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61.
Yury J. Ionin 《Discrete Mathematics》2006,306(14):1557-1568
The first infinite families of symmetric designs were obtained from finite projective geometries, Hadamard matrices, and difference sets. In this paper we describe two general methods of constructing symmetric designs that give rise to the parameters of all other known infinite families of symmetric designs. The method of global decomposition produces an incidence matrix of a symmetric design as a block matrix with each block being a zero matrix or an incidence matrix of a smaller symmetric design. The method of local decomposition represents incidence matrices of a residual and a derived design of a symmetric design as block matrices with each block being a zero matrix or an incidence matrix of a smaller residual or derived design, respectively. 相似文献
62.
Yury Nikulin 《Journal of Heuristics》2008,14(4):391-402
This paper addresses the robust spanning tree problem with interval data, i.e. the case of classical minimum spanning tree
problem when edge weights are not fixed but take their values from some intervals associated with edges. The problem consists
of finding a spanning tree that minimizes so-called robust deviation, i.e. deviation from an optimal solution under the worst
case realization of interval weights. As it was proven in Kouvelis and Yu (Robust Discrete Optimization and Its Applications,
Kluwer Academic, Norwell, 1997), the problem is NP-hard, therefore it is of great interest to tackle it with some metaheuristic approach, namely simulated
annealing, in order to calculate an approximate solution for large scale instances efficiently. We describe theoretical aspects
and present the results of computational experiments. To the best of our knowledge, this is the first attempt to develop a
metaheuristic approach for solving the robust spanning tree problem. 相似文献
63.
64.
Buckling of slender structures under compressive loading is a failure of infinitesimal stability due to a confluence of two
factors: the energy density non-convexity and the smallness of Korn’s constant. The problem has been well understood only
for bodies with simple geometries when the slenderness parameter is well defined. In this paper, we present the first rigorous
analysis of buckling for bodies with complex geometry. By limiting our analysis to the “near-flip” instability, we address
the universal features of the buckling phenomenon that depend on neither the shape of the domain nor the degree of constitutive
nonlinearity of the elastic material.
相似文献
65.
Synthesis of Carbon/Sulfur Nanolaminates by Electrochemical Extraction of Titanium from Ti2SC
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Dr. Meng‐Qiang Zhao Morgane Sedran Zheng Ling Maria R. Lukatskaya Olha Mashtalir Michael Ghidiu Boris Dyatkin Darin J. Tallman Prof. Thierry Djenizian Prof. Michel W. Barsoum Prof. Yury Gogotsi 《Angewandte Chemie (International ed. in English)》2015,54(16):4810-4814
Herein we electrochemically and selectively extract Ti from the MAX phase Ti2SC to form carbon/sulfur (C/S) nanolaminates at room temperature. The products are composed of multi‐layers of C/S flakes, with predominantly amorphous and some graphene‐like structures. Covalent bonding between C and S is observed in the nanolaminates, which render the latter promising candidates as electrode materials for Li‐S batteries. We also show that it is possible to extract Ti from other MAX phases, such as Ti3AlC2 , Ti3SnC2 , and Ti2GeC, suggesting that electrochemical etching can be a powerful method to selectively extract the “M” elements from the MAX phases, to produce “AX” layered structures, that cannot be made otherwise. The latter hold promise for a variety of applications, such as energy storage, catalysis, etc. 相似文献
66.
Prof. Sergey N. Britvin Dr. Sergei A. Kashtanov Dr. Maria G. Krzhizhanovskaya Dr. Andrey A. Gurinov Dr. Oleg V. Glumov Dr. Stanislav Strekopytov Dr. Yury L. Kretser Prof. Anatoly N. Zaitsev Prof. Nikita V. Chukanov Prof. Sergey V. Krivovichev 《Angewandte Chemie (International ed. in English)》2015,54(48):14340-14344
The Group 18 elements (noble gases) were the last ones in the periodic system to have not been encountered in perovskite structures. We herein report the synthesis of a new group of double perovskites KM(XeNaO6) (M=Ca, Sr, Ba) containing framework‐forming xenon. The structures of the new compounds, like other double perovskites, are built up of the alternating sequence of corner‐sharing (XeO6) and (NaO6) octahedra arranged in a three‐dimensional rocksalt order. The fact that xenon can be incorporated into the perovskite structure provides new insights into the problem of Xe depletion in the atmosphere. Since octahedrally coordinated XeVIII and SiIV exhibit close values of ionic radii (0.48 and 0.40 Å, respectively), one could assume that XeVIII can be incorporated into hyperbaric frameworks such as MgSiO3 perovskite. The ability of Xe to form stable inorganic frameworks can further extend the rich and still enigmatic chemistry of this noble gas. 相似文献
67.
Impedimetric Detection of DNA Damage with the Sensor Based on Silver Nanoparticles and Neutral Red
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Yury Kuzin Anna Porfireva Veronika Stepanova Vladimir Evtugyn Ivan Stoikov Gennady Evtugyn Tibor Hianik 《Electroanalysis》2015,27(12):2800-2808
Novel electrochemical DNA‐sensor based on glassy carbon electrode (GCE) modified with Ag nanoparticles, Neutral red covalently attached to its surface and native DNA adsorbed on modifier coating was developed for the estimation of DNA damage on example of model system based on Fenton reagent. As was shown, the oxidation process resulted in synchronous increase of electron transfer resistance and capacitance measured by electrochemical impedance spectroscopy (EIS). The contribution of each sensor component on the signal was specified and sensitivity estimated against similar surface coatings. The shift of EIS parameters was found to be higher than that of similar biosensors reported. The DNA sensor was tested on the estimation of antioxidant capacity of green tea infusions again the results of coulometric titration with electrogenerated bromine. 相似文献
68.
Observation of the multiple halogenation of peptides in the electrospray ionization source
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Yury Kostyukevich Ekaterina Zhdanova Alexey Kononikhin Igor Popov Eugene Kukaev Eugene Nikolaev 《Journal of mass spectrometry : JMS》2015,50(7):899-905
The chlorination of peptides and proteins is an important posttranslational modification, which is a physiological signature of an enzyme myeloperoxidase and can serve as a potential biomarker of some diseases (Parkinson's disease, Alzheimer's disease, etc.). The quantification of the chlorinated peptides has been very challenging in part due to their low levels and artifacts associated with sample preparation. One of the most convenient and promising methods to detect and investigate the chlorinated peptides in the biological samples is the electrospray ionization (ESI) mass spectrometry coupled to the fragmentation techniques (collision‐induced dissociation and electron capture dissociation/electron transfer dissociation). We have shown that if the chlorine anions are present in the solution, then the peptide can undergo the chlorination during the ESI ionization. The effect was found to depend on the values of electric potentials of metal parts of the ESI interface. It was found that the grounding of ESI syringe results in the formation of an additional electric loop leading to the electrolytic production of Cl2 and as a consequence the hypochlorous acid inside the ESI needle. Hypochlorous acid reacts with amino groups of peptides and proteins producing chloramine or causing the protein cleavage. In the paper, it is shown on the example of the solution of the several peptides in the presence of HCl that by manipulating the ESI syringe potential, it is possible to create complexes with up to five Cl atoms for sample peptides when the ESI is operated in the positive mode. Copyright © 2015 John Wiley & Sons, Ltd. 相似文献
69.
Yury D. Fomin Elena N. Tsiok Valentin N. Ryzhov 《Journal of computational chemistry》2015,36(12):901-906
We present the molecular dynamics study of benzene molecules confined into the single wall carbon nanotube. The local structure and orientational ordering of benzene molecules are investigated. It is found that the molecules mostly group in the middle distance from the axis of the tube to the wall. The molecules located in the vicinity of the wall demonstrate some deviation from planar shape. There is a tilted orientational ordering of the molecules which depends on the location of the molecule. It is shown that the diffusion coefficient of the benzene molecules is very small at the conditions we report here. © 2015 Wiley Periodicals, Inc. 相似文献
70.