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排序方式: 共有291条查询结果,搜索用时 46 毫秒
151.
Amdursky N Gepshtein R Erez Y Koifman N Huppert D 《The journal of physical chemistry. A》2011,115(24):6481-6487
Time-resolved emission techniques were employed to study the nonradiative process of thioflavin-T (ThT) in 1-propanol, 1-butanol, and 1-pentanol as a function of the hydrostatic pressure. Elevated hydrostatic pressure increases the alcohol viscosity, which in turn strongly influences the nonradiative rate of ThT. A diamond-anvil cell was used to increase the pressure up to 2.4 GPa. We found that the nonradiative rate constant, k(nr), decreases with pressure. We further found a remarkable linear correlation between a decrease in k(nr) (increase in the nonradiative lifetime, τ(nr)) and an increase in the solvent viscosity. The viscosity was varied by a factor of 1000 and k(nr) was measured at high pressures, at which the nonradiative rate constant of the molecules decreased from (7 ps)(-1) to (13 ns)(-1), (13 ps)(-1) to (17 ns)(-1) and (17 ps)(-1) to (15 ns)(-1) for 1-propanol, 1-butanol, and 1-pentanol, respectively. The viscosity-dependence of k(nr) is explained by the excited-state rotation rate of the two-ring systems, with respect to each other. 相似文献
152.
Belman N Israelachvili JN Li Y Safinya CR Ezersky V Rabkin A Sima O Golan Y 《Physical chemistry chemical physics : PCCP》2011,13(11):4974-4979
We describe methodology for producing highly uniform, ordered and reproducible superstructures of surfactant-coated ZnS nanorod and nanowire assemblies, and propose a predictive multiscale "packing model" for superstructure formation based on electron microscopy and powder X-ray diffraction data on the superstructure, as well as on individual components of the nanostructured system. The studied nanoparticles showed a hierarchical structure starting from the individual faceted ZnS inorganic cores, onto which the crystalline surfactant molecules are adsorbed, to the superstructure of the nanoparticle arrays. Our results point out the critical role of the surfactant headgroup and polarity in nanoparticle assembly, and demonstrate the relationship between the molecular structure of the surfactant and the resulting superstructure of the nanoparticle assemblies. 相似文献
153.
Colloidal spheres driven through water along a circular path by an optical ring trap display unexpected dynamical correlations. We use Stokesian dynamics simulations and a simple analytical model to demonstrate that the path's curvature breaks the symmetry of the two-body hydrodynamic interaction, resulting in particle pairing. The influence of this effective nonequilibrium attraction diminishes as either the temperature or the stiffness of the radial confinement increases. We find a well-defined set of dynamically paired states whose stability relies on hydrodynamic coupling in curving trajectories. 相似文献
154.
A protocol employing weak values (WVs) to obtain ultrasensitive amplification of weak signals in the context of a solid-state setup is proposed. We consider an Aharonov-Bohm interferometer where both the orbital and the spin degrees of freedom are weakly affected by the presence of an external charge to be detected. The interplay between the spin and the orbital WVs leads to a significant amplification even in the presence of finite temperature, voltage, and external noise. 相似文献
155.
A junction between two topological superconductors containing a pair of Majorana fermions exhibits a "fractional" Josephson effect, 4π periodic in the superconductors' phase difference. An additional fractional Josephson effect, however, arises when the Majorana fermions are spatially separated by a superconducting barrier. This new term gives rise to a set of Shapiro steps which are essentially absent without Majorana modes and therefore provides a unique signature for these exotic states. 相似文献
156.
Tal Ben Shalom Yuval Nevo David Leibler Zvi Shtein Clarite Azerraf Shaul Lapidot Oded Shoseyov 《Macromolecular bioscience》2019,19(3)
This study is aimed to explore the properties of cellulose nanocrystals (CNC)/polyvinyl alcohol (PVA) composite films with and without 1,2,3,4‐butane tetracarboxylic acid (BTCA), a nontoxic crosslinker. CNC and CNC‐PVA nanocomposite films are prepared using solution‐casting technique. Differential scanning calorimetry (DSC) analyses show that crosslinking increased the glass transition temperature but reduced the melting temperature and crystallinity. Furthermore, high CNC concentrations in the PVA matrix interfere with PVA crystallinity, whereas in specific ratio between CNC and PVA, two different crystalline structures are observed within the PVA matrix. Film surfaces and fracture topographies characterized using scanning electron microscope indicate that at certain CNC‐PVA ratios, micron‐sized needle‐like crystals have formed. These crystalline structures correlate with the remarkable improvement in mechanical properties of the CNC‐PVA nanocomposite films, that is, enhanced tensile strain and toughness to 570% and 202 MJ m?3, respectively, as compared to pristine PVA. BTCA enhances the tensile strain, ultimate tensile stress, toughness, and modulus of CNC films compared to pristine CNC films. Water absorption of crosslinked CNC and CNC‐PVA nanocomposite films is significantly reduced, while film transparency is significantly improved as a function of PVA and crosslinker content. The presented results indicate that CNC‐PVA nanocomposite films may find applications in packaging, and though materials applications. 相似文献
157.
The block number of a permutation is the maximum number of components in its expression as a direct sum. We show that, for 321-avoiding permutations, the set of left-to-right maxima has the same distribution when the block number is assumed to be k, as when the last descent of the inverse is assumed to be at position \(n - k\). This result is analogous to the Foata–Schützenberger equidistribution theorem, and implies that the quasi-symmetric generating function of the descent set over 321-avoiding permutations with a prescribed number of blocks is Schur-positive. 相似文献
158.
Superior biolubricant from a species of red microalga 总被引:1,自引:0,他引:1
Arad SM Rapoport L Moshkovich A van Moppes D Karpasas M Golan R Golan Y 《Langmuir : the ACS journal of surfaces and colloids》2006,22(17):7313-7317
The rheological properties of the sulfated polysaccharide of the red microalga Porphyridium sp., a heteropolymer with a molecular weight of 3-5 x 10(6) Da, indicated that this material might be an excellent candidate for lubrication applications: the viscosity of the polysaccharide is stable over a range of temperatures, pH values, and salinities. In this study, various rheological and lubricant properties of the polysaccharide were evaluated in comparison with those of a widely used biolubricant, hyaluronic acid. The viscosity of the Porphyridium sp. polysaccharide remained essentially unchanged in a temperature range of 25-70 degrees C. In tribology tests on a ball-on-flat ceramic pair, the values for the friction coefficient and wear rate for the pair lubricated with polysaccharide were remarkably lower than those for hyaluronic acid, especially at high loads. In a test on a steel ring/ultrahigh-molecular-weight polyethylene (UHMWPE) block pair, the wear tracks on the surface of the UHMWPE were more pronounced for hyaluronic acid than for the polysaccharide. Atomic force microscopy showed that the polysaccharide was effectively adsorbed onto mica surfaces, forming ultrathin coating layers in the nanometer range. As is required for biolubricant applications, the polysaccharide was not degraded by hyaluronidase. The stability of the Porphyridium sp. polysaccharide to heat and to hyaluronidase combined with its ability to reduce friction and wear indicate its potential as an advantageous biolubricant. 相似文献
159.
We give a short proof that the largest component C
1 of the random graph G(n, 1/n) is of size approximately n
2/3. The proof gives explicit bounds for the probability that the ratio is very large or very small. In particular, the probability
that n
−2/3|C
1| exceeds A is at most e - cA3{e^{ - c{A^3}}} for some c > 0. 相似文献
160.
We study the scaling limits of three different aggregation models on ℤ
d
: internal DLA, in which particles perform random walks until reaching an unoccupied site; the rotor-router model, in which
particles perform deterministic analogues of random walks; and the divisible sandpile, in which each site distributes its
excess mass equally among its neighbors. As the lattice spacing tends to zero, all three models are found to have the same
scaling limit, which we describe as the solution to a certain PDE free boundary problem in ℝ
d
. In particular, internal DLA has a deterministic scaling limit. We find that the scaling limits are quadrature domains, which
have arisen independently in many fields such as potential theory and fluid dynamics. Our results apply both to the case of
multiple point sources and to the Diaconis-Fulton smash sum of domains. 相似文献