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41.
Wen Piao Satoru Tsuda Dr. Yuji Tanaka Dr. Satoshi Maeda Dr. Fengyi Liu Shodai Takahashi Yu Kushida Dr. Toru Komatsu Dr. Tasuku Ueno Dr. Takuya Terai Prof. Toru Nakazawa Prof. Masanobu Uchiyama Prof. Keiji Morokuma Prof. Tetsuo Nagano Dr. Kenjiro Hanaoka 《Angewandte Chemie (International ed. in English)》2013,52(49):13028-13032
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本文给出了掺CdSxSe1-x玻璃平面波导分布反馈(DFB)光学双稳器件的设计和制备方法,实现了低功耗、快速的本征光学双稳。 相似文献
44.
Xianqing Piao Xianmin Zhang Yuichi Mori Masayuki Koishi Akinari Nakaya Shinichiro Inoue Isao Aoki Akira Otomo Shiyoshi Yokoyama 《Journal of polymer science. Part A, Polymer chemistry》2011,49(1):47-54
Electro‐optic side‐chain polymers have been synthesized by the post‐functionalization of methacrylate isocyanate polymers with novel phenyl vinylene thiophene vinylene bridge (FTC) nonlinear optical chromophores. For this application, FTC‐based chromophores were modified in their electronic donor structure, exhibiting much larger molecular hyperpolarizabilities compared with the benchmark FTC. Of these new chromophores, absorption spectra, hyper‐Rayleigh scattering experiment, and thermal analysis were carried out to confirm availability as effective nonlinear optical units for electro‐optic side‐chain polymers. The electro‐optic coefficients (r33) of obtained polymers were investigated in the process of in situ poling by monitoring the temperature, current flow, poling field, and electro‐optic signal. Compared with the nonsubstituted analogue, benxyloxy modified FTC chromophore significantly achieved higher nonlinear optical property, exhibiting molecular hyperpolarizability at 1.9 μm of 4600 × 10?30 esu and an r33 value of 150 pm/V at the wavelength of 1.31 μm. Synthesized electro‐optic polymers showed high glass transition temperature (Tg), so that the temporal stability examination exhibited >78% of the electro‐optic intensity remaining at 85 °C over 500 h. © 2010 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem, 2010 相似文献
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A microbial strain, Vagococcus sp. B32, was isolated and applied to degrade p-chloronitrobenzene (p-CNB) in aqueous solutions. Three degradation methods: biodegradation, direct γ-irradiation and 60Co-γ pre-irradiation with biodegradation by B32 were carried out. The decrease of p-CNB and the net increase of Cl− were investigated to evaluate the degradation efficiency. The preliminary results showed that the combined method of pre-irradiation with biodegradation of B32 was more effective than the two others. 相似文献
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Nitrogen‐rich double salt ammonium 3,4‐diamino‐1,2,4‐triazoliumstyphnate (NH4 · DATr · TNR) ( 2 ) with good thermal stability was successfully synthesized by reacting 3,4‐diamino‐1,2,4‐triazolium chloride aqueous solution with styphnic acid methanol solution under the reaction medium of aqueous ammonia. The title double salt was characterized by elemental analysis (EA), Fourier transformation infrared spectrum (FT‐IR), and X‐ray single‐crystal diffraction. It crystallizes in the monoclinic crystal system with space group P21/n. Its density is 1.780 g · cm–3. Compound 2 is thermal stable below 200 °C by the differential scanning calorimetry (DSC) test. The non‐isothermal kinetics parameters were calculated by the Kissinger's method and Ozawa‐Doyle's method, respectively. In addition, compound 2 showed low friction and impact sensitivities. 相似文献
48.
Fangdi Hu Shilan Feng Yuqiong Wu Yingyan Bi Fang Cui Yongjie Li Prof. Dr. Chunming Wang 《中国化学》2010,28(11):2293-2300
A simple and sensitive high performance liquid chromatographic (HPLC) method for simultaneous determination of costunolide and dehydrocostuslactone in mice plasma and tissues was developed and validated. Costunolide and dehydrocostuslactone were extracted into acetonitrile and separated using an isocratic mobile phase, on a Hypersil ODS C18 column. The effluent was monitored by UV detector at 210 nm and at a flow rate of 1.0 mL· min?1 and 25°C. The linearity ranges of proposed method were 0.223–8.920 µg·mL?1 for costunolide and 0.227–9.080 µg·mL?1 for dehydrocostuslactone. The intra‐day and inter‐day RSD of the assay method for the two components were less than 5%, and mean recovery was within the 86.5% to 101.8% range. The method was found to be precise, accurate, and specific during the study. The method was successfully applied for pharmacokinetic study of costunolide and dehydrocostuslactone after application of ethanol extraction of Muxiang (EEM) in mice. 相似文献
49.
Hyun Sik Kim Yuanzhe Piao Soon Hyung Kang Taeghwan Hyeon Yung-Eun Sung 《Electrochemistry communications》2010,12(3):382-385
Uniform α-Fe2O3 nanocapsules with a high surface area were synthesized by a novel wrap–bake–peel approach consisting of silica coating, heat treatment and finally the removal of the silica coating layer. The length, diameter and shell thickness of the hematite nanocapsules were about 65, 15 and 5 nm, respectively. The electrochemical properties of the α-Fe2O3 nanocapsules were investigated by cyclic voltammetry and charge/discharge measurements. The α-Fe2O3 nanocapsules showed a high reversible capacity of 888 mAh/g in the initial cycle and 740 mAh/g after 30 cycles as well as good capacity retention. This excellent electrochemical performance was attributed to the high surface area, thin shell and volume space of the hollow structure. 相似文献
50.
在建立水平井流动方程的基础上,通过气固两相流动基本数学模型的求解数值模拟不同工况条件下的气固混合物冲蚀能量,得出了冲蚀能量的变化规律。算例数值模拟显示:环空速度剖面主要由注气量大小决定,机械钻速的影响不大;相同注气量条件下,机械钻速降低与井下岩屑浓度等比例下降;注气量的增加能提高井眼净化程度,但不如降低机械钻速效果明显;环空总冲蚀能中气体冲蚀能量占绝对主要地位,岩屑冲蚀能量只占极小部分,在相同注气量条件下总冲蚀能量基本相同;岩屑冲蚀能量主要取决于机械钻速,机械钻速越大井底产生岩屑越多冲蚀能力越强,相同机械钻速条件下,较大注气量能提供较大岩屑运移速度,提高了岩屑冲蚀能量。 相似文献