全文获取类型
收费全文 | 583篇 |
免费 | 29篇 |
国内免费 | 4篇 |
专业分类
化学 | 381篇 |
力学 | 20篇 |
数学 | 55篇 |
物理学 | 160篇 |
出版年
2024年 | 1篇 |
2023年 | 3篇 |
2022年 | 18篇 |
2021年 | 27篇 |
2020年 | 24篇 |
2019年 | 28篇 |
2018年 | 22篇 |
2017年 | 13篇 |
2016年 | 29篇 |
2015年 | 27篇 |
2014年 | 26篇 |
2013年 | 50篇 |
2012年 | 39篇 |
2011年 | 53篇 |
2010年 | 37篇 |
2009年 | 33篇 |
2008年 | 39篇 |
2007年 | 22篇 |
2006年 | 13篇 |
2005年 | 17篇 |
2004年 | 17篇 |
2003年 | 10篇 |
2002年 | 16篇 |
2001年 | 2篇 |
2000年 | 7篇 |
1999年 | 3篇 |
1998年 | 5篇 |
1997年 | 2篇 |
1996年 | 6篇 |
1995年 | 2篇 |
1994年 | 5篇 |
1993年 | 2篇 |
1992年 | 3篇 |
1989年 | 2篇 |
1988年 | 2篇 |
1987年 | 1篇 |
1985年 | 1篇 |
1984年 | 1篇 |
1983年 | 3篇 |
1981年 | 3篇 |
1979年 | 1篇 |
1972年 | 1篇 |
排序方式: 共有616条查询结果,搜索用时 0 毫秒
21.
Amit Kumar S. M. Yusuf J. V. Yakhmi 《Applied Physics A: Materials Science & Processing》2010,99(1):79-83
We have synthesized nanoparticles of Cu1.5[Cr(CN)6]⋅6.5H2O of varying size by using poly(vinylpyrrolidone) (PVP) as a protecting polymer. The particle size variation has been achieved
by varying the amount of the PVP surfactant with the reactants. The prepared nanoparticles have been investigated by using
X-ray diffraction, transmission electron microscopy, and direct-current magnetization techniques. The nanoparticles crystallize
in a face centred cubic structure (space group: Fm3m). The approximate particle sizes for the three samples are 18, 9, and
5 nm, respectively. Non-PVP nanoparticles (18 nm) show a magnetic ordering temperature of 65 K. A decrease in the magnetic
ordering temperature was observed with decreasing particle size. These nanoparticles are magnetically very soft, showing negligibly
small values of the coercivity and remanent magnetization. The maximum magnetization and spontaneous magnetization values
at 5 K are found to decrease with decreasing particle size. The observed magnetization behaviour of the nanoparticles has
been attributed to the increasing surface spin disorder with decreasing particle size. 相似文献
22.
Avcı Davut Altürk Sümeyye Sönmez Fatih Tamer Ömer Başoğlu Adil Atalay Yusuf Zengin Kurt Belma Dege Necmi 《Molecular diversity》2021,25(1):171-189
Molecular Diversity - The World Health Organization (WHO) report shows that diabetes mellitus (DM) will be one of the ten deadly diseases in the near future. The best way to prevent DM is to... 相似文献
23.
The methodology and numerical solution of problems concerning transport processes via the method of differential quadrature are presented. Application of the method is demonstrated by solving a simple one-dimensional, time-dependent (transient) diffusion process involving an irreversible reaction without any flux across the end boundary. In addition, the same technique is used (for the first time to the authors' knowledge) to solve a steady-state problem. For this purpose, a convection-diffusion problem involving an irreversible reaction is considered. The demonstration is carried out in two ways, (1) using the Bellman et al. technique which employs approximation formulas for higher order partial derivatives derived by iterating the linear quadrature approximation for the first order partial derivative, and (2) using individual quadratures to approximate the partial derivatives of first, as well as higher orders, as suggested by Mingle. Both approaches give the same results; however, the latter saves an appreciable amount of iterative computing effort despite the fact that it requires separate weighting coefficients for each individual quadrature. Since the technique of differential quadrature can produce solutions with sufficient accuracy even when using as few as three discrete points, both the programming task and computational effort are alleviated considerably. For these reasons the differential quadrature approach appears to be very practical in solving a variety of problems related to transport phenomena. 相似文献
24.
Koksal Yildiz Unal Akgul Hartmut S. Leipner Yusuf Atici 《Applied Physics A: Materials Science & Processing》2014,117(3):1387-1392
The film of thermoelectric ternary p-type (Bi0.15Sb0.85)2Te3 was deposited on polyimide foil substrate at 168 °C using direct-current magnetron sputtering. Microstructural investigations of the film were performed by electron microscopy techniques. SEM observations showed that the film surface consisted of large-sized particulates with small-sized particles and also mound-like crystal agglomerates in some areas. Chemical composition of the film was analyzed using energy-dispersive X-ray spectrometer (EDS). It has been observed that the EDS results were in an agreement with nominal composition for the film. Detailed microstructural investigations were carried out using transmission electron microscopy (TEM). TEM images and selected area electron diffraction patterns showed that the film has randomly oriented polycrystalline grain structure. High-resolution TEM images indicated that the microstructure of film also contained nano-crystal structure, smaller than 10 nm. 相似文献
25.
Sharma VK Mitra S Kumar A Yusuf SM Juranyi F Mukhopadhyay R 《J Phys Condens Matter》2011,23(44):446002
Here we report the dynamical behaviour of water in Prussian blue analogue (PBA) Cu(0.75)Mn(0.75)[Fe(CN)(6)]·7H(2)O molecular magnet in the temperature range 260-360 K as studied using the quasielastic neutron scattering technique. While significant quasielastic broadening is observed in the hydrated sample, no broadening was observed in the dehydrated one. Data analysis showed that the observed quasielastic broadening in Cu(0.75)Mn(0.75)[Fe(CN)(6)]·7H(2)O corresponds to the dynamics of the non-coordinated water molecules at the 32f site and the coordinated water molecules at the 24e site, existing in the cavities created by the absence of Fe(CN)(6) units. The non-coordinated water molecules at 8c interstitial sites do not contribute to the broadening, suggesting that they are immobile at least within the time window of the spectrometer used. Behaviour of the elastic incoherent structure factor is consistent with the model where the water molecules undergo translational diffusion localized within the cavity of 5.1 ?. While all the non-coordinated water molecules at the 32f site are dynamic over the entire range of temperatures, the coordinated ones at the 24e site become progressively dynamic with temperature. The water molecules were found to undergo hindered (~1.16 × 10(-5) cm(2) s(-1) at 300 K) diffusion compared to bulk water and the diffusivity followed Arrhenius behaviour within the measured temperature range with an activation energy of 1.26 kcal mol(-1). 相似文献
26.
Yusuf Z. Umul 《Optik》2014
The scattering integrals of the modified theory of physical optics are redefined according to the illuminated and unlit surfaces of the scattering object. With this aim the canonical problem of wedge diffraction is taken into account. It is shown that the new scattering integral contain two geometrical optics and diffracted fields. One of the geometrical optics waves is the reflected field component that propagates in the real space. The other one transmits to an imaginary space through the scattering surface and does not have any influence in the real space. The diffracted waves exist in the real space and satisfy the related boundary condition on the scattering surfaces. The resultant field expressions are compared with the exact series solution of the problem numerically. 相似文献
27.
Yusuf Ziya Umul 《Optik》2012,123(19):1786-1791
The transmission and diffraction of waves by an aperture in an impedance screen is investigated. The Senior's solution of the scattering problem of waves by an impedance half-plane is transformed into a physical optics type integral. The obtained method is applied to the transmission problem of waves by a slit in an impedance screen. The results are compared with the aperture problem in black and conducting screens numerically. 相似文献
28.
Yusuf Öztürk Asım Egemen Yılmaz Evrim Çolak Ekmel Özbay 《Photonics and Nanostructures》2012,10(4):624-631
Planar metamaterials, which have incident to normal plane excitation unlike SRR-type structures and that are easily fabricated in multilayer form, have received great interest in recent years. In this paper, one-dimensional and polarization independent circular fishnet metamaterials and their equivalent discontinuous slab-pair modeling for tuning resonance frequencies are introduced. After the numerical and experimental demonstration of the inclusions, the standard retrieval characterization methods and the correspondent/related backward-wave propagation observation are realized in order to check the physical explanation mentioned in the paper. In addition, a detailed phase analysis is performed in order to demonstrate the application of the suggested structure as a phase compensator. 相似文献
29.
Yusuf Ziya
Umul 《等离子体物理论文集》2020,60(8):e202000009
The interaction of magnetic polarized electromagnetic wave with a resistive half-plane in magneto-ionic plasma is investigated. The method of transition boundary is used for the evaluation of the diffracted wave. The excitation of surface waves is examined in the medium and their diffracted fields are derived by using the diffraction theory for grazing incidence. The uniform field expressions are obtained with the aid of the uniform theory for evanescent waves. The behaviours of the derived scattered waves are studied numerically. 相似文献
30.
Selcuk Denizligil Aysegul Baskan Yusuf Yagci 《Macromolecular rapid communications》1995,16(5):387-391
The polymerization of tetrahydrofuran was initiated with 4,4′-azobis(4-cyanovaleryl chloride) in conjunction with silver hexafluoroantimonate and the living polytetrahydrofuran (PTHF) was terminated with pyridinium N-oxide derivatives. The resulting PTHF-macroinitiator possesses both a thermally and photochemically labile group. 相似文献