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991.
Masanobu Isshiki Porponth Sichanugrist Yusuke Abe Takuji Oyama Hidefumi Odaka Makoto Konagai 《Current Applied Physics》2014,14(12):1813-1818
High transmittance of transparent conductive oxide (TCO) substrates is one of the most important factors for achieving high efficiency in thin-film silicon solar cells. Immersion (IM) method with CH2I2 liquid is widely used for the evaluation of optical properties (transmittance, reflectance and absorption) for TCO substrates with textured surface in order to reduce the scattering at the TCO surface. However, in order to measure transmittance accurately, three problems have been found. (1) CH2I2 liquid itself absorbs the light in short wavelength region. (2) The transmittance around the absorption edge of CH2I2 liquids is very sensitive to its amount. (3) Scattering cannot be suppressed when the scattering surfaces are more than 2 surfaces (for example, TCO on reactive ion etching (RIE) processed glass). To overcome these problems, we proposed a new setup to measure optical properties of TCO substrates by holding the samples inside the integral sphere. As the results, we have confirmed that their absorption in all wavelength could be measured accurately and the transmittance measured by the new method was well consistent with the external quantum efficiency (EQE) of the fabricated cell while the transmittance measured with conventional IM method showed differently. Therefore, this new method could be a useful tool to evaluate TCO substrates for thin-film silicon solar cells. 相似文献
992.
993.
Nobuyuki Sakai Dr. Yusuke Fujiwara Yukina Takahashi Dr. Tetsu Tatsuma Prof. 《Chemphyschem》2009,10(5):766-769
Reversed photoresponse: Indium tin oxide (ITO)/Au nanoparticle (NP)/TiO2 electrodes (see picture) exhibit cathodic photocurrents and positive photopotentials under visible light, whereas ITO/TiO2/Au NP electrodes show an inverted response. This behavior indicates that electron transfer occurs from the plasmon‐excited Au NPs to the TiO2 film. An enhanced O2 photoreduction activity is found for ITO/Au NP/TiO2/Pt electrodes.
994.
995.
Tomoe Sanada Hisakazu Seto Yusuke Morimoto Kazuhiro Yamamoto Noriyuki Wada Kazuo Kojima 《Journal of Sol-Gel Science and Technology》2010,56(1):82-86
To develop new fluorescent and afterglow materials, Mn2+ and Eu3+ co-doped ZnO–GeO2 glasses and glass ceramics were prepared by a sol–gel method and their optical properties were investigated by measuring
luminescence, excitation and afterglow spectra, and luminescence quantum yield (QY). Under UV irradiation at 254 nm, some
glasses and all of the glass ceramics showed green luminescence peaking at 534 nm due to the 4T1 → 6A1 transition of tetrahedrally coordinated Mn2+ ions. The strongest luminescence was observed in a glass ceramic of 0.1MnO–0.3Eu2O3–25ZnO–75GeO2 heat treated at 900 °C, with QY of 49.8%. All of the green-luminescent glasses and glass ceramics showed green afterglow,
and the afterglow lasting for more than 60 min was obtained in a glass ceramic heat treated at 900 °C. It is considered that
the Eu3+ ions may behave as electron trapping centers to be associated with the occurrence of the green afterglow due to the Mn2+ ions in the co-doped system. 相似文献
996.
997.
Yusuke Sato Toshiki Ichihashi Zhiai Xu Seiichi Nishizawa 《Analytica chimica acta》2010,675(1):49-14110
By using iodide (I−) as a quencher, we successfully improve the fluorescence response of amiloride when binding to thymine opposite an AP site in a 21-meric DNA duplex. From fluorescence measurements, as compared to the NaCl solutions, the addition of NaI as a quencher as well as salt to adjust the ionic strength effectively suppresses the background fluorescence from unbound amiloride in a solution. The Stern-Volmer analysis shows that the bound amiloride to the nucleobase at the AP site is unexposed to NaI quencher. Therefore the high signal-to-background fluorescence response of amiloride is obtained. Such enhancement in fluorescence response of amiloride by using the quencher can provide the significant improvement of the detection limit for DNA duplexes carrying T target base. The method presented in this study is simple and effective. The present method could be applicable to other detection system where microenvironment of fluorophores changes at a recognition event. 相似文献
998.
Yamauchi Y Itagaki T Yokoshima T Kuroda K 《Dalton transactions (Cambridge, England : 2003)》2012,41(4):1210-1215
Preparation of Ni nanoparticles between montmorillonite layers using dimethylaminoborane (DMAB) as a reducing agent is reported. The DMAB molecules are first intercalated into the interlayer space of Ni-montmorillonite (Ni-mont). Then, as a result of a heating process, the DMAB is decomposed to release electrons for the reduction of the Ni ions. From high-resolution TEM images, it is demonstrated that the deposited Ni nanoparticles with about 1-2 nm in size are formed uniformly over the entire area of the Ni-mont matrix. Considering the gallery height calculated by subtracting the silicate sheet thickness from the basal spacing (1.30 nm), the morphology of the formed Ni nanoparticles in the interlayer space is thought to be disc-like in shape with a thickness of 0.3-0.4 nm and an average lateral size of 1.2 nm. 相似文献
999.
1000.
A method for synthesizing highly strained cyclic structures by combining photochromic and synthetic reactions is described. Tightly linked azobenzene-binaphthyl dyads (R)-4 and (R)-6 could not be obtained by conventional cyclization, but continuous application of photoirradiation, which induced (E)→(Z) isomerization of the azobenzene moiety, allowed the cyclization reaction to proceed, affording the desired chiral azobenzenophanes. 相似文献