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111.
This paper is concerned with the following rational difference equation xn+1=axn-bxn-1+ex2n/(cXn+dxn-1), with the initial conditions x-1 , x0 ∈ (0, +∞) and a, b, c, d, e ∈ R+ . Locally asymptotically stability, global attractively and boundedness character of the equilibrium point of the equation are investigated. Moreover, simulation is shown to support the results. 相似文献
112.
113.
Guoping Dong Xiudi Xiao Xiaofeng Liu Bin Qian Yang Liao Chen Wang Danping Chen Jianrong Qiu 《Applied Surface Science》2009,255(17):7623-7626
Face-centered cubic Ag porous films have been prepared directly from the heat treatment of AgNO3-doped poly(vinyl alcohol) (PVA) electrospun nanofibers. Using Rhodamine B (RB) as the probing molecule, the surface-enhanced Raman scattering (SERS) effect of Ag porous films was demonstrated. The antibacterial activity of Ag porous films was also studied in this work. The propagation and biological activity of yeast cells were effectively inhibited by Ag porous films. These functional Ag porous films were expected to be applied in many fields, such as catalysis, diagnostics, sensors and antibacterial, etc. 相似文献
114.
扩展的Sinh—Gordon方程展开法与Kaup—Kupershmidt方程的Jacobi椭圆函数解 总被引:1,自引:0,他引:1
利用扩展的Sinh—Gordon方程展开法研究了Kaup—Kupershmidt方程的Jacobi椭圆函数解,此方法也适用于求解其他非线性演化方程,从而丰富了方程解的范围. 相似文献
115.
Density functional theory was employed to investigate rhodium(I)‐catalyzed C–C bond activation of siloxyvinylcyclopropanes and diazoesters. The B3LYP/6‐31G(d,p) level (LANL2DZ(f) for Rh) was used to optimize completely all intermediates and transition states. The computational results revealed that the most favorable pathway was the channel forming the methyl‐branched acyclic product p1 in path A (cyclooctadiene (cod) as the ligand), and the oxidative addition was the rate‐determining step for this channel. It proceeded mainly through the complexation of diazoester to rhodium, rhodium–carbene formation, coordination of siloxyvinylcyclopropane, oxidative addition (C2–C3 bond cleavage) of siloxyvinylcyclopropane, carbene migratory insertion, β‐hydrogen elimination and reductive elimination. The complexation of diazoester to rhodium occurred prior to the coordination of siloxyvinylcyclopropane. Also, the role of the ligands cod, chlorine and 1,4‐dioxane, the effect of di‐rhodium catalyst and the solvent effect are discussed in detail. 相似文献
116.
Xue‐qin Zhao Sheng Guo Hui Yan You‐yuan Lu Fang Zhang Da‐wei Qian Han‐qing Wang Jin‐ao Duan 《Biomedical chromatography : BMC》2019,33(8)
The leaves of Lycium barbarum (LLB) have been utilized as crude drugs and functional tea for human health in China and Southeast Asia for thousands of years. To control its quality, a rapid and sensitive ultra‐high‐performance liquid chromatography coupled with triple quadrupole tandem mass spectrometry method was established and validated for the first time for simultaneous determination of 10 phenolic acids and flavonoids (including neochlorogenic acid , protocatechuic aldehyde, p‐hydroxybenzoic acid, chlorogenic acid, cryptochlorogenic acid, caffeic acid, p‐coumaric acid, ferulic acid, rutin and kaempferol‐3‐O‐rutinoside) in LLB. The separation was performed on an Acquity UPLC C18 chromatographic column (100 × 2.1 mm internal diameter, 1.7 μm particle size) with 0.1% formic acid in water (A)–acetonitrile (B) as the mobile phase under gradient elution. Multiple reaction monitoring mode was adopted to simultaneously monitor the target components. The developed method was fully validated in terms of linearity (r2 ≥ 0.9860), precision (RSD ≤ 6.58%), repeatability (RSD ≤ 6.60%), stability (RSD ≤ 6.17%), recovery (95.56–108.06%, RSD ≤ 4.64%) and limit of detection (0.021–0.664 ng/mL) and limit of quantitation (0.069–2.210 ng/mL), and then successfully applied to evaluate the quality of 64 batches of LLB collected from 41 producing areas in four different provinces of China. The results showed that the LLB, especially collected from Inner Mongolia regions, were rich in the phenolic acids and flavonoids. Rutin, kaempferol‐3‐O‐rutinoside and chlorogenic acid are the predominant compounds contained in LLB. The above findings will provide helpful information for the effective utilization of LLB. 相似文献
117.
Qian Li Mingrui Yuan Jinyu Li Di Wei Shuangxi Mei Tao Cui Jingkun Wang Zhaoyun Zhu Xun Dong Jinfu Wan 《Magnetic resonance in chemistry : MRC》2019,57(11):934-938
Two new eudesmane derivatives, 1α,6β,9β-trihydroxy-eudesm-3-ene-1-O-β-d -glucopyranoside ( 1 ) and 1α,6β,9β-trihydroxy-eudesm-3-ene-1-(6-cinnamoyl)-O-β-d -glucopyranoside ( 2 ) were discovered from Merremia yunnanensis. The structures were elucidated by analysis of their spectroscopic data including HR-ESI-MS, 1D, and 2D NMR. It should be noted that this is the first report about structure elucidation and NMR assignment of compounds from M. yunnanensis. 相似文献
118.
已探明塔里木盆地下古生界碳酸盐岩地层储量巨大。对塔里木盆地西北部柯坪-巴楚-阿图什一带的4块区域开展了系统的野外和重点观测工作,包括蓬莱坝剖面、柯坪水泥厂剖面、托普郎剖面等。本研究通过考察塔里木盆地奥陶系碳酸盐岩热液溶蚀及相关现象。从野外产状、伴生关系以及矿物岩石学特征角度解剖奥陶系地层中热液矿物组合的地质特征。研究表明,该区域存在富镁流体、富氟流体和富硫流体3种流体,分别来源于封存卤水、火成活动和TSR热液。不同性质流体蚀变具有相似的分带性。 相似文献
119.
Lin-Feng Dai Qian Liang Tie Liu Ming-Yu He Ping Zhao 《Natural product research》2016,30(14):1639-1645
One new tigliane-type diterpene, 4-deoxy-4(β)H-8-hydroperoxyphorbol-12-benzoate-13-isobutyrate (1), together with two known diterpenoids, 3-acetyl-5,8-dibenzoyl-14α-propanoyl-13,17-epoxy-7-myrsinaone diterpene with C9–C10 cyclised to form an additional lactone ring (2), Euphodendriane A (3) have been isolated from the whole plants of Euphorbia dracunculoides Lam. Their structures were elucidated by means of extensive spectroscopic analysis (NMR and HR-ESI-MS) and comparison with data reported in the literature. This is the first isolation of 8-hydroperoxy tigliane diterpene (1) from the genus of Euphorbia. All compounds were evaluated for their antifungal activities. 相似文献
120.
Ab initio molecular orbital calculations for N9, N−
9 and N+
9 isomers were carried out at the HF/ 6-31G*, B3PW91/6-31G*, B3LYP/6-31G* and MP2/ 6-31G* levels of theory. Stable equilibrium
geometric structures were determined by harmonic vibrational frequency analyses at the HF/6-31G*, B3PW91/6-31G* and B3LYP/6-31G*
levels of theory. The most stable free-radical N9 cluster is structure 1 with C
2
v
symmetry and that of anion N−
9 is structure 3 with C
s
symmetry. Only one stable structure of the N+
9 cation with C
2
v
symmetry was predicted. Their potential application as high-energy-density materials has been examined.
Received: 15 June 1999 / Accepted: 11 October 1999 / Published online: 14 March 2000 相似文献