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201.
We analyze a discrete-time, single-server queueing system in which the length of each service period is limited. The server takes a vacation when the limit expires or the queue empties, whichever occurs first. In the former case, the preempted service is resumed after the vacation without loss or creation of any work. This system models the transmission of message frames from a station on timed-token local-area networks (for example, FDDI and IEEE 802.4 token bus). We study the process of the unfinished work and the joint process of the queue size and the remaining service time. By using the technique of discrete Fourier transforms to determine some unknown functions in the governing equations, we numerically obtain exact mean waiting times.A part of the work of H. Takagi was done while he was with IBM Research, Tokyo Research Laboratory. 相似文献
202.
203.
204.
We present firstT 1e ?1 andT 2e ?1 measurements on the organic ion radical salt 3,3′-diethyl-4,4′-dimethyl-2,2′-thiazolocyanine-(TCNQ)2 as function of temperature and of orientation. The electronic spin diffusion constant could be determined directly by the electron spin echo field gradient technique:D (300 K)=0.03±0.02 cm2/sec. Pulsed ESR experiments have — in comparison to conventional cw-ESR — the advantage to monitor viaT 1e ?1 andT 2e ?1 the spectral density of dynamical processes at different frequencies. This is shown in a general manner on 3,3′-diethyl-4,4′-dimethyl-2,2′-thiazolocyanine-(TCNQ)2. Between 300 and 60 K,T 1e ?1 andT 2e ?1 are close in amplitude and have a similar temperature dependence. At 60 K their degeneracy is lifted, yielding a quantitative value for the effective spin exchange between localized spinsτ ex ?1 sec?1 and via the absolute value of the relaxation an average distance of the localized centers of about 12 Å. The dynamical data as evaluated above cannot be correlated with the conductivity, clearly indicating that the conduction electrons are a minority, not being monitored by the ESR-experiments. 相似文献
205.
Y. Kato E. Miura T. Tachi H. Shiraga H. Nishimura H. Daido M. Yamanaka T. Jitsuno M. Takagi P. R. Herman H. Takabe S. Nakai C. Yamanaka M. H. Key G. J. Tallents S. J. Rose P. T. Rumsby 《Applied physics. B, Lasers and optics》1990,50(4):247-256
Planer stripe and foil targets coated with NaF were irradiated with high intensity 351 nm laser radiation of 130 ps duration. Time-integrated as well as time-resolved measurement of gain on NaXIH at 54.2Å were made. A time-integrated gain of 1.2
–1.1
+0.8
cm–1 and a time-resolved peak gain of 3.2±1.0 cm–1 were obtained. A detailed account of the experimental procedures for determination of gain is given. 相似文献
206.
Yui T Tsuchino T Itoh T Ogawa M Fukushima Y Takagi K 《Langmuir : the ACS journal of surfaces and colloids》2005,21(7):2644-2646
Composite films of a meso-(tetramethylpyridinium)porphyrin (TMPyP) hybrid incorporated in mesoporous silica (MPS) and cast on a methyl viologen (MV2+)/titania nanosheet hybrid were synthesized and a light-induced charge separation between the two could be observed. These composite thin films were able to initiate a one-electron reduction of the MV2+ ions accompanied by the simultaneous decomposition of the TMPyP organic dye within the mesoporous silica channels. 相似文献
207.
208.
Yanada R Obika S Inokuma T Yanada K Yamashita M Ohta S Takemoto Y 《The Journal of organic chemistry》2005,70(17):6972-6975
We have developed efficient catalytic methods for the stereoselective and diversity synthesis of various (E)-, (Z)-, and disubstituted 3-alkylideneoxindoles and 3-alkylidenebenzofuran-2-ones via palladium-catalyzed Heck/Suzuki-Miyaura, Heck/Heck, and Heck/carbonylation/Suzuki-Miyaura domino reactions. 相似文献
209.
Miharu Eguchi Hiroshi Tachibana Shinsuke Takagi Haruo Inoue 《Research on Chemical Intermediates》2007,33(1-2):191-200
The intercalation behavior of cationic porphyrin derivatives within the interlayer spaces of nano-layered clay minerals has been investigated. The porphyrins were successfully intercalated by the newly adopted method of repeated freeze-thaw cycles. The absorption spectra of the porphyrins were compared in the solution phase, adsorbed onto the exfoliated clay nano-sheets, intercalated within the interlayer spaces of clay sheets dispersed in water and intercalated in dry films. Substantial red shifts of the λmax values in the absorption spectra of the porphyrins were observed on the exfoliated clay sheets, and further red shifts were induced within the interlayer space. The dry films of the intercalated samples exhibited the largest red shifts. X-ray diffraction studies revealed that the clearance space between the layers in these intercalated hybrid compounds is only large enough for the porphyrins to be rigidly packed parallel to the clay layer. For the exfoliated clay nano-sheets, theoretical calculations were carried out on the correlation between the dihedral angle of the meso-substituted pyridiniumyl plane vs. the porphyrin ring and the λmax of the porphyrin Soret band. An extrapolation of the experimental λmax value to the correlation curve, afforded the dihedral angle to be 61.6°. The microscopic structure of the adsorbed state of the cationic porphyrins on the exfoliated clay nano-sheets was, thus, proposed to involve an orientation parallel to the clay surface, with a distance of 0.15 nm from the surface, which implies the expulsion of the solvent water molecules. 相似文献
210.
Yoshiki Katayama Ryuji Fukuda Toshiharu Iwasaki Kazuhide Nita Makoto Takagi 《Analytica chimica acta》1988
New crown ether dyes carrying two pendent anionic side-arms were synthesized for the extraction-spectrophotometry of alkaline earth metal ions. In the extraction of alkaline earth metal ions by these dianionic reagents, size recognition by the crown ether ring was more remarkable than in the case of alkali metal ion extraction by a similar type of monoanionic reagents. Dramatic changes in metal selectivity were observed when the nature of the anionic side-arm was changed while the crown ether skeleton was kept the same. The structure/selectivity relationship is discussed in terms of “chelate” and “intramolecular ion-pair” formation. Typically, when the basicity of the pendent anions was relatively high and a six-membered chelate was structurally possible for the pendent anions and the crown-bound metal, the extraction of calcium was favored by up to a factor of 3000 in the ratio of the Ca/Ba extraction constants for reagents of the diaza-18-crown-6 type. In contrast, the reagents which had pendent anions with only poor coordination ability for metal ions seemed to form complexes of the ion-pair type, and calcium ion was 105 times less extractable than barium ion for the same diaza-18-crown-6-skeleton. Strontium ion seemed to be extracted most effectively when the extracted complex assumed properties intermediate between the chelate and intramolecular ion-pair. 相似文献