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31.
The steady laminar thermosolutal Marangoni convection in the presence of temperature-dependent volumetric heat sources/sinks as well as of a first-order chemical reaction is considered in this paper. Assuming that the surface tension varies linearly with temperature and concentration and that the interface temperature and concentration are quadratic functions of the interface arc length x, exact analytical similarity solutions are obtained for the velocity, temperature and concentration fields. The features of these exact solutions as functions of the physical parameters of the problem are discussed in detail.  相似文献   
32.
    
Aiming toward compounds with improved anti-Toxoplasma activity by exploiting the parasite auxotrophies, a library of nucleobase-tethered trithiolato-bridged dinuclear ruthenium(II)-arene conjugates was synthesized and evaluated. Structural features such as the type of nucleobase and linking unit were progressively modified. For comparison, diruthenium hybrids with other type of molecules were also synthesized and assessed. A total of 37 compounds (diruthenium conjugates and intermediates) were evaluated in a primary screening for in vitro activity against transgenic Toxoplasma gondii tachyzoites constitutively expressing β-galactosidase (T. gondii β-gal) at 0.1 and 1 µM. In parallel, the cytotoxicity in non-infected host cells (human foreskin fibroblasts, HFF) was determined by alamarBlue assay. Twenty compounds strongly impairing parasite proliferation with little effect on HFF viability were subjected to T. gondii β-gal half maximal inhibitory concentration determination (IC50) and their toxicity for HFF was assessed at 2.5 µM. Two promising compounds were identified: 14, ester conjugate with 9-(2-oxyethyl)adenine, and 36, a click conjugate bearing a 2-(4-(hydroxymethyl)-1H-1,2,3-triazol-1-yl)methyl substituent, with IC50 values of 0.059 and 0.111 µM respectively, significantly lower compared to pyrimethamine standard (IC50 = 0.326 µM). Both 14 and 36 exhibited low toxicity against HFF when applied at 2.5 µM and are candidates for potential treatment options in a suitable in vivo model.  相似文献   
33.
    
The synthesis of Faujasite‐type zeolites with high purity has been successfully performed from Tunisian kaolinite and the effects of different crystallization parameters on the final products were widely investigated. The alkaline fusion of kaolinite followed by hydrothermal treatment lead to zeolite NaX synthesis whereas the classic hydrothermal transformation of metakaolinite produces NaY zeolite. The results show that an increase in the synthesis temperature and time has improved the crystallization process of the zeolite NaX whereas the SiO2/Al2O3 and the Na2O/SiO2 molar ratios were the key parameters to obtain a pure zeolite NaY. The highest specific surface areas obtained with the optimal crystallization conditions were 554 m2 g?1 and 592 m2 g?1 for respectively NaX and NaY zeolites. The basic properties of NaX and NaY zeolites were explored in the Knoevenagel condensation of benzaldehyde with ethyl cyanoacetate at 140 °C as a test reaction in the absence of solvent. The influence of ion exchange with cesium cation on the catalytic activity of prepared catalysts was also investigated. It was found that the NaX provided higher activity than that of NaY catalyst due to its lower Si/Al ratio whereas a cesium exchange conferred higher basicity to the prepared Na‐faujasite.  相似文献   
34.
The problem of steady, laminar, thermosolutal Marangoni convection flow of an electrically-conducting fluid along a vertical permeable surface in the presence of a magnetic field, heat generation or absorption and a first-order chemical reaction effects is studied numerically. The general governing partial differential equations are converted into a set of self-similar equations using unique similarity transformations. Numerical solution of the similarity equations is performed using an implicit, iterative, tri-diagonal finite-difference method. Comparisons with previously published work is performed and the results are found to be in excellent agreement. Approximate analytical results for the temperature and concentration profiles as well as the local Nusselt and sherwood numbers are obtained for the conditions of small and large Prandtl and Schmidt numbers are obtained and favorably compared with the numerical solutions. The effects of Hartmann number, heat generation or absorption coefficient, the suction or injection parameter, the thermo-solutal surface tension ratio and the chemical reaction coefficient on the velocity, temperature and concentration profiles as well as quantitites related to the wall velocity, boundary-layer mass flow rate and the Nusselt and Sherwood numbers are presented in graphical and tabular form and discussed. It is found that a first-order chemical reaction increases all of the wall velocity, Nusselt and Sherwood numbers while it decreases the mass flow rate in the boundary layer. Also, as the thermo-solutal surface tension ratio is increased, all of the wall velocity, boundary-layer mass flow rate and the Nusselt and Sherwood numbers are predicted to increase. However, the exact opposite behavior is predicted as the magnetic field strength is increased.  相似文献   
35.
Journal of Thermal Analysis and Calorimetry - In the present paper, the first and second laws of thermodynamics are utilized to select the optimized position of porous insert to achieve maximum...  相似文献   
36.
Journal of Thermal Analysis and Calorimetry - The purpose of the current study is to numerically investigate the effects of shape factors of nanoparticles on natural convection in a fluid-saturated...  相似文献   
37.
Journal of Thermal Analysis and Calorimetry - The paper presents the mixed convection heat transfer and entropy generation of a nanofluid containing carbon nanotubes, flowing in a 3D rectangular...  相似文献   
38.
Journal of Thermal Analysis and Calorimetry - Bioconvection in magneto-nanoliquid embedded with gyrotactic microorganisms across an elongated sheet with velocity slip of second order is addressed....  相似文献   
39.
 An analysis has been carried out to determine the development of momentum and heat transfer occurring in the laminar boundary layer of an incompressible viscous electrically conducting fluid in the stagnation region of a rotating sphere caused by the impulsive motion of the free stream velocity and the angular velocity of the sphere. At the same time the wall temperature is also suddenly increased. This analysis includes both short and long-time solutions. The partial differential equations governing the flow are solved numerically using an implicit finite-difference scheme. There is a smooth transition from the short-time solution to the long-time solution. The surface shear stresses in the longitudinal and rotating directions and the heat transfer are found to increase with time, magnetic field, buoyancy parameter and the rotation parameter. Received on 27 January 2000  相似文献   
40.
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