Synthesis and Electrocatalytic Activity of 3Au?1Pd Alloy Nanoparticles/Graphene Composite for Bisphenol A Detection

In this study, a 3Au? 1Pd alloy nanoparticles/graphene composite (3Au? 1Pd alloy NPs/GN) with carboxyl groups and hydroxyl groups was prepared facilely by co‐reduction of graphene oxide (GO), HAuCl₄, K₂PdCl₄, with an Au? Pd alloy molar ratio of 3 : 1. The composite modified glass carbon electrode (GCE) showed a good performance for detecting bisphenol A (BPA) due to the enhanced electron transfer kinetics and large active surface area. The effective enrichment of BPA is attributed to the carboxyl groups and hydroxyl groups on the composite. According to the results of differential pulse voltammetry (DPV), the BPA oxidation current is linear to its concentration in the range of 10 nM–5.0 µM (R=0.998), and the detection limit is found to be 4.0 nM (S/N=3).     

雾化辅助化学气相沉积法氧化镓薄膜生长研究

采用自主设计搭建的雾化辅助化学气相沉积系统设备,开展了Ga₂O₃薄膜制备及其特性研究工作。通过X射线衍射研究了沉积温度、系统沉积压差对Ga₂O₃薄膜结晶质量的影响。结果表明,Ga₂O₃在425~650 ℃温度区间存在物相转换关系。随着沉积温度从425 ℃升高至650 ℃,薄膜结晶分别由非晶态、纯α-Ga₂O₃结晶状态向α-Ga₂O₃、β-Ga₂O₃两相混合结晶状态改变。通过原子力显微镜表征探究了生长温度对Ga₂O₃薄膜表面形貌的影响,从475 ℃升高至650 ℃时,薄膜表面粗糙度由26.8 nm下降至24.8 nm。同时,高分辨X射线衍射仪测试表明475 ℃、5 Pa压差条件下的α-Ga₂O₃薄膜样品半峰全宽仅为190.8″,为高度结晶态的单晶α-Ga₂O₃薄膜材料。     

低曝光量下投影算法的稳健性研究

研究了在低曝光量情况下灰度投影算法的稳健性,为提出的稳定成像系统的设计与实现提供可行性论证。通过合成视频实验探讨、实际视频实验论证相结合的研究方法,探讨曝光量不足对灰度投影算法性能的影响。实验结果表明,灰度投影算法在欠曝5档和存在一定随机噪声的情况下,仍能保持良好的运动矢量估计性能,从而说明了投影算法在一定的曝光量范围内仍能准确地得到运动矢量估计,是一种运算量小、实时性好且稳健性较强的电子稳像算法。投影算法在低曝光量情况下良好的稳像稳健特性,使其能在低亮度及高实时性要求等环境下应用于航拍、卫星遥感等稳定成像或高清晰成像场合。     

Protective effects on ovalbumin-induced mouse asthma models and qualitative and quantitative analysis of multiple compounds in Gerberae Piloselloidis Herba

Gerberae Piloselloidis Herba is widely used to treat cough and asthma in China. However, its effects on allergic asthma as related to its chemical compositions have not been fully elucidated, and there is a scarcity of methods to determine multi-component contents for quality control. In this study, protective effects of Gerberae Piloselloidis Herba on ovalbumin-induced asthma models were investigated, while qualitative and quantitative analyses of multiple constituents in Gerberae Piloselloidis Herba were conducted by using an ultrahigh-performance liquid chromatography–Q Exactive hybrid quadrupole-orbitrap high-resolution accurate mass spectrometry and an ultrahigh-performance liquid chromatography–photodiode array detection. The results showed that Gerberae Piloselloidis Herba could significantly mitigate asthma symptoms, reduce eosinophils counts in the bronchoalveolar lavage fluid, as well as decrease IgE, IL-5, and IL-13 concentration, and inflammatory cellular infiltration in lung tissues. A total of 51 compounds were tentatively identified, in which the content of 10 representative compounds was determined in 24 batches of Gerberae Piloselloidis Herba by using an ultrahigh-performance liquid chromatography method with good linearity, precision, repeatability, accuracy, and stability. This research presents a comprehensive strategy combining biological activity evaluation with chemical profiling, providing a useful and comprehensive reference for further application and quality control of Gerberae Piloselloidis Herba.     

4'-substituted-4-biphenylyloxenium ions: reactivity and selectivity in aqueous solution

Azide trapping shows that the 4'-substituted-4-biphenylyloxenium ions 1b-d are generated during hydrolysis of 4-aryl-4-acetoxy-2,5-cyclohexadienones, 2c and 2d, and O-(4-aryl)phenyl-N-methanesulfonylhydroxylamines, 3b and 3c. In addition, the 4'-bromo-substituted ester, 2d, undergoes a kinetically second-order reaction with N3- that accounts for a fraction of the azide adduct, 5d. Since both first-order and second-order azide trapping occurs simultaneously in 2d, the second-order reaction is not enforced by the short lifetime of 1d, which has similar azide/solvent selectivity to the unsubstituted ion, 1a. In contrast the 4'-CN and 4'-NO2 ions 1e and 1f cannot be detected by azide trapping during the hydrolysis of the dichloroacetic acid esters 2e' and 2f' even though 18O labeling experiments show that a fraction of the hydrolysis of both esters occurs through C(alkyl)-O bond cleavage. These esters exhibit only second-order trapping by azide. Correlations of the azide/solvent selectivities of 1a-d with the calculated relative driving force for hydration of the ions (DeltaE of eq 4) determined at the pBP/DN//HF/6-31G and BP/6-31G//HF/6-31G levels of theory suggest that 1e and 1f have lifetimes in the 1-100 ps range. Ions with these short lifetimes are not in diffusional equilibrium with nonsolvent nucleophiles, and must be trapped by such nucleophiles via a preassociation mechanism. The second-order trapping that is observed in these two cases is enforced by the short lifetime of the cations, and may occur by a concerted S(N)2' mechanism or by internal azide trapping of an ion sandwich produced by azide-assisted ionization. Comparison of azide/solvent selectivities of the oxenium ions 1a-c with the corresponding biphenylylnitrenium ions 8a-c shows that 4'-substituent effects on reactivity in both sets of ions are similar in magnitude, although the nitrenium ions are ca. 30-fold more stable in an aqueous environment than the corresponding oxenium ions. The magnitude of the 4'-substituent effects for electron-donating substituents suggest that both sets of ions are more accurately described as 4-aryl-1-imino-2,5-cyclohexadienyl or 4-aryl-1-oxo-2,5-cyclohexadienyl carbocations. Calculated structures of the oxenium ions are also consistent with this interpretation.     

一类分块矩阵的谱包含域

给出了一类复分块矩阵的谱包含域，推广与改进了文[1～5]的相应结果．     

A Switching Algorithm Based on Modified Quasi-Newton Equation

In this paper, a switching method for unconstrained minimization is proposed. The method is based on the modified BFGS method and the modified SR1 method. The eigenvalues and condition numbers of both the modified updates are evaluated and used in the switching rule. When the condition number of the modified SR1 update is superior to the modified BFGS update, the step in the proposed quasi-Newton method is the modified SR1 step. Otherwise the step is the modified BFGS step. The efficiency of the proposed method is tested by numerical experiments on small, medium and large scale optimization. The numerical results are reported and analyzed to show the superiority of the proposed method.     

近十年来流动测量技术的新发展

流动是一种跨行业、跨部门、跨学科的现象。现代空气动力学、流体力学、热力学、水力学以及航空航天工程、水利水电工程、热能工程、流体机械工程都提出了一系列复杂流动问题，其中包括高速流、低速流、管道流、燃烧流、冲击流、振荡流、涡流、湍流、旋转流、多相流等等。这些流动都需要人们提供新的测量方法和新的量测仪器、使之能够适应单点向多点、平面向空间、稳态向瞬态、单相向多相方向发展，这就促使人们不断利用新技术，发展新原理，采用新结构和新工艺，以改善食品性能，增强讯号处理能力，提高仪器的测量精度。同时简化操作技术，使之便于推广应用。近10年来，伴随着光纤技术、芯片技术、激光技术、数字信号处理技术，图形、图像处理技术以及计算机技术的日益成熟和完善，流速测量技术也随之得到了新的发展。本文就这些发展作一扼要介绍。     

Fast image enhancement using multi-scale saliency extraction in infrared imagery

We propose a multi-scale saliency extraction based fast infrared image enhancement approach. A local frequency-tuned based saliency extraction technique is designed for highlighting the salient regions, firstly. Then, multi-scale saliency extraction is demonstrated, introducing multi-scale local windows with different sizes to extract regions of interest at different scales. Finally, the original image is enhanced with combining multi-scale salient image regions into one image. The experimental results prove the proposed approach is robust and efficient for infrared image enhancement.     

基于面阵CCD的时间延时积分模式的空间相机自动对焦

空间面阵相机在轨运动会产生运动模糊,影响自动对焦准确率。为解决该问题,提出行间转移面阵CCD的时间延时积分(TDI)模式实现去运动模糊。选取行间转移面阵CCD KAI-1003作为成像器件,利用可编程逻辑器件(PLD)控制时序信号,匹配CCD的行转移速度与目标运动速度,实现去运动模糊。实验表明该成像系统不仅能去运动模糊而且还大幅提高图像信噪比。去运动模糊后,根据较短时间间隔内空间相机拍摄的图像有重叠区域的特点提出一种空间相机自动对焦方法。通过配准算法找出序列图像间的重叠区域,并计算重叠区域的清晰度评价值,然后根据传递特性将评价值映射到同一个评价体系中,最后找到最佳对焦位置。实验表明该成像系统对高速运动的目标能够实现自动对焦。