首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   31983篇
  免费   5404篇
  国内免费   4035篇
化学   23167篇
晶体学   350篇
力学   2046篇
综合类   283篇
数学   3887篇
物理学   11689篇
  2024年   89篇
  2023年   629篇
  2022年   1071篇
  2021年   1140篇
  2020年   1237篇
  2019年   1334篇
  2018年   1060篇
  2017年   1034篇
  2016年   1486篇
  2015年   1518篇
  2014年   1871篇
  2013年   2280篇
  2012年   2880篇
  2011年   2889篇
  2010年   2019篇
  2009年   1903篇
  2008年   2078篇
  2007年   1822篇
  2006年   1759篇
  2005年   1427篇
  2004年   1123篇
  2003年   965篇
  2002年   1030篇
  2001年   833篇
  2000年   661篇
  1999年   682篇
  1998年   541篇
  1997年   488篇
  1996年   501篇
  1995年   411篇
  1994年   351篇
  1993年   313篇
  1992年   271篇
  1991年   272篇
  1990年   211篇
  1989年   203篇
  1988年   152篇
  1987年   111篇
  1986年   119篇
  1985年   105篇
  1984年   81篇
  1983年   62篇
  1982年   56篇
  1981年   42篇
  1980年   32篇
  1979年   26篇
  1978年   30篇
  1977年   29篇
  1976年   27篇
  1973年   29篇
排序方式: 共有10000条查询结果,搜索用时 31 毫秒
71.
罗娟  袁广南  杨招军 《经济数学》2005,22(3):261-265
针对投资者可能的投资需求确立了基于安全第一思想下两个相近的投资目标:1、极大化投资末期总收益率超过给定水平α的概率;2、极小化投资末期总收益率与给定水平α的距离.并分别就这两个目标建立了优化决策模型,得到了模型解析解,最后对两个模型结果进行了比较分析和经济解释.  相似文献   
72.
In the title compound, catena‐poly[lithium‐μ3‐ethyl­ene­diphos­phon­ato], [Li(C2H7O6P2)]n, the supra­molecular monoclinic (C2/c) structure consists of one‐dimensional lithium chains [Li⋯Li = 2.7036 (8) Å] that are embedded within ethyl­ene­diphosphon­ate anions linked by strong symmetric hydrogen bonds [O⋯O = 2.473 (3) Å]. The Li atoms and the H atom in the symmetric hydrogen bond reside on twofold rotation axes and there is an inversion center at the mid‐point of the C—C bond of the ethylenediphosphonate ligand.  相似文献   
73.
物理模型教学与创新能力的培养   总被引:1,自引:0,他引:1  
现代教学以能力培养为重点.学生获得研究问题、探索问题的能力是十分重要的,物理模型的教学过程对培养学生研究问题、探索问题、发展创造思维、培养辩证唯物主义思想方法都极为有利,因此,必须重视物理模型教学.  相似文献   
74.
Wang  Qing-Lun  Zhao  Bin  Liao  Dai-Zheng  Yan  Shi-Ping  Cheng  Peng  Jiang  Zong-Hui 《Transition Metal Chemistry》2003,28(3):326-330
The copper(II) complex Na2[Cu(pba)] · 6H2O has been synthesized and its structure determined. It consists of a novel two-dimensional network of [Cu(pba)]2– anions connected to each other through the sodium ion as a bridge. Spectroscopic and magnetic properties have been measured and a spin distribution calculation has been carried out with the GAUSSIAN-94. Theoretical calculations indicate the rather larger spin density on nitrogen atoms should be responsible for the satellite lines appearing beside the main hyperfine coupling signs of copper(II). The antiferromagnetic interaction may be due to the intermolecular interaction and/or different copper(II) ions through the Na+ bridge in the same layer.  相似文献   
75.
A novel cycloartane,named sphaerophysone A,9,19-cycloart-7β,24β,25-triol-1-en-3-one,was isolated from the ethanol extract of Sphaerophysa salsula DC.The structure was elucidated on the basis of spectral evidences and confirmed by X-ray analysis,the stereochemistry of the compound was also defined by X-ray analysis.  相似文献   
76.
We have synthesized a blue‐light‐emitting polyfluorene (PF) derivative ( PF‐CBZ‐OXD ) that presents bulky hole‐transporting carbazole and electron‐transporting oxadiazole pendent groups functionalized at the C‐9 positions of alternating fluorene units. The results from photoluminescence and electrochemical measurements indicate that both the side chains and the PF main chain retain their own electronic characteristics in the copolymer. An electroluminescent device incorporating this polymer as the emitting layer was turned on at 4.5 V; it exhibited a stable blue emission with a maximum external quantum efficiency of 1.1%. Moreover, we doped PF‐CBZ‐OXD and its analogue PF‐TPA‐OXD with a red‐light‐emitting iridium phosphor for use as components of phosphorescent red‐light emitters to investigate the effect of the host's HOMO energy level on the degree of charge trapping and on the electrophosphorescent efficiency. We found that spectral overlap and individual energy level matching between the host and guest were both crucial features affecting the performance of the electroluminescence devices. Atomic force microscopy measurements indicated that the dipolar nature of PF‐CBZ‐OXD , in contrast to the general nonpolarity of polydialkylfluorenes, provided a stabilizing environment that allowed homogeneous dispersion of the polar iridium triplet dopant. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 2925–2937, 2007  相似文献   
77.
Langduin C, a novel dimeric diterpenoid, was isolated from the roots of Euphorbia fischeriana and its structure was established by spectral data and single-crystal X-ray diffraction analysis.  相似文献   
78.
In Shack–Hartmann wavefront sensor (SHWS), the behavior of the irradiance pattern produced by the micro-lens array is important for an accurate centroid estimation. In this paper, the behavior of a micro-lens array in SHWS is analyzed using Fourier optics, and reveals that in addition to the main, expected spots, secondary spots with smaller intensities also appeared as a result of diffraction by the small dimensions of the micro-lens and interference from the different micro-lenses. This result is confirmed by comparing with a irradiance pattern taken from an actual SHWS. The additional error in centroid estimation caused by these secondary spots is discussed and relationship to the parameters of the micro-lens of SHWS is analyzed.  相似文献   
79.
The novel phase transfer catalysts S-8 [4-(dimethyloctylammonium) propansultan] and DB-X [1,4-bis(triethylmethylammonium)benzene dibromide] were synthesized and employed for high conversion synthesis of dichlorocyclopropane from various olefins.This revised version was published online in December 2005 with corrections to the Cover Date.  相似文献   
80.
本在以往研究的基础上对关系专用投资的价值创造功能作了进一步的讨论,分析了其创造准租金收入的机理和一般表示,在此基础上结合以往交易成本经济学对关系专用性投资的认识以及其作为沉没成本的特征,从效用最大化的角度建立了两个成员的联盟中关系专用性投资的决策模型,分析了关系专用性投资创造准租的具体特征对投资水平的影响。  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号