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991.
Peng Dong Zeyu Li Dong Ji Xiaorui Wang Hongfei Yun Zhisong Du Jie Bian Guixian Li 《Journal of inclusion phenomena and macrocyclic chemistry》2018,90(1-2):149-155
Modified Y type catalyst (M-Y) shows great potential for the preparation of toluene attribute to catalyst topology and synergistic effect of Lewis acid and Brönsted acid in the alkylation reaction. However, it still remains a big challenge to build a reaction mechanism. Thereby, based on the study of HZSM-5, H-beta and M-Y catalysts structure and physical properties, a plausible reaction mechanism was proposed. The samples were characterized by X-ray diffraction, N2 adsorption/desorption, Fourier transform infrared absorption spectra and Pyridine adsorption infrared. The activity of catalysts was tested in benzene alkylation with methanol and was found to be in the following increasing order: Na-Y (no effect)?<?H-Y?<<?HZSM-5?<?H-beta?<?M-Y. 相似文献
992.
Guangping Wan Hongjun Xia Jun Wang Jiawei Liu Botao Song Ying Yang Quan Bai 《中国化学快报》2018,29(1):213-216
The monodisperse superficially porous core-shell silica microspheres (CSSMs) with controllable shell thickness and pore size were synthesized by an improved polymerization-induced colloid aggregation (PICA) approach for fast separation of small solutes and proteins. 相似文献
993.
Jing Wu Ying Qu Kun Shi Bingyang Chu Yanpeng Jia Xue Xiao Qianjun He Zhiyong Qian 《中国化学快报》2018,29(12):1819-1823
The CPT was loaded into the HMSNs with the high loading capacity. Then the CPT@HMSNs were loaded into the PLEL thermosensitive hydrogels for local therapy to prevent the recurrence of breast cancer after the tumor was resected. 相似文献
994.
选择了市场上口碑好、占有率高的3款便携式水质现场应急检测设备,通过准确度、精密度、检测时长及价格等指标,以权重积分法对3款仪器进行了比选,结果表明德国MN公司的PF-12型便携式多参数分光光度计的综合性能最优. 相似文献
995.
Zhiquan Yang Jie Ding Jinna Feng Chong He Ying Li Xiaowen Tong Xiaojun Niu Hongguo Zhang 《应用有机金属化学》2018,32(4)
Because of their desired features, including very specific surface areas and designable framework architecture together with their possibility to be functionalized, Metal Framework (MOF) is a promising platform for supporting varied materials in respect of catalytic applications in water treatment. In this work, a novel visible‐light‐responsive photocatalyst that comprised BiVO4 together with MIL‐125(Ti), was synthesized by a two‐step hydrothermal approach. The characterization of as‐obtained samples as performed by X‐ray diffraction, scanning electron microscopy, high resolution transmission electron microscopy, Fourier transform infrared spectroscope, X‐ray photoelectron spectroscopy and ultraviolet‐visible diffuse reflection spectra. Rhodamine B was selected being a target for the evaluation of the photocatalytic function of as‐developed photocatalyst. The photocatalytic reaction parameters, for example, the content of BiVO4 as well as initial concentration of Rhodamine B was researched. The composite photocatalyst possessing Bi:Ti molar ratio of 3:2 brought to light the fact that the greatest photocatalytic activity had the ability to degrade 92% of Rhodamine B in 180 min. In addition to that, the BiVO4/MIL‐125(Ti) composite could keep its photocatalytic activity during the recycling test. The phenomenon of disintegration of the photo‐generated charges in the BiVO4/MIL‐125(Ti) composite was brought to discussion as well. 相似文献
996.
Guo‐yu Ren Jie Li Xu‐zhan Wei Jin‐hua Zhou Biao Yan Zhao‐qi Guo Ying‐hui Ren Xiao‐hong Sun Hai‐xia Ma 《应用有机金属化学》2018,32(9)
In order to screen effective fungicides, three Zn (II) complexes, [Zn L 1 4 (NO3)2]·2H2O·2EtOH ( 1 ), [Zn L 2 4 (NO3)2] ( 2 ), and [Zn L 3 4 (DMF)2](NO3)2 ( 3 ), ( L 1 = paclobutrazol, L 2 = diniconazole, and L 3 = hexaconazole), were synthesized and characterized by elemental analysis, FT‐IR spectroscopy, and single‐crystal XRD. The antifungal activities of these complexes were then evaluated against four selected fungi using the mycelial growth rate method. The resulting data indicate that all the complexes show the enhanced antifungal activities than the corresponding ligand and mixtures. And, the interactions between the metal salt and ligands in the three complexes seem to be synergistic. According to the study of the influence of the structures on the activity, complex 2 with C=C linkage and 2,4‐dichlorophenyl moieties enhances the bioactivity significantly, especially against Wheat gibberellic ( II ). Density functional theory (DFT) calculations were carried out to help explain the enhanced bioactivity of the Zn (II) complexes. Meanwhile, all complexes are excellent grow‐regulators, especially complex 3 . The resulting data show that the complexes based on triazole fungicides have the potential applications in agriculture. 相似文献
997.
基于最低未被占据分子轨道(LUMO)和最高被占据分子轨道(HOMO)的高斯态密度分布与载流子在允许量子态中的费米-狄拉克(Fermi-Dirac)分布,提出有机半导体中物理掺杂的理论模型;研究了掺杂浓度、温度和禁带宽度对载流子浓度的影响,并与一些报道的实验结果做了比较.研究发现无论是否掺杂,温度升高时,有机半导体中的载流子浓度都会增大,并且随温度倒数的线性减小而指数增大;对于本征有机半导体,载流子浓度随禁带宽度的增大而指数下降,随高斯分布宽度的平方指数增加;对杂质和主体不同能级关系的掺杂情形下掺杂浓度对载
关键词:
有机半导体
掺杂
高斯态密度
载流子浓度 相似文献
998.
水溶液中Cr^3+的火焰原子吸收光谱法测试条件的优化 总被引:2,自引:0,他引:2
为优化火焰原子吸收光谱法测定水溶液中的Cr^3+的测试条件,分别采用单因素简单比较法、正交实验设计极差分析及正交实验回归方法考察了光谱通带n,空心阴极灯电流I,燃烧器高度h以及乙炔/空气流量比P对于仪器灵敏度的影响。结果表明单因素简单比较法获得的实验条件最优。乙炔/空气流量比P对火焰原子吸收仪器灵敏度影响最大、其次是光谱通带n,燃烧器高度h和灯电流I的影响很小。测定水溶液中的Cr^3+时仪器灵敏度最佳的实验条件为:乙炔/空气流量比P=0.4;光谱通带n=0.2nm;灯电流I=5mA;燃烧器高度h=5cm。 相似文献
999.
1000.
光学多普勒层析三维矢量测速方法研究 总被引:1,自引:0,他引:1
光学多普勒层析术(ODT)是一种高分辨、非侵入的生物医学成像手段,能同时得到组织的结构信息和组织内血管的流速信息.提出了一种新型的基于相位分辨技术的ODT三维矢量测速方法.在ODT系统样品臂的准直镜和聚焦透镜之间加入窄带相位片,形成三个不同的相位延迟,通过计算多普勒频移和不同相位延迟下的多普勒展宽,可得到毛细管内的三维矢量流场分布.对已知浓度的聚苯乙烯溶液进行了一系列不同角度和不同流速的实验,结果证明这种新型的ODT矢量测速方法可以较精确的实现三维矢量流速的测量. 相似文献