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21.
M. Yu. Berezkin E. G. Polyakov V. V. Turygin L. V. Kaabak A. V. Khudenko A. P. Tomilov 《Russian Journal of Applied Chemistry》2008,81(8):1360-1363
Anodic dissolution of ferroniobium in anhydrous methanol in the presence of sodium methylate was studied. The possibility of recovering pure hexamethoxyniobate from the electrolyzate and its conversion into niobium methylate with an iron content not exceeding 0.01% was analyzed. 相似文献
22.
We consider a discretized volume V consisting of finite, congruent and attached copies of a tile t. We find a group L
V
the orbit of which, when applied to t, is just V. We show the connection between the structural matrixQ in the formal solution of a boundary value problem formulated for volume V and the so called auxiliary matrix of the graph Γ
v
associated with V. We show boundary value problems to be isomorphic if the graphs associated with the volumes are isomorphic, or, if the covering
groups are Sunada pairs. 相似文献
23.
24.
A. S. Romakhin I. M. Zaripov Yu. G. Budnikova Yu. M. Kargin E. V. Nikitin A. P. Tomilov Yu. A. Ignat'ev 《Russian Chemical Bulletin》1992,41(6):1036-1040
The mechanism of the electrosynthesis of phosphate esters from white phosphorus was investigated. It was shown that the reaction takes place by two paths, i.e., monomeric (with the participation of dissolved phosphorus) and polymeric (with the participation of phosphorus on the surface of an emulsion drop). It was established that in an alcohol solution of tetraethylammonium iodide the main part of the final product is formed through an intermediate polymeric compound. It was noticed that by studying the dynamics of the accumulation of the dissolved product during electrolysis it is possible to trace the mechanism of reaction of the phosphorus at the individual stages of the process.A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan' Scientific Center, Russian Academy of Sciences, 420028 Kazan'. V. I. Ul'yanov-Lenin Kazan' State University, 420028 Kazan'. Translated fromIzvestiya Akademii Nauk, Seriya Khimicheskaya, No. 6, pp. 1328–1333, June, 1992. 相似文献
25.
Mironov YV Yarovoi SS Naumov DY Kozlova SG Ikorsky VN Kremer RK Simon A Fedorov VE 《The journal of physical chemistry. B》2005,109(50):23804-23807
The novel vanadium thiobromide, V4S9Br4, with a square-planar metal cluster core was synthesized and characterized by single-crystal X-ray diffraction, measurements of magnetic properties and the heat capacity, and DFT calculations of the electronic structure. At the room temperature, the compound displays paramagnetic properties with an independent spin on each V atom and with a weak exchange constant (J approximately 10 cm(-1)). The paramagnetic state is transformed into a low-spin state (AF-type ordering) at low temperatures. This change is accompanied by a heat-capacity anomaly. The observed magnetic and heat-capacity anomalies can be explained by the thermal excitation of electrons on the closely spaced molecular energy levels in the presence of the Jahn-Teller effect. 相似文献
26.
V. E. Pushkarev A. V. Ivanov I. V. Zhukov E. V. Shulishov Yu. V. Tomilov 《Russian Chemical Bulletin》2004,53(3):554-560
New hexadecaalkyl-substituted diphthalocyanine complexes of lanthanides RPc2Ln (R = Et, or Bu; Ln = Lu, Dy, or Eu) were synthesized by three methods: in solution in the presence of 1,8-diazabicyclo[5.4.0]undec-7-ene, in a melt of a mixture of the reagents, and under microwave irradiation. The first of the above-mentioned procedures has an advantage for the preparation of Dy and Eu diphthalocyanines, whereas the melt synthesis is a method of choice for the preparation of Lu complexes. The reaction time decreases in going from the first to the third method. The structures of the complexes were confirmed by mass spectrometry, NMR spectroscopy, and electronic absorption spectroscopy. 相似文献
27.
Weiping Huang Suwen Liu Xianghai Tang Menachem Motiei Yuri Koltypin A. Gedanken 《Research on Chemical Intermediates》2004,30(7-8):793-805
Ag-TiO2, Cu-TiO2 and Ni-TiO2 were prepared by sonication. The interactions of Ti-gel with silver, copper and nickel ions under ultrasound irradiation are very different, although these ions can be dispersed very well in titania. The results of EDXA and XRD analysis indicate that Ti-gel does not react with AgCl and crystallizes unaffectedly to form rutile. M(OH)2 (M = Cu and Ni), on the other hand, favors polycondensation with Ti-gel and affects the crystallization of Ti-gel. CuO favors stabilization of the anatase phase. Ni2+ ions tend to incorporate more easily into titania than Cu2+ ions do when the samples are calcined. TEM, and BET were also used to characterize the samples. 相似文献
28.
Dzhemilev U. M. Ibragimov A. G. Khafizova L. O. Khalilov L. M. Vasil"ev Yu. V. Tomilov Yu. V. 《Russian Chemical Bulletin》2001,50(2):297-299
1-Ethyl-2,3-fullerenoaluminacyclopropanes (EtAl)n(2-C60) were synthesized by the reaction of fullerene C60 with an excess of EtAlCl2 in the presence of Mg and using Cp2TiCl2 as the catalyst in a THF--toluene solution at 20 °C. Deuterolysis of fullerenoaluminacyclopropanes afforded a mixture of deuteriofullerenes C60Dm, where m = 6--12. 相似文献
29.
Sessler JL Roznyatovskiy V Pantos GD Borisova NE Reshetova MD Lynch VM Khrustalev VN Ustynyuk YA 《Organic letters》2005,7(23):5277-5280
[reaction: see text] Two easy-to-synthesize polypyrrolic 2,5-diamidothiophene Schiff base macrocycles are reported, along with their anion binding properties as determined via UV-vis spectroscopic titrations carried out in dichloroethane. There is a striking difference between the interactions with anions of the two macrocycles, a finding ascribed to differences in their rigidity. For example, the more flexible dipyrromethane-derived macrocycle displays a 1.2:1 hydrogen sulfate versus nitrate selectivity, while its more rigid bipyrrole-derived congener shows a 7.4:1 selectivity in favor to hydrogen sulfate. 相似文献
30.
Yu. V. Tomilov I. V. Kostyuchenko E. V. Shulishov O. M. Nefedov 《Russian Chemical Bulletin》1998,47(4):666-668
The reaction of diazocyclopropane generatedin situ with vinyl bromide occurs as regioselective 1,3-dipolar cycloaddition to give 5-bromospiro(1-pyrazoline-3,1′-cyclopropane)
in ∼60% yield. Reactions of the latter with nucleophilic reagents, which can occur both with retention and opening of the
cyclopropane ring, were studied.
Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 4, pp. 688–690, April 1998. 相似文献