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41.
Yamazaki Kazuyoshi Hosaka Makoto Yamada Kenichiro Ogata Takeshi Shimada Kenichi 《Optical Review》2016,23(5):848-858
Optical Review - A precise and fast method for controlling the reference-beam angle of an angular-multiplexed holographic data storage system (HDSS)—to achieve larger capacity and faster... 相似文献
42.
Chiral Palladacycle Catalysts Generated on a Single‐Handed Helical Polymer Skeleton for Asymmetric Arylative Ring Opening of 1,4‐Epoxy‐1,4‐dihydronaphthalene
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Dr. Takeshi Yamamoto Yuto Akai Prof. Dr. Michinori Suginome 《Angewandte Chemie (International ed. in English)》2014,53(47):12785-12788
Post‐polymerization C? H activation of poly(quinoxaline‐2,3‐diyl)‐based helically chiral phosphine ligands (PQXphos) with palladium(II) acetate afforded chiral phosphapalladacycles quantitatively. In situ generated palladacycles exhibited enantioselectivities up to 94 % ee in the palladium‐catalyzed asymmetric ring‐opening arylation of 1,4‐epoxy‐1,4‐dihydronaphthalenes with arylboronic acids. 相似文献
43.
44.
Elaine Tsui Anthony J. Metrano Yuto Tsuchiya Robert R. Knowles 《Angewandte Chemie (International ed. in English)》2020,59(29):11845-11849
We report a catalytic, light‐driven method for the intramolecular hydroetherification of unactivated alkenols to furnish cyclic ether products. These reactions occur under visible‐light irradiation in the presence of an IrIII‐based photoredox catalyst, a Brønsted base catalyst, and a hydrogen‐atom transfer (HAT) co‐catalyst. Reactive alkoxy radicals are proposed as key intermediates, generated by direct homolytic activation of alcohol O?H bonds through a proton‐coupled electron‐transfer mechanism. This method exhibits a broad substrate scope and high functional‐group tolerance, and it accommodates a diverse range of alkene substitution patterns. Results demonstrating the extension of this catalytic system to carboetherification reactions are also presented. 相似文献
45.
Proteome analysis of Oncorhynchus species during embryogenesis 总被引:3,自引:0,他引:3
Kanaya S Ujiie Y Hasegawa K Sato T Imada H Kinouchi M Kudo Y Ogata T Ohya H Kamada H Itamoto K Katsura K 《Electrophoresis》2000,21(9):1907-1913
To understand the molecular mechanisms underlying normal and abnormal development of two salmonids, masu salmon (Oncorhynchus masou) and rainbow trout (O. mykiss), we used two-dimensional (2-D) electrophoresis to construct a series of 2-D maps during the embryonic period. We identified all visible protein spots on the 2-D map by assigning numbers for masu salmon and rainbow trout, and we determined N-terminal sequences of proteins for one hundred of the spots, that appear at very high concentrations in the whole embryos of masu salmon and rainbow trout. We also characterized embryonic stages according to the periods of appearance of spots. Most of the N-terminal sequences were identical or at least highly similar to partial sequences reported for vitellogenin (Vtg) of O. mykiss. A potential proteolytic processing of Vtg for rainbow trout is discussed in relation to the time of appearance and relative position of Vtg fragments within the complete protein sequence. 相似文献
46.
Tsuyoshi Satoh Takayuki Kuramoto Shingo Ogata Hiroyuki Watanabe Takahito Saitou Makoto Tadokoro 《Tetrahedron: Asymmetry》2010,21(1):1-5
Treatment of enantiomerically pure 1-chlorovinyl p-tolyl sulfoxides, derived from cyclic ketones and (R)-chloromethyl p-tolyl sulfoxide, with the lithium enolate of tert-butyl carboxylates gave adducts in quantitative yields as single diastereomers. The adducts were treated with i-PrMgCl in toluene to afford optically active bicyclo[n.1.0]alkanes bearing a tert-butyl carboxylate moiety in up to 99% enantiomeric excess through the enantioselective 1,3-CH insertion reaction of the generated chiral magnesium carbenoids. This is the first example of the enantioselective 1,3-CH insertion reaction of magnesium carbenoid. 相似文献
47.
T. Ohshima M. Tanaka K. Katori M. Fujiwara H. Ogata M. Kondo N. Shimakura 《Hyperfine Interactions》1993,78(1-4):251-257
Nuclear polarization was measured by means of beam foil spectroscopy for a3He+ ion produced by an electron capture process of a3He2+ from a polarized sodium atom in an incident energy range from 20 to 28 keV. Assuming that a polarized electron of a sodium atom is predominantly captured to the 3d orbital of a3He+ ion andcascades down to the 1s ground state via the 2p orbital, an alignment factorA
0
col
(L=2) for the 3d orbital of a3He+ ion was extracted by comparing the observed initial sodium polarization andfinal nuclear polarization. The observedA
0
col
(L=2) showed a less pronounced energy dependence andwere qualitatively reproduced by the theoretical calculation. 相似文献
48.
The divalent ruthenium complexes bearing benzene, mesitylene triphenylbenzene as a π-ligand were prepared and their catalytic activity for olefin hydrogenation was examined. They showed activity in the presence of a small amount of base. Particularly, the complex with triphenylbenzene was found to have extremely high activity. Discussion here is on a role of a π-arene ligand in the activity. 相似文献
49.
50.
The hydrodynamic instability of surfactant solutions between two coaxial cylinders was investigated by using a laser-induced-fluorescence flow visualization technique to clarify the effect of drag-reducing additives on vortex formation in Taylor-Couette flow. The test fluids were Ethoquad O/12 surfactant solutions, which have a gel-like structure called “shear-induced structurer” (SIS). Photographs of the formation of Görtler vortices were taken and compared with these of tap water. In the Taylor number range of 1.2×105≤Ta≤7.1×105, tap water and 10 ppm surfactant solution flows consisted of Taylor vortices and much smaller Görtler vortices at the rotating inner wall. However, for 50 and 100 ppm surfactant solutions, Taylor vortices were not apparent and Görtler vortices were collapsed. Measurements of the wavelength of Görtler vortices lead to the conclusion that surfactant solutions have a stabilizing effect on Görtler instabilities. This effect depends on surfactant concentration and becomes considerable with increasing acceleration of the inner cylinder. 相似文献