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991.
Dr. Cher Hon Lau Dr. Kristina Konstas Dr. Aaron W. Thornton Dr. Amelia C. Y. Liu Dr. Stephen Mudie Dr. Danielle F. Kennedy Dr. Shaun C. Howard Dr. Anita J. Hill Dr. Matthew R. Hill 《Angewandte Chemie (International ed. in English)》2015,54(9):2669-2673
Porosity loss, also known as physical aging, in glassy polymers hampers their long term use in gas separations. Unprecedented interactions of porous aromatic frameworks (PAFs) with these polymers offer the potential to control and exploit physical aging for drastically enhanced separation efficiency. PAF‐1 is used in the archetypal polymer of intrinsic microporosity (PIM), PIM‐1, to achieve three significant outcomes. 1) hydrogen permeability is drastically enhanced by 375 % to 5500 Barrer. 2) Physical aging is controlled causing the selectivity for H2 over N2 to increase from 4.5 to 13 over 400 days of aging. 3) The improvement with age of the membrane is exploited to recover up to 98 % of H2 from gas mixtures with N2. This process is critical for the use of ammonia as a H2 storage medium. The tethering of polymer side chains within PAF‐1 pores is responsible for maintaining H2 transport pathways, whilst the larger N2 pathways gradually collapse. 相似文献
992.
The immune modulating effects of selected herbs deserve careful studies to gain evidence-based support for their further development. We have been working hard on many items of medicinal herbs to gain insight into their immunomodulatory effects relevant to cancer treatment in particular, while infection control is not excluded. Nine of them have been selected to give the results of our exploration on their biological, particularly immunomodulatory activities. Since Hong Kong people especially favor one medicinal mushroom, viz. Coriolus versicolor, a number of clinical trials using Coriolus for cancer-related studies are included in this review. While immune modulation platforms are being built for relevant studies, a brief account on the research targets and related procedures are given. 相似文献
993.
The derangement graph is the Cayley graph on the symmetric group \(\mathcal {S}_{n}\) whose generating set \(D_{n}\) is the set of permutations on \([n]=\{1, \ldots , n\}\) without any 1-cycle. For any fixed positive integer \(k \le n\), the Cayley graph generated by the subset of \(D_{n}\) consisting of permutations without any i-cycles for all \(1 \le i \le k\) is a regular subgraph of the derangement graph. In this paper, we determine the smallest eigenvalue of these subgraphs and show that the set of all the largest independent sets in these subgraphs is equal to the set of all the largest independent sets in the derangement graph, provided n is sufficiently large in terms of k. 相似文献
994.
Aldy Gunawan Hoong Chuin Lau Pieter Vansteenwegen Kun Lu 《The Journal of the Operational Research Society》2017,68(8):861-876
The Team Orienteering Problem with Time Windows (TOPTW) is the extension of the Orienteering Problem (OP) where each node is limited by a predefined time window during which the service has to start. The objective of the TOPTW is to maximize the total collected score by visiting a set of nodes with a limited number of paths. We propose two algorithms, Iterated Local Search and a hybridization of Simulated Annealing and Iterated Local Search (SAILS), to solve the TOPTW. As indicated in multiple research works on algorithms for the OP and its variants, determining appropriate parameter values in a statistical way remains a challenge. We apply Design of Experiments, namely factorial experimental design, to screen and rank all the parameters thereby allowing us to focus on the parameter search space of the important parameters. The proposed algorithms are tested on benchmark TOPTW instances. We demonstrate that well-tuned ILS and SAILS lead to improvements in terms of the quality of the solutions. More precisely, we are able to improve 50 best known solution values on the available benchmark instances. 相似文献
995.
Nan Chen B. Reeja‐Jayan Andong Liu Jonathan Lau Bruce Dunn Karen K. Gleason 《Macromolecular rapid communications》2016,37(5):446-452
A group of crosslinked cyclic siloxane (Si O) and silazane (Si N) polymers are synthesized via solvent‐free initiated chemical vapor deposition (iCVD). Notably, this is the first report of cyclic polysilazanes synthesized via the gas‐phase iCVD method. The deposited nanoscale thin films are thermally stable and chemically inert. By iCVD, they can uniformly and conformally cover nonplanar surfaces having complex geometry. Although polysiloxanes are traditionally utilized as dielectric materials and insulators, our research shows these cyclic organosilicon polymers can conduct lithium ions (Li+) at room temperature. The conformal coating and the room temperature ionic conductivity make these cyclic organosilicon polymers attractive for use as thin‐film electrolytes in solid‐state batteries. Also, their synthesis process and properties have been systemically studied and discussed.
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997.
Wai-Lun Man Jing Xiang Pui-Ha Lau Song Gao Wing-Tak Wong Tai-Chu Lau 《中国科学:化学(英文版)》2010,53(10):2106-2111
A series of tricyanoiron(III) complexes with the general formula mer-[FeIII(5-Xsap)(CN)3]2? (X = H, Me, MeO, Cl or Br, sapH2 = N-salicylidene-o-aminophenol) have been synthesized. These complexes were characterized by IR, ESI-MS, UV/Vis, elemental analysis and magnetic measurements. The structures of (PPh4)2[FeIII(sap)(CN)3] and (PPh4)2[FeIII(5-Mesap)(CN)3] have been determined by X-ray crystallography. These low-spin d 5 tricyanoiron(III) complexes are potential building blocks for the construction of molecule-based magnets. 相似文献
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