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排序方式: 共有616条查询结果,搜索用时 15 毫秒
81.
Yusuf Uar Nuri M. Yamurlu hsan elikkaya 《Numerical Methods for Partial Differential Equations》2019,35(2):478-492
The aim of this study is to obtain numerical behavior of a one‐dimensional modified Burgers' equation using cubic B‐spline collocation finite element method after splitting the equation with Strang splitting technique. Moreover, the Ext4 and Ext6 methods based on Strang splitting and derived from extrapolation have also been applied to the equation. To observe how good and effective this technique is, we have used the well‐known the error norms L2 and L∞ in the literature and compared them with previous studies. In addition, the von Neumann (Fourier series) method has been applied after the nonlinear term has been linearized to investigate the stability of the method. 相似文献
82.
The differential cross sections for coherent scattering of 59.5 keV γ-rays by Mo and Sn were measured using a high-purity germanium detector. The results were compared with predictions of form factor theories and S-matrix calculations. 相似文献
83.
84.
Baris Kiskan Güniz Demiray Yusuf Yagci 《Journal of polymer science. Part A, Polymer chemistry》2008,46(11):3512-3518
Novel side‐chain benzoxazine functional polyvinylchloride (PVC‐Benzoxazine) was synthesized by using “Click Chemistry” strategy. First, approximately 10% of chloro groups of PVC were converted to azido groups by using NaN3 in N,N‐dimethylformamide. Propargyl benzoxazine was prepared independently by a ring closure reaction between p‐propargyloxy aniline, paraformaldehyde, and phenol. Finally, azidofunctionalized PVC was coupled to propargyl benzoxazine with high efficiency by click chemistry. The spectral and thermal analysis confirmed the presence of benzoxazine functionality in the resulting polymer. It is shown that PVC containing benzoxazine undergoes thermally activated curing in the absence of any catalyst forming PVC thermoset with high thermal stability. © 2008 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 46: 3512–3518, 2008 相似文献
85.
Seda Yurteri Ioan Cianga A. Levent Demirel Yusuf Yagci 《Journal of polymer science. Part A, Polymer chemistry》2005,43(4):879-896
1,4‐Dibromo‐2‐(bromomethyl)benzene and 1,3‐dibromo‐5‐(bromomethyl)benzene were used as initiators in the atom transfer radical polymerization of styrene in conjunction with CuBr/2,2′‐bipyridine as a catalyst. The resulting polystyrene (PSt)‐based macromonomers, possessing at one end a 2,5‐dibromophenylene or 3,5‐dibromophenylene moiety, were used in combination with 2,5‐dihexylbenzene‐1,4‐diboronic acid for Suzuki coupling in the presence of Pd(PPh3)4 as a catalyst or with the system NiCl2/2,2′‐bipyridine/triphenylphosphine/Zn for Yamamoto polymerization. Polyphenylenes (PPs) with PSt chains as substitution groups were obtained. The same macromonomers were used in Yamamoto copolycondensation reactions, in combination with a poly(ε‐caprolactone) (PCL) macromonomer, and this resulted in PPs with PSt/PCL side chains. The obtained PPs had good solubility properties in common organic solvents at room temperature similar to those of the starting macromonomers. The new polymers were characterized with 1H (13C) NMR, IR, and gel permeation chromatography. The optical properties of the polymers were monitored with UV and fluorescence spectroscopy. The thermal behaviors of the macromonomers and final PPs were investigated with differential scanning calorimetry and compared. The morphology of PPs containing PSt and PCL blocks was characterized with atomic force microscopy, and a microphase‐separated layered morphology was observed. © 2005 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 43: 879–896, 2005 相似文献
86.
The methodology and numerical solution of problems concerning transport processes via the method of differential quadrature are presented. Application of the method is demonstrated by solving a simple one-dimensional, time-dependent (transient) diffusion process involving an irreversible reaction without any flux across the end boundary. In addition, the same technique is used (for the first time to the authors' knowledge) to solve a steady-state problem. For this purpose, a convection-diffusion problem involving an irreversible reaction is considered. The demonstration is carried out in two ways, (1) using the Bellman et al. technique which employs approximation formulas for higher order partial derivatives derived by iterating the linear quadrature approximation for the first order partial derivative, and (2) using individual quadratures to approximate the partial derivatives of first, as well as higher orders, as suggested by Mingle. Both approaches give the same results; however, the latter saves an appreciable amount of iterative computing effort despite the fact that it requires separate weighting coefficients for each individual quadrature. Since the technique of differential quadrature can produce solutions with sufficient accuracy even when using as few as three discrete points, both the programming task and computational effort are alleviated considerably. For these reasons the differential quadrature approach appears to be very practical in solving a variety of problems related to transport phenomena. 相似文献
87.
Civan F 《Journal of colloid and interface science》2005,285(1):429-432
The validity of the Vogel-Tammann-Fulcher type asymptotic exponential functions for representing the temperature dependence of various properties, such as the particle-particle pull-off adherence forces in ice and hydrates and the annealing effect on polystyrene latex films, is demonstrated. The parameters of this equation are determined using the reported experimental data. The applications show that such functions yield accurate correlations of the experimental property data measured at various temperatures. 相似文献
88.
Yusuf Yaci Anthony Ledwith 《Journal of polymer science. Part A, Polymer chemistry》1988,26(7):1911-1918
Polymerization of tetrahydrofuran (THF) (bulk) promoted by a free radical source, 2,2-dimethoxy-2-phenyl acetophenone (DMPA), in the presence of 4,4′-di-(methylphenyl)iodonium hexafluorophosphate was studied in detail. Rate dependence of the polymerizing system on both DMPA and the iodonium salt was studied dilatometrically. Rate saturation for the iodonium salt was attributed to the formation of iodobenzene, which may react with propagating cations to form an iodonium salt. DMPA was shown to be an efficient transfer agent in the cationic polymerization of THF. A transfer constant for DMPA was estimated to be 2.8 and, whilst the precise details of the overall mechanism cannot be deduced from the present results, it may result in functionalized polytetrahydrofuran chains having photochemically active end groups. 相似文献
89.
The effects of sulfur dioxide (SO(2)), sodium chloride (NaCl), and peroxymonosulfate or oxone (2KHSO(5).KHSO(4).K(2)SO(4) with active ingredient, HSO(5)(-)) on the sonochemical removal of nitric oxide (NO) have been studied in a bubble column reactor. The initial concentration of NO studied ranged from about 500 to 1040 ppm. NaCl in the concentration range of 0.01-0.5 M was used as the electrolyte to study the effect of ionic strength. At the low NaCl concentration (0.01 M), the percent fractional removal of NO with initial concentration of 1040 ppm was enhanced significantly, while as the NaCl concentration increased, the positive effects were less pronounced. The presence of approximately 2520 ppm SO(2) in combination with 0.01 M NaCl further enhanced NO removal. However, with a NO initial concentration of 490 ppm, the addition of NaCl was detrimental to NO removal at all NaCl concentration levels. The combinative effect of sonication and chemical oxidation using 0.005-0.05 M oxone was also studied. While the lower concentrations of HSO(5)(-) enhanced NO removal efficiency, higher concentrations were detrimental depending on the initial concentration of NO. It was also demonstrated that in the presence of ultrasound, the smallest concentration of oxone was needed to obtain optimal fractional conversion of NO. 相似文献
90.
Amit Kumar S. M. Yusuf J. V. Yakhmi 《Applied Physics A: Materials Science & Processing》2010,99(1):79-83
We have synthesized nanoparticles of Cu1.5[Cr(CN)6]⋅6.5H2O of varying size by using poly(vinylpyrrolidone) (PVP) as a protecting polymer. The particle size variation has been achieved
by varying the amount of the PVP surfactant with the reactants. The prepared nanoparticles have been investigated by using
X-ray diffraction, transmission electron microscopy, and direct-current magnetization techniques. The nanoparticles crystallize
in a face centred cubic structure (space group: Fm3m). The approximate particle sizes for the three samples are 18, 9, and
5 nm, respectively. Non-PVP nanoparticles (18 nm) show a magnetic ordering temperature of 65 K. A decrease in the magnetic
ordering temperature was observed with decreasing particle size. These nanoparticles are magnetically very soft, showing negligibly
small values of the coercivity and remanent magnetization. The maximum magnetization and spontaneous magnetization values
at 5 K are found to decrease with decreasing particle size. The observed magnetization behaviour of the nanoparticles has
been attributed to the increasing surface spin disorder with decreasing particle size. 相似文献