using the Lpp-Lac promoter and PIN-Ⅲ OmpA2 signal sequence. About two thirds of the expression product was secreted into the periplasmic space , and purified with ammonium sulfate fractionation, affinity chro-matography on Lysine-Sepharose, and FPLC-Mono Q exchange chromatography. The amino acid composition observed from the Kringle-2 purified from E. coli is identical with that expected for the 174-262 fragment of human tPA. Radio binding assay shows that the recombinant Kringle-2 domain possesses the activity of fibrin binding. 相似文献
155.
StudiesonArtificialImitationofGlutathionePeroxidasebyChemicalMutationDINGLan;ZHUZhen-qi;LUOGui-min;SUNQi-an;YANGTong-shuandSH... 相似文献
156.
The spectral evolution of the surface-enhanced Raman scattering (SERS) of 4-tert-butylbenzylmer-captan(4-tBBM)on gold nanopanlcles assembly under laser irradiation is reported.The reIative intensities of typical peaks in the spectrum of 4-tBBM gradually change with irradiation time.Comparison of the rate of spectral changes under several experimental conditions indicates that the surface plasmon resonance(SPR)induced heat in the gold nanoparticles assembly is the origin of the spectraI evolution.During the process of self-assembly,4-tBBM molecules do not form a compact ordered monolayer because of the spatial hindrance of the 4-tert-butyl end group.The heat induced by laser irradiation drives the 4-tBBM molecules to rearrange to a more stable orientation. 相似文献
157.
LIU Tie-mei WANG Shu-sheng ZHU Guang-ze LI Ming-yang ZHANG Li-ping 《高等学校化学研究》2007,23(3):300-302
Antibody-directed enzyme prodrug therapy(ADEPT) is a new strategy for the treatment of cancer that has arisen in recent twenty years, the main merits of which are that it can improve the selectivity of anticancer drugs and reduce the side effects in remote tissue. In the present study, two prodrugs-glycosylated aromatic nitrogen mustard derivatives were synthesized. Glucose and lactose were converted into glycosyl donors-trichloroacetimidate; the obtained glycosyl donors were glycosylated with p-nitrophenol(glycosyl donors) to form β-glucosyl p-nitrobenzene and β-lactosyl p-nitrobenzene that were protected by acetyl in a stereoselective manner; the two products were reduced by zinc dust and then treated with ethylene oxide, afforded two glycosylated nitrogen mustard derivatives that were protected by acetyl; the last step was to deacetylate and then afforded the two target compounds that could be used as prodrugs of ADEPT for further Anti-tumor research. 相似文献
158.
159.
160.
A series of 2-cyano-3-methylthio-3-substituted methylaminoacrylates were synthesized as herbicidal inhibitors of photosystem Ⅱ (PSⅡ) electron transport, in order to estimate the effect of fluorine atom, pyridyl group, chirality and ester chain on activity. The important intermediate 2-fluoro-5-aminomethylpyridine was synthesized with high yield. The bioassay results showed that most of rifle compounds had high herbicidal activity in postemergence treatment. The introduction of an a-methyl into the 3-substituted methylamino could improve the activity notably. The replacement of hydrogen by chlorine or fluorine group and phenyl by pyridyl group showed different effects, and at the same time, the ester chain affected the activity too. 相似文献