Theoretical Study on the Mass Transfer of Metal Ions in Ion Exchange Process

The kinetics of ion exchange between Ca2 , Mg2 , Co(Ⅱ), Cu(Ⅱ),Ni(Ⅱ), Fe(Ⅲ), y3 or Sm3 , respectively, in 0.50 mol/L HC1 and H on macrorecticular sulfonic ion exchange resin and the kinetics of the same reactions (M -H exchange) when Mn(Ⅱ) coexisted in resin phase as accelerating ion were studied. The accelerating effect manifested and its rule are consistent with the accelerating effect theory based on the concept concerned with adsorption electrical double layer which has been suggested in a previous paper published.     

稀土元素在LD30铝合金真空钎焊中的作用

研究了添加La和Ce的Al-Si基钎料真空钎焊LD30铝合金接头的力学性能，微观组织形貌和EDS，并与未添加稀土元素的Al-Si基钎料真空钎焊接头进行对比。结果表明，添加稀土元素的LD30铝合金真空钎焊接头抗拉强度为288MPa，达母材抗拉强度的97．6％，明显高于未添加稀土的LD30合金真空钎焊接头。其机制在于La,Ce能够明显提高Al-Si基钎料与LD30铝合金的润湿性能，改善LD30铝合金真空钎焊接头焊缝及其基体中杂质元素的分布，促进钎料和母材中各元素的均匀扩散，从而提高真空钎焊接头的力学性能。     

Design and synthesis of 2-alkylbenzimidazole derivatives as novel non-peptide angiotensin Ⅱ AT1 receptor antagonists

A series of 2-alkylbenzimidazole derivatives 9a-n have been designed and synthesized as a novel class of non-peptide angiotensin Ⅱ AT1 receptor antagonists. The synthesized compounds were evaluated for their antagonism of angiotensin Ⅱ, induced contraction in the rabbit thoracic aortic ring and the results showed that compounds 9a, 9g and 9j exhibited potent antagonistic activity of AT1 receptor.     

A new catalyst for direct synthesis of dimethyl ether from synthesis gas

A new catalyst has been prepared by coprecipitation sedimentation method developed in our laboratory. It exhibits excellent catalytic activity, selectivity and stability for conversion of synthesis gas to dimethyl ether: conversion of CO 92%, selectivity of dimethyl ether 98%. Catalytic properties of the catalyst show no evident change after being used for 100 h.     

Efficient syntheses of imidazolo[1,2-a]pyridines and -[2, 1-a]isoquinolines

2-Aminopyridines 1a-c and 1-aminoisoquinoline with 1-chloromethylbenzotriazole give 2-amino-1-[alpha-benzotriazol-1-ylmethyl]pyridinium chlorides 2a-c and 1-amino-2-(alpha-benzotriazol-1-ylmethyl)isoquinolinium++ + chloride 12, respectively. Compounds 2a-c and 12 react with aryl aldehydes 3a-h to afford imidazolo[1,2-a]pyridines 7a-k and imidazolo[2, 1-a]isoquinolines 13a,b in good yields.