全文获取类型
收费全文 | 797篇 |
免费 | 20篇 |
国内免费 | 3篇 |
专业分类
化学 | 632篇 |
晶体学 | 10篇 |
力学 | 8篇 |
数学 | 39篇 |
物理学 | 131篇 |
出版年
2023年 | 6篇 |
2022年 | 2篇 |
2021年 | 6篇 |
2020年 | 9篇 |
2019年 | 10篇 |
2018年 | 6篇 |
2017年 | 4篇 |
2016年 | 16篇 |
2015年 | 15篇 |
2014年 | 17篇 |
2013年 | 40篇 |
2012年 | 30篇 |
2011年 | 65篇 |
2010年 | 26篇 |
2009年 | 27篇 |
2008年 | 51篇 |
2007年 | 45篇 |
2006年 | 60篇 |
2005年 | 47篇 |
2004年 | 48篇 |
2003年 | 47篇 |
2002年 | 42篇 |
2001年 | 15篇 |
2000年 | 12篇 |
1999年 | 14篇 |
1998年 | 9篇 |
1997年 | 8篇 |
1996年 | 7篇 |
1995年 | 9篇 |
1994年 | 5篇 |
1993年 | 6篇 |
1992年 | 8篇 |
1991年 | 6篇 |
1990年 | 8篇 |
1989年 | 7篇 |
1988年 | 8篇 |
1987年 | 6篇 |
1986年 | 4篇 |
1985年 | 8篇 |
1984年 | 5篇 |
1983年 | 2篇 |
1982年 | 3篇 |
1981年 | 11篇 |
1980年 | 6篇 |
1979年 | 9篇 |
1978年 | 8篇 |
1977年 | 12篇 |
1975年 | 1篇 |
1974年 | 1篇 |
1968年 | 2篇 |
排序方式: 共有820条查询结果,搜索用时 15 毫秒
71.
Tachi T Hase T Okamoto Y Kaji N Arima T Matsumoto H Kondo M Tokeshi M Hasegawa Y Baba Y 《Analytical and bioanalytical chemistry》2011,401(7):2301-2305
Microchip analysis is a promising method for therapeutic drug monitoring. This led us to evaluate a microchip-based fluorescence
polarization immunoassay (FPIA) system for point-of-care testing on patients being treated with theophylline. The sera were
collected from 20 patients being treated with theophylline. Fluorescence polarization was measured on the microchip and theophylline
concentrations in serum were obtained. Regression analysis of the correlations was done between the results given by the microchip-based
FPIA and the conventional cloned enzyme donor immunoassay (CEDIA), and between the results given by the microchip-based FPIA
and the conventional particle-enhanced turbidimetric inhibition immunoassay (PETINIA). We successfully carried out a quantitative
analysis of theophylline in serum at values near its therapeutic range in 65 s. The results obtained by the microchip-based
FPIA correlated well with CEDIA and PETINIA results; the correlation coefficients (R
2) were 0.986 and 0.989, respectively. The FPIA system is a simple and rapid method for point-of-care testing of drugs in serum,
and its accuracy is the same as the conventional CEDIA and PETINIA. It is essential to use real samples from patients and
to confirm good correlations with conventional methods for a study on the realization of microchip. 相似文献
72.
Yukihiro Uchida 《manuscripta mathematica》2011,134(3-4):273-308
We generalize the division polynomials of elliptic curves to hyperelliptic Jacobians over the complex numbers. We construct them by using the hyperelliptic sigma function. Using the division polynomial, we describe a condition that a point on the Jacobian is a torsion point. We prove several properties of the division polynomials such as determinantal expressions and recurrence formulas. We also study relations among the sigma function, the division polynomials, and the canonical local height functions. 相似文献
73.
Chen L Han X Yang J Zhou J Song W Zhao B Xu W Ozaki Y 《Journal of colloid and interface science》2011,360(2):482-487
We have employed the proposed Silica-Silver Core-Shell (SSCS) SERS-active substrates to detect four model proteins: lysozyme (a protein without chromophore), cytochrome c (a protein with chromophore of heme), fluorescein isothiocyanate (FITC)-anti human IgG (labeled with FITC) and atto610-biotin/avidin (recognition with labeled small molecules). SERS spectra of these proteins and Raman labels on the SSCS substrates show both high sensitivity and reproducibility, which are due to electromagnetic SERS enhancement with additional localization field within closely packed Ag nanoparticles decorated on the SiO(2) nanoparticles and the aggregation of SiO(2)@Ag particles. We have found that the SERS intensities of atto610-biotin/avidin adsorbed on the SSCS substrates are about 20 times stronger than those from Ag plating on Au-decorated substrate. Moreover, the broad surface plasmon resonance (SPR) of the proposed substrates will extend SERS applications to more biological molecules with different laser excitations. 相似文献
74.
Shintani R Narui R Tsutsumi Y Hayashi S Hayashi T 《Chemical communications (Cambridge, England)》2011,47(21):6123-6125
Novel chiral phosphorus-olefin bidentate ligands have been synthesized in a few steps from a readily available enantiopure compound. These ligands have been applied to a rhodium-catalyzed asymmetric addition of organoboroxines to N-sulfonyl aldimines, achieving high yield and enantioselectivity. 相似文献
75.
Ryosuke Hyakuna Masayoshi Tsutsumi 《NoDEA : Nonlinear Differential Equations and Applications》2011,18(3):309-327
We consider the Cauchy problem for the nonlinear Schrödinger equations $ \begin{array}{l} iu_t + \triangle u \pm |u|^{p-1}u =0, \qquad x \in \mathbb{R}^d, \quad t \in \mathbb{R} \\ u(x,0)= u_0(x), \qquad x \in \mathbb{R}^d \end{array} $ for 1 < p < 1 + 4/d and prove that there is a ${\rho (p ,d) \in (1,2)}We consider the Cauchy problem for the nonlinear Schr?dinger equations
l iut + \triangle u ±|u|p-1u = 0, x ? \mathbbRd, t ? \mathbbR u(x,0) = u0(x), x ? \mathbbRd \begin{array}{l} iu_t + \triangle u \pm |u|^{p-1}u =0, \qquad x \in \mathbb{R}^d, \quad t \in \mathbb{R} \\ u(x,0)= u_0(x), \qquad x \in \mathbb{R}^d \end{array} 相似文献
76.
We have investigated the pressure-induced Raman spectral changes of 1-ethyl-3-methylimidazolium tetrafluoroborate ([emim][BF4]). We found that [emim][BF4] did not crystallize up to 1.2 GPa. The Raman CH stretching spectra arising from the CH3 groups of the ethyl-chain and the CH3 group adjacent to the imidazolium-ring in [emim]+ cation largely changed against pressure. Moreover, the Raman intensity of the CH2 (N) bending band arising from the alkyl-chain drastically changes with increasing pressure, but that of the imidazolium-ring in-plane bending band arising from the imidazolium-ring is independent of pressure. Our results show that the environment around the alkyl-chain of [emim][BF4] is largely perturbed rather than that around the imidazolium-ring upon compression. 相似文献
77.
Yukihiro Aiba Naomichi Hatano Hideki Takayasu Kouhei Marumo Tokiko Shimizu 《Physica A》2002,310(3-4):467-479
We first show that there are in fact triangular arbitrage opportunities in the spot foreign exchange markets, analyzing the time dependence of the yen–dollar rate, the dollar–euro rate and the yen–euro rate. Next, we propose a model of foreign exchange rates with an interaction. The model includes effects of triangular arbitrage transactions as an interaction among three rates. The model explains the actual data of the multiple foreign exchange rates well. 相似文献
78.
Yukihiro Okada Manabu Mizutani Fuyuhiko Ishii Jun Nishimura 《Tetrahedron letters》1997,38(52):5347-9016
The modification of title compounds to chiral receptors and their characterization are reported. The two synthetic methods were developed. The racemates obtained could be resolved to each stable enantiomer by a chiral HPLC column. Chiral calixarenes were designed as the receptors with planar chirality. The (−)-receptor strongly forms 1:1 complex with (R)-(+)--phenylethylammonium picrate. 相似文献
79.
80.
Nobuhiro Kawatsuki Ryoji Tsutsumi Akie Hiraiwa Hirofumi Takatsuka Takeya Sakai 《Journal of polymer science. Part A, Polymer chemistry》2008,46(14):4712-4718
Thermally enhanced photoinduced in‐plane molecular reorientation in new photo‐cross‐linkable polymer liquid crystalline (PPLC) films comprising 4‐[ω‐(4‐methoxycinnamoyloxy)alkyloxy]biphenyl side groups is explored using linearly polarized ultraviolet (LPUV) light exposure and subsequent annealing. The influence of the alkylene spacer length between the photo‐cross‐linkable group and the biphenyl mesogenic moiety is investigated. The straight‐line characteristics of the photoreactive mesogenic side group and the 4‐methoxycinnamoyl group play important roles in the high photoreactivity and the large thermally enhanced molecular reorientation, where the in‐plane order and the birefringence of the reoriented film are 0.61 and 0.18 are obtained. Finally, cooperative molecular reorientation of dichroic dyes doped in PPLC films is also achieved to fabricate a linear polarizer. © 2008 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 46: 4712–4718, 2008 相似文献
|