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901.
镉的化学蒸气发生-原子光谱分析法 总被引:6,自引:0,他引:6
从反应体系、反应机理和应用三方面对镉的化学蒸气发生-原子光谱分析法进行了综述,引用文献34篇。 相似文献
902.
Effects of clouds, sea surface temperature, and its diurnal variation on precipitation efficiency 总被引:1,自引:0,他引:1 下载免费PDF全文
The effects of clouds, sea surface temperature, and its diurnal variation on precipitation efficiency are investigated using grid-scale data from nine equilibrium sensitivity cloud-resolving model experiments driven without large-scale vertical velocity. The precipitation efficiencies are respectively defined in surface rainfall, cloud, and rain microphysical budgets. We mathematically and physically demonstrate the relationship between these precipitation efficiencies. The 2℃ increases in spatiotemporal invariant sea surface temperature (SST) from 27℃ to 29℃ and from 29℃ to 31℃, and the inclusion of diurnal SST difference 1℃ and the 1℃ increase in diurnal SST difference generate opposite changes in the precipitation efficiency by changing ice cloud-radiation interactions. The radiative and microphysical processes of ice clouds have opposite effects on the precipitation efficiency because of the rainfall increase associated with the reduction in the saturation mixing ratio caused by the exclusion of radiative effects and the decrease in rainfall related to the reduction in net condensation caused by the exclusion of deposition processes. The radiative effects of water clouds on the precipitation efficiency are statistically insensitive to the radiative effects of ice clouds. 相似文献
903.
Coiled carbon nanostructure (CNS) is prepared by a catalytic chemical vapor deposition (CVD) process on copper/chromium films deposited by radio frequency (RF) sputtering. Uniform CNS with coiled structure is fabricated by changing the size of the catalyst particles. The effects of Cu catalyst size and RF sputtering power, on the growth of the coiled CNS are discussed, and the results importantly conclude that Cu-catalyzed CVD offers a preferable control of coiled CNS to optimize the field emission property for application. 相似文献
904.
High-performance undoped white organic light-emitting diode (OLED) has been fabricated using an ultrathin yellow-emitting layer of 5,6,11,12-tetraphenylnaphthacene (rubrene) inserted at two sides of interface between two N,N′-bis-(1-naphthyl)-N,N′- biphenyl-1,1′-biphenyl-4,4′- diamine (NPB) layers as a hole transporting and blue emissive layer, respectively. The results showed that a maximum luminance of the device reached to as high as 21,500 cd/m2 at 15 V. The power efficiencies of 2.5 and 1.6 lm/W at a luminance of 1000 and 10000 cd/m2, respectively, were obtained. The peaks of electroluminescent (EL) spectra locate at 429 and 560 nm corresponding to the Commissions Internationale De L’Eclairage (CIE) coordinates of (0.32, 0.33), which is independent of bias voltage. The performance enhancement of the device may result from direct charge carrier trapping in rubrene. Energy transfer mechanism was also found in the EL process. 相似文献
905.
906.
Guo‐Xu Zhang Ying Xie Hai‐Tao Yu Hong‐Gang Fu 《Journal of computational chemistry》2009,30(12):1785-1798
The structural and electronic properties of five terminations of cubic lead titanate (PbTiO3) (110) polar surface were investigated by first‐principles total‐energy calculations using a periodic slab model. On the PbTiO termination, an anomalous filling of conduction band was observed, whereas on the O2 termination, two surface oxygen atoms formed a peroxo group, demonstrating that the electronic structures of the two stoichiometric terminations undergo significant changes with respect to bulk materials. However, for the three nonstoichiometric TiO‐, Pb‐, and O‐terminated surfaces, their electronic structures are very similar to bulk. Charge redistribution results for the five terminations confirmed that electronic structure and surface composition changes are responsible for their polarity compensation. However, which mechanism actually dominates the stabilization process depends upon energetic considerations. A thermodynamic stability diagram suggested that the two stoichiometric terminations are unstable; however, the three nonstoichiometric terminations can be stabilized in some given regions. Furthermore, this study indicates that the very different stabilities and surface states filling behaviors of the PbTiO3 (110) polar surface with respect to SrTiO3 and BaTiO3 ones seem to originate from the partially covalent characteristics of Pb O pairs. © 2008 Wiley Periodicals, Inc. J Comput Chem 2009 相似文献
907.
Tao Song Corey N. W. Lam Dominic C. M. Ng Galina Orlova Julia Laskin De-Cai Fang Ivan K. Chu 《Journal of the American Society for Mass Spectrometry》2009,20(6):972-984
The dissociation of [CuII(L)His]•2+ complexes [L=diethylenetriamine (dien) or 1,4,7-triazacyclononane (9-aneN3)] bears a strong resemblance to the previously reported behavior of [CuII(L)GGH]•2+ complexes. We have used low-energy collision-induced dissociation experiments and density functional theory (DFT) calculations
at the B3LYP/6-31+G(d) level to study the macrocyclic effect of the auxiliary ligands on the formation of His•+ from prototypical [CuII(L)His]•2+ systems. DFT revealed that the relative energy barriers of the same electron-transfer (ET) dissociation pathways of [CuII(9-aneN3)His]•2+ and [CuII(dien)His]•2+ are very similar, with the ET reactions of [CuII(9-aneN3)His]•2+ leading to the generation of two distinct His•+ species; in contrast, the proton transfer (PT) dissociation pathways of [CuII(9-aneN3)His]•2+ and [CuII(dien)His]•2+ differ considerably. The PT reactions of [CuII(9-aneN3)His]•2+ are associated with substantially higher barriers (>13 kcal/mol) than those of [CuII(dien)His]•2+. Thus, the sterically encumbered auxiliary 9-aneN3 ligand facilitates ET reactions while moderating PT reactions, allowing the formation of hitherto nonobservable histidine
radical cations. 相似文献
908.
By introducing a bivariate matrix-valued linear functional on the scalar polynomial space, a general two-dimensional (2-D) matrix Padé-type approximant (BMPTA) in the inner product space is defined in this paper. The coefficients of its denominator polynomials are determined by taking the direct inner product of matrices. The remainder formula is developed and an algorithm for the numerator polynomials is presented when the generating polynomials are given in advance. By means of the Hankel-like coefficient matrix, a determinantal expression of BMPTA is presented. Moreover, to avoid the computation of the determinants, two efficient recursive algorithms are proposed. At the end the method of BMPTA is applied to partial realization problems of 2-D linear systems. 相似文献
909.
Jianhui Wang Tao Liu Dr. Guotao Wu Dr. Wen Li Yongfeng Liu Dr. C. Moysés Araújo Dr. Ralph H. Scheicher Dr. Andreas Blomqvist Rajeev Ahuja Prof. Zhitao Xiong Dr. Ping Yang Dr. Mingxia Gao Dr. Hongge Pan Prof. Ping Chen Prof. 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2009,121(32):5942-5946
910.
Tao Yang Xiao Bo Yang Ren Hou Liu En Li Tie Hua Wang Mong Lin Zheng 《International Journal of Infrared and Millimeter Waves》2001,22(2):343-349
In this paper, a new method to realize pre-selected harmonic mixer is introduced. It includes a harmonic mixer, and a YIG turning filter (YTF) design. A digital driver is used for YTF, which can realize linearization modification and temperature compensation. The spectrum analyzer's out scanning voltage is given an A/D conversion and interface to digital driver. 相似文献